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21.
H. O. Di Rocco 《光谱学快报》2013,46(8):1019-1023
A comprehensive study of Xe II line shifts (after considering more than 900 transitions) provides the basis for establishing a simple empirical linear relation between the shifts and the inverse of the ionization potential for the er level. 相似文献
22.
Sandra di Rocco 《Mathematische Nachrichten》1996,179(1):47-56
A k-very ample line bundle L on a Del Pezzo Surface is numerically characterized, improving the results of Biancofiore— Ceresa in [7]. 相似文献
23.
24.
A prototype calix[4]arene-based receptor for carbohydrate recognition containing peptide and phosphate binding groups 总被引:2,自引:0,他引:2
Segura M Bricoli B Casnati A Muñoz EM Sansone F Ungaro R Vicent C 《The Journal of organic chemistry》2003,68(16):6296-6303
A novel class of macrobicyclic receptors for carbohydrate recognition based on upper rim, peptide-bridged calix[4]arenes has been designed and synthesized. Receptor 12, in which a charged phosphate group cooperates with peptide hydrogen-bonding donor and acceptor groups in the binding process, is the most efficient and selective in the complexation of simple carbohydrate derivatives. The selectivity observed is toward beta-glucoside 13a, which is better bound (DeltaG degrees = 19.6 kJ mol(-)(1)) compared to the corresponding alpha anomer 13b (DeltaG degrees = 17.0 kJ mol(-)(1)) and to the beta-galactoside 13c (DeltaG degrees = 17.7 kJ mol(-)(1)) in CDCl(3). A substantial drop in the stability constant is observed by esterification of the phosphate group in the host 12 or by alkylation of the OH groups in the 2 and 3 positions in the beta-glucoside and beta-galactoside derivatives. On the basis of a careful analysis of the (1)H NMR data available, a binding mode of the beta-octylglucoside 13a to receptor 12 is proposed. 相似文献
25.
H. O. Di Rocco 《Il Nuovo Cimento D》1990,12(11):1485-1490
Summary The shifts and widths of prominent XeII transitions are calculated in the semi-empirical approach; a very good agreement with
experimental values is obtained. The oscillator strengths were calculated using complete intermediate coefficients after energy
matrix diagonalization.
The author of this paper has agreed to not receive the proofs for correction. 相似文献
26.
A high transmission spherical electrostatic electron spectrometer for Mössbauer conversion electron spectroscopy was built. Depth selective Mössbauer studies can be carried out from T=4 K to 350 K in a 10?8 Torr vacuum changing the electron energies and/or the electron escape angles. 相似文献
27.
Rocco Angelone Dr. Francesco Ciardelli Prof. Arturo Colligiani Prof. Francesco Greco Dr. Paolo Masi Prof. Annalisa Romano Dr. Giacomo Ruggeri Prof. 《Chemphyschem》2010,11(2):460-465
A derivative of 2‐methylindole, 3‐[2‐(4‐nitrophenyl)ethenyl]‐1‐allyl‐2‐methylindole, NPEMI‐A, is studied for its photoconductivity and photorefractivity behaviour. Its blends with the organic polymer poly‐(2,3‐dimethyl‐N‐vinylindole), PVDMI, are also investigated. Due to the expected and devised mutual solubility of the two components of the blends, it is possible to carry out measurements with the weight percent of the chromophore NPEMI‐A changing from zero to 100. Films were produced by a squeezing process between two ITO‐covered glass sheets. No opacity phenomena, that are so common for many other organic blends due to the segregation of the dissolved chromophore, are observed. The photorefractive optical gain Γ2 is obtained as a function of the chromophore content. Differential scanning calorimetry measurements (DSC) are also carried out to obtain the whole change of the glass transition temperature Tg as a function of the amount of chromophore contained in the blends. From the experimental trend of Tg a meaningful quantitative estimate of the value of the electrostatic interactions acting in the studied blends, is obtained. The importance of the value of Tg, and of the electrostatic interactions, in determining the extent of the photorefractivity is clearly evident. The results are compared for NPEMI‐A (Γ2=210 cm?1) and for NPEMI‐E (Γ2 ≈ 2000 cm?1) that has a N‐2‐ethylhexyl group instead of a N‐allyl group. The Pockels and Kerr contributions and—for the first time—a “collaborative effect” of the photorefractivity of NPEMI‐A are distinguished and quantitatively evaluated. 相似文献
28.
H.O. Di Rocco D.I. Iriarte J.A. Pomarico H.F. Ranea Sandoval R. Macdonald 《Journal of Quantitative Spectroscopy & Radiative Transfer》2007,105(1):68-83
In this work we present a method for determining the optical parameters of turbid media, namely its absorption coefficient (μa) and its reduced scattering coefficient . It is based on the measurement of CW transmittance profiles and analysis of the experimental data by a theoretical model based on the diffusion approximation (DA) of the radiative transfer equation (RTE). The method developed has been investigated with solid polymer probes but it could be applied for liquid materials as well. Experimental results are presented and compared to those of other authors together with a discussion about the accuracy of measurements. In addition, measurements using integrating spheres as well as Monte Carlo simulations are also presented to validate these results. 相似文献
29.
The purpose of this note is to study initial sequences of 0–dimensional subschemes of Hirzebruch surfaces and classify subschemes whose initial sequence has the minimal possible growth. 相似文献
30.
Arnesano F Belviso BD Caliandro R Falini G Fermani S Natile G Siliqi D 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(5):1569-1578
The metal-binding ability of human ubiquitin (hUb) towards a selection of biologically relevant metal ions and complexes has been probed. Different techniques have been used to obtain crystals suitable for crystallographic analysis. In the first type of experiments, crystals of hUb have been soaked in solutions containing copper(II) acetate and two metallodrugs, Zeise salt (K[PtCl(3)(η(2)-C(2)H(4))]·H(2)O) and cisplatin (cis-[PtCl(2)(NH(3))(2)]). The Zeise salt is used in a test for hepatitis, whereas cisplatin is one of the most powerful anticancer drugs in clinical use. The Zeise salt readily reacts with hUb crystals to afford an adduct with three platinum residues per protein molecule, Pt(3)-hUb. In contrast, copper(II) acetate and cisplatin were found to be unreactive for contact times up to one hour and to cause degradation of the hUb crystals for longer times. In the second type of experiments, hUb was cocrystallized with a solution of copper(II) or zinc(II) acetate or cisplatin. Zinc(II) acetate gives, at low metal-to-protein molar ratios (8:1), crystals containing one metal ion per three molecules of protein, Zn-hUb(3) (already reported in previous work), whereas at high metal-to-protein ratios (70:1) gives crystals containing three Zn(II) ions per protein molecule, Zn(3)-hUb. In contrast, once again, copper(II) acetate and cisplatin, even at low metal-to-protein ratios, do not give crystalline material. In the soaking experiment, the Zeise anion leads to simultaneous platination of His68, Met1, and Lys6. Present and previous results of cocrystallization experiments performed with Zn(II) and other Group 12 metal ions allow a comprehensive understanding of the metal-ion binding properties of hUb with His68 as the main anchoring site, followed by Met1 and carboxylic groups of Glu16, Glu18, Glu64, Asp21, and Asp32, to be reached. In the case of platinum, Lys6 can also be a binding site. The amount of bound metal ion, with respect to that of the protein, appears to be a relevant parameter influencing crystal packing. 相似文献