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Polarized light leads to an effective reorientation of the optic axis in the glassy state of liquid-crystalline side chain polymers containing azobenzene mesogenic groups, via a trans-cis and cis-trans isomerization. Using a combination of U V and IR dichroitic studies it is shown for copolymers consisting of chromophores (azobenzene) and non-chromophores (phenylbenzoate) that only the chromophores are reoriented by light as far as the glassy state is concerned. Individual chromophores are thus addressed by photoselection. Photoselection in the fluid nematic state, on the other hand, leads also to a reorientation of the non-chromophores.  相似文献   
23.
Recent studies have established that side chain polymeric liquid crystals composed of mesogenic and non-mesogenic side groups keep their liquid-crystalline properties even for a low proportion of mesogens. We show that the detailed structures of three kinds of new diluted liquid crystal polysiloxanes depend on the nature of the co-substituent as well as on the proportion of the silicon sites occupied by the mesogenic groups. Mixtures of these systems with low molar mass liquid crystals were also investigated in terms of compatibility and/or stabilization of smectic A phases.  相似文献   
24.
Network location problems occur when new facilities must be located on a network, and the network distances between new and existing facilities are important. In urban, regional, or geographic contexts, there may be hundreds of thousands (or more) of existing facilities, in which case it is common to aggregate existing facilities, e.g. represent all the existing facility locations in a zip code area by a centroid. This aggregation makes the size of the problem more manageable for data collection and data processing purposes, as well as for purposes of analysis; at the same time, it introduces errors, and results in an approximating location problem being solved. There seems to be relatively little theory for doing aggregation, or evaluating the results of aggregation; most approaches are based on experimentation or computational studies. We propose a theory that has the potential to improve the means available for doing aggregation.This research was supported in part by the National Science Foundation, Grant No. DDM-9023392.  相似文献   
25.
We define and analyze anM/G/1/N vacation model that uses a service discipline that we call theE-limited with limit variation discipline. According to this discipline, the server provides service until either the system is emptied (i.e. exhausted) or a randomly chosen limit ofl customers has been served. The server then goes on a vacation before returning to service the queue again. The queue length distribution and the Laplace-Stieltjes transforms of the waiting time, busy period and cycle time distributions are found. Further, an expression for the mean waiting time is developed. Several previously analyzed service disciplines, including Bernoulli scheduling, nonexhaustive service and limited service, are special cases of the general varying limit discipline that is analyzed in this paper.  相似文献   
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The effects of imaging-gas hyperpolarisability and field-gradient polarisabuity terms on field-adsorption binding energies have been explored. At best image fields for the noble imaging gases and molecular hydrogen, the correction to long-range binding energy is at most a few percent and may be neglected. At the tungsten evaporation field the correction is significant in the cases of Ar, Kr, H2, and especially Xe. The system He on W(111) has been used as a paradigm in the investigation of short-range binding energy. The largest correction here is due to one of the field-gradient polarisabuity terms. In the field range of most relevance to the field-ion techniques the total correction is about 15–20%, and should not be neglected in detailed treatments.  相似文献   
28.
This paper presents the design and test of asymmetric quasioptical resonators for gyrotron applications, where most of the diffraction output coupling comes from the smaller of two mirrors. A computer code based on scalar diffraction theory is used to calculate the resonator losses and the electric field near the mirrors. Resonators with mirror separations approaching confocal have reduced side lobes in the diffraction patterns, which should allow for better power transmission and focusing. Cold tests have been performed at 94 and 141 GHz to measure the quality factor of the asymmetric resonators as a function of mirror separation and mirror misalignment. Typical resonator parameters include 65 cm mirror separation, 1-3% output coupling and 85% of the losses from the small mirror. A half-symmetric resonator with one flat and one curved mirror has also been investigated. The calculated values of Q are in reasonably good agreement with the cold test measurements.  相似文献   
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For a given n-by-n matrix A, we consider the set of matrices which commute with A and all of whose principal submatrices commute with the corresponding principal submatrices of A. The properties of this set are examined, with particular attention to its dimension.  相似文献   
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