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71.
有机金属聚合物/多酸纳米杂化LB膜的制备与光电性质研究 总被引:1,自引:0,他引:1
以含有共轭大π键的有机金属聚合物(OMP)作有机组分, 以Keggin结构和Dawson结构钨(钼)磷杂多酸作无机组分, 以十八胺为辅助成膜剂, 用LB技术制备了3种新型有机金属聚合物/十八铵/杂多阴离子OMP/ODA/HPA (HPA=PMo12, PW12, P2Mo18)杂化LB膜. 用π-A曲线﹑UV-vis吸收光谱﹑荧光光谱﹑原子力显微镜(AFM)﹑扫描隧道显微镜(STM)和表面光电压谱(SPS)对标题LB膜的成膜性能及光电性质进行了研究, 结果表明标题杂化LB膜的崩溃压为26.8 mN/m, 在可见光区有较强的光电压响应, 并有好的发光性质. 当电压为±8.0 V时, 隧道电流是-0.1~-2.3 nA. 相似文献
72.
John M. G. Cowie Roderick Ferguson 《Journal of Polymer Science.Polymer Physics》1985,23(10):2181-2191
A series of poly(itaconate ester)s containing methyl-terminated poly(ethylene oxide) side chains with lengths ranging from 1 to 5 ethylene oxide units has been synthesized. Both heat capacity Cp and dynamic mechanical measurements have been carried out on these polymers using differential scanning calorimetry (DSC) and torsional braid analysis (TBA), respectively. The resulting data for this polymer series are discussed, and comparisons are made with work previously published for the corresponding di-n-alkyl itaconate ester polymers where appropriate. 相似文献
73.
74.
In this paper, we give certain homotopy and diffeomorphism versions as a generalization to an earlier result due to W.S. Cheung, Bun Wong and Stephen S. T. Yau concerning a local rigidity problem of the tangent bundle over compact surfaces of general type. 相似文献
75.
Spinning Sidebands in Slow-Magic-Angle-Spinning NMR Spectra Arising from TightlyJ-Coupled Spin Pairs
Gang Wu Boqin Sun Roderick E. Wasylishen Robert G. Griffin 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1997,124(2):366-371
Complex spinning sidebands are observed in magic-angle-spinning (MAS) NMR spectra arising from isolated tightlyJ-coupled spin pairs under slow spinning conditions. Such spinning sidebands are sensitive to the magnitude and relative orientation of the chemical-shift tensors, the dipolar-coupling tensor, and the sign of the indirect spin–spin (J) coupling. We show that it is possible to extract information concerning such NMR parameters from an analysis of the observed spinning sidebands. As an example, numerical simulations are carried out to reproduce observed31P MAS NMR spectra of a phosphole tetramer (1) ando-bis(diphenylphosphino)benzene (2), so that invaluable information concerning the orientations of the phosphorus chemical-shift tensors and the sign ofJ(31P,31P) can be deduced. Simulations are carried out by numerically evaluating the spin-density matrix of the spin system. 相似文献
76.
Superconducting Transition Temperature and Metal--Semiconductor Transition Temperature in
YBa2Cu4O8/La0.67Ca0.33MnO3/YBa2Cu4O8 Trilayer Films
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YBa2Cu4O8/La0.67Ca0.33MnO3/YBa2Cu4O8(YBCO/LCMO/YBCO) trilayer films were prepared by magnetron facing-target sputtering. For the first time, the oscillatory behaviour of superconducting transition temperature Tc,ON with the thickness of LCMO (dL) has been observed. The strongest nonmonotonic information in the Tc,ON--dL curves appears clearly when dL is larger than the critical thickness dLCR. The metal--semiconductor transition temperature can only be detected at dL>dLCR. The dependence on the ferromagnetic spacer layer in YBCO/LCMO/YBCO systems suggests strongly the interplay of ferromagnetic and superconducting couplings. 相似文献
77.
The piperidine alkaloid, (+)-sedamine has been synthesised starting from (S)-1-phenyl-3-butenol using a stereoselective, intramolecular palladium-catalysed cyclocarbonylation reaction of a substituted hydroxylamine. 相似文献
78.
Electromagnetic implosion of spherical liner 总被引:1,自引:0,他引:1
79.
A beef fat sample was prepared and tested as candidate reference material for the pesticides chlorfluazuron (CFZ) and fluazuron (FZN). An analytical method employing HPLC with UV absorbance detection was developed for homogeneity and stability testing. The material consisted of beef fat spiked with acetone solutions of CFZ and FZN to achieve concentrations close to 1.0 mg/kg for each compound. The coefficients of variation of 7 analyses carried out to test between-jar homogeneity were 1.8% and 2.3% for FZN and CFZ, respectively. No instability of CFZ was detected over a three month period. The candidate reference material was found to be suitable for certification by interlaboratory testing. 相似文献
80.
The first observations of (31)P-(31)P indirect spin-spin (J) coupling in copper(I) phosphine complexes are reported for solid Cu(PPh(3))(2)X (X = NO(3)(-), BH(4)(-)). Values of (2)J((31)P,(31)P), 157 +/- 5 and 140 +/- 5 Hz for Cu(PPh(3))(2)NO(3) and Cu(PPh(3))(2)BH(4), respectively, have been obtained from two-dimensional (2D) J-resolved (31)P NMR spectra obtained under slow magic-angle spinning (MAS) conditions. In both complexes, the two phosphine ligands are crystallographically equivalent; thus, the two (31)P nuclei have identical isotropic chemical shifts. Under rapid sample spinning conditions, the (31)P MAS NMR spectra exhibit relatively sharp overlapping asymmetric quartets arising from (1)J((63/65)Cu,(31)P) and residual (63/65)Cu-(31)P dipolar interactions. No evidence of (2)J((31)P,(31)P) is apparent from the spectra obtained with rapid MAS; however, under slow MAS conditions there is evidence of homonuclear J-recoupling. Peak broadening due to heteronuclear dipolar interactions precludes measurement of (2)J((31)P,(31)P) from standard 1D (31)P MAS NMR spectra. It is shown that this source of broadening can be effectively eliminated by employing the 2D J-resolved experiment. For the two copper(I) phosphine complexes investigated in this study, the peak widths in the f(1) dimension of the 2D J-resolved (31)P MAS NMR spectra are about three times narrower than those found in the corresponding 1D (31)P MAS NMR spectra. 相似文献