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61.
A fused silica capillary column was packed with RP(18) silica stationary phase entrapping the particles between two frits obtained by two different procedures. The inlet frit consisted of a short organic polymer made via a thermopolymerization process while the outlet frit was prepared by sintering the octadecylsilica (ODS) material. The packed column was employed in capillary electrochromatography (CEC) experiments for the separation of three selected test compounds. Retention time and separation efficiency were evaluated. Results were compared with those ones obtained with a packed capillary containing the same stationary phase entrapped between two sinterized frits. The novel packed column exhibited comparable separation efficiency and resolution with the traditional one. However, it allowed experiments without pressure support during the runs with no bubble formation. 相似文献
62.
Maurizio DAuria Lucia Emanuele Rocco Racioppi Vincenzina Velluzzi 《Journal of photochemistry and photobiology. A, Chemistry》2008,198(2-3):156-161
The fate of the crude oil under irradiation was studied. After the UV irradiation, the fraction present in the highest percentage shifted from C8–C9 fraction to C13 one, in GC–MS analysis. An increase of the relative amount of the C13–C25 fraction was observed, while a decrease in the relative amount of the C7–C12 fractions was present. The synchronous fluorescence spectrum showed a maximum at 396 nm. Two hours irradiation of the sample induced an increase of the fluorescence emission in the region 420–550 nm. After 20, 40, 60, and 100 h irradiation we observed a decrease of the fluorescence emission. 相似文献
63.
Florica Corina Cîrstea Cristina Trombetti 《Calculus of Variations and Partial Differential Equations》2008,31(2):167-186
We consider the Monge–Ampère equation det D 2 u = b(x)f(u) > 0 in Ω, subject to the singular boundary condition u = ∞ on ?Ω. We assume that \(b\in C^\infty(\overline{\Omega})\) is positive in Ω and non-negative on ?Ω. Under suitable conditions on f, we establish the existence of positive strictly convex solutions if Ω is a smooth strictly convex, bounded domain in \({\mathbb R}^N\) with N ≥ 2. We give asymptotic estimates of the behaviour of such solutions near ?Ω and a uniqueness result when the variation of f at ∞ is regular of index q greater than N (that is, \(\lim_{u\to \infty} f(\lambda u)/f(u)=\lambda^q\) , for every λ > 0). Using regular variation theory, we treat both cases: b > 0 on ?Ω and \(b\equiv 0\) on ?Ω. 相似文献
64.
Vanderah DJ Walker ML Rocco MA Rubinson KA 《Langmuir : the ACS journal of surfaces and colloids》2008,24(3):826-829
Self-assembled monolayers (SAMs) of the disulfide [S(CH2CH2O)6CH3]2 ([S(EO)6]2) on Au from 95% ethanol and from 100% water are described. Spectroscopic ellipsometry and reflection-absorption infrared spectroscopy indicate that the [S(EO)6]2 films are similar to the disordered films of HS(CH2CH2O)6CH3 ((EO)6) and HS(CH2)3O(CH2CH2O)5CH3 (C3EO5) at their protein adsorption minima. The [S(EO)6]2 SAMs exhibit constant film thickness (d) of 1.2 +/- 0.2 nm over long immersion times (up to 20 days) and do not attain the highly ordered, 7/2 helical structure of the (EO)6 and C3EO5 SAMs (d = 2.0 nm). Exposure of these self-limiting [S(EO)6]2 SAMs to bovine serum albumin show high resistance to protein adsorption. 相似文献
65.
66.
We describe some simple changes to the geometry of the IPG strips that make them suitable to the loading of very large sample volumes and of high-salt solutions. Of special relevance is the possibility of using strips with immobilized plateau(s) to either side of the gradient, or to both, also in connection with in-gel rehydration protocols and focusing in stock trays. The only requirement to achieve this is to leave the all-ready-made attitude and go back to custom polymerization of the IPGs in one's laboratory. 相似文献
67.
Birkholz MN Dubrovina NV Jiao H Michalik D Holz J Paciello R Breit B Börner A 《Chemistry (Weinheim an der Bergstrasse, Germany)》2007,13(20):5896-5907
Three sets of new and related chiral phospholane and phosphepine ligands have been prepared for Rh-catalyzed enantioselective hydrogenation. The size and substitution pattern of the cyclic monophosphanes were varied. More importantly, the ligands differ in the nature of the heterocyclic group linked to the trivalent phosphorus atom: 2-pyridone or 2-alkoxypyridine. In the corresponding Rh complexes, the pyridone units of two monodentate P ligands can assemble by hydrogen bonding and form chelates. In contrast, synthetic precursors bearing alkoxypyridine appendages are not able to aggregate via intramolecular hydrogen bonds. The nature of self-assembly is dependent on the nature of the P ligand and the solvent used for the hydrogenation (CH2Cl2 vs. MeOH). These features affect the rate of the reaction as well as the enantioselectivity, which varied in the range of 0-99 % ee Complexation studies and DFT calculations were performed to explain these differences. 相似文献
68.
Castelli F Sarpietro MG Rocco F Ceruti M Cattel L 《Journal of colloid and interface science》2007,313(1):363-368
The stability and bioavailability of anticancer agents, such as gemcitabine, can be increased by forming prodrugs. Gemcitabine is rapidly deaminated to the inactive metabolite (2('),2(')-difluorodeoxyuridine), thus to improve its stability a series of increasingly lipophilic gemcitabine prodrugs linked through the 4-amino group to valeroyl, lauroyl, and stearoyl acyl chains were synthesized. Studies of monolayer properties are important to improve understanding of biological phenomena involving lipid/gemcitabine or lipid/gemcitabine derivative interactions. The interfacial behavior of monolayers constituted by DMPC plus gemcitabine or lipophilic gemcitabine prodrugs at increasing molar fractions was studied at the air/water interface at temperatures below (10 degrees C) and above (37 degrees C) the lipid phase transition. The effect of the hydrophobic chain length of gemcitabine derivatives on the isotherm of pure DMPC was investigated by surface tension measurement, and the results are reported as molar fractions as a function of mean molecular area per molecule. The results show that the compounds interact with DMPC producing mixed monolayers that are subject to an expansion effect, depending on the prodrug chain length. The results give useful hints of the interaction of these prodrugs with biological membranes and increase knowledge on the incorporation site of such compounds, as a function of their lipophilicity, in a lipid carrier; they may lead to improved liposomal formulation design. 相似文献
69.
Sandra Di Rocco 《Mathematische Zeitschrift》1999,231(1):169-188
The notion of a k-convex -support function for a toric variety is introduced. A criterion for a line bundle L to generate k-jets on X is given in terms of the k-convexity of the -support function . Equivalently L is proved to be k-jet ample if and only if the restriction to each invariant curve has degree at least k.
Received October 22, 1997; in final form January 12, 1998 相似文献
70.
G. Fischfeld A. Affranchino A. Di Loreto C. Rocco 《Crystal Research and Technology》2004,39(10):920-925
The results obtained for the r63 electro‐optic coefficient of B‐doped and undoped KDP (KH2PO4) crystals irradiated with neutrons (including thermalized neutrons) produced by scattering of 30 Mev cyclotron protons on a target of Ta201, are presented and compared to those obtained for non‐irradiated doped and undoped crystals. The B‐doped (H3BO3, Na2B4O7 and Li2B4O7) crystals were obtained by the conventional growth method by temperature decrease with 1 wt % dopant concentration in solution. The thermal neutron flux was around ϕ = 1. 1010 n/cm2 s. Pulses of ∼15 μs long, in damped oscillatory mode (V= 8 kV, τ=1.95 μs) were used for the electro‐optic measurements. A Pockels cell, a photomultiplier, a He‐Ne laser (λ=632.8 nm, 5 mW, linearly polarized) and a Tk 720 A oscilloscope complete the experimental setup. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献