Meromorphic Traveling Wave Solutions of the Complex Cubic-Quintic Ginzburg-Landau Equation

We look for singlevalued solutions of the squared modulus M of the traveling wave reduction of the complex cubic-quintic Ginzburg-Landau equation. Using Clunie??s lemma, we first prove that any meromorphic solution M is necessarily elliptic or degenerate elliptic. We then give the two canonical decompositions of the new elliptic solution recently obtained by the subequation method.     

Separable geodesic action slicing in stationary spacetimes

A simple observation about the action for geodesics in a stationary spacetime with separable geodesic equations leads to a natural class of slicings of that spacetime whose orthogonal geodesic trajectories represent the world lines of freely falling fiducial observers. The time coordinate function can then be taken to be the observer proper time, leading to a unit lapse function, although the time coordinate lines still follow Killing trajectories to retain the explicitly stationary nature of the coordinate grid. This explains some of the properties of the original Painlevé-Gullstrand coordinates on the Schwarzschild spacetime and their generalization to the Kerr-Newman family of spacetimes, reproducible also locally for the Gödel spacetime. For the static spherically symmetric case the slicing can be chosen to be intrinsically flat with spherically symmetric geodesic observers, leaving all the gravitational field information in the shift vector field.     

Fibrous Networks with Incorporated Macrocycles: A Chiral Stimuli‐Responsive Supramolecular Supergelator and Its Application to Biocatalysis in Organic Media

A new and versatile, crown ether appended, chiral supergelator has been designed and synthesized based on the bis‐urea motif. The introduction of a stereogenic center improved its gelation ability significantly relative to its achiral analogue. This low‐molecular‐weight gelator forms supramolecular gels in a variety of organic solvents. It is sensitive to multiple chemical stimuli and the sol–gel phase transitions can be reversibly triggered by host–guest interactions. The gel can be used to trap enzymes and release them on demand by chemical stimuli. It stabilizes the microparticles in Pickering emulsions so that enzyme‐catalyzed organic reactions can take place in the polar phase inside the microparticles, the organic reactants diffusing through the biphasic interface from the surrounding organic phase. Because of the higher interface area between the organic and polar phases, enzyme activity is enhanced in comparison with simple biphasic systems.     

Suppressing one‐bond homonuclear 13C,13C scalar couplings in the J‐HMBC NMR experiment: application to 13C site‐specifically labeled oligosaccharides

Site‐specific ¹³C isotope labeling is a useful approach that allows for the measurement of homonuclear ¹³C,¹³C coupling constants. For three site‐specifically labeled oligosaccharides, it is demonstrated that using the J‐HMBC experiment for measuring heteronuclear long‐range coupling constants is problematical for the carbons adjacent to the spin label. By incorporating either a selective inversion pulse or a constant‐time element in the pulse sequence, the interference from one‐bond ¹³C,¹³C scalar couplings is suppressed, allowing the coupling constants of interest to be measured without complications. Experimental spectra are compared with spectra of a nonlabeled compound as well as with simulated spectra. The work extends the use of the J‐HMBC experiments to site‐specifically labeled molecules, thereby increasing the number of coupling constants that can be obtained from a single preparation of a molecule. Copyright © 2014 John Wiley & Sons, Ltd.     

A generic framework for time-stepping partial differential equations (PDEs): general linear methods,object-oriented implementation and application to fluid problems

Time-stepping algorithms and their implementations are a critical component within the solution of time-dependent partial differential equations (PDEs). In this article, we present a generic framework – both in terms of algorithms and implementations – that allows an almost seamless switch between various explicit, implicit and implicit–explicit (IMEX) time-stepping methods. We put particular emphasis on how to incorporate time-dependent boundary conditions, an issue that goes beyond classical ODE theory but which plays an important role in the time-stepping of the PDEs arising in computational fluid dynamics. Our algorithm is based upon J.C. Butcher's unifying concept of general linear methods that we have extended to accommodate the family of IMEX schemes that are often used in engineering practice. In the article, we discuss design considerations and present an object-oriented implementation. Finally, we illustrate the use of the framework by applications to a model problem as well as to more complex fluid problems.     

An α-Lactam as an Alkilating Agent

The ‘normal’ reaction of α-lactams (aziridinones) is mcleophilic ring ening,¹ which can occur with fission of either one of the three bonds (a-b-c), depending on the reagent, to yield and acyclic addition prodnct (I,II,III).²