水杨醛类希夫碱在LB膜上的光谱性能的研究

合成了两种末端碳锭长度不同的水杨醛类希夫碱N-十二烷基（2-羟基-5-硝基苯甲亚胺）和N-十六烷基（2-羟基-5-硝基苯甲亚胺），研究了它们在气-液界面上的成膜性能，并通过紫外、荧光、红外显微镜等光谱手段对它们在LB膜上的性能进行了表征。实验结果表明两种希夫碱分子在LB膜中都形成了J-聚体，末端碳链较长的希夫碱 成膜性能相对较好，并且在膜上也能光致发光，但希夫碱分子的LB膜存在一定的缺陷。     

混沌动力学方法在等离子体尾迹流场研究中的应用

用混沌动力学方法对多道扫描静电探针的离子饱和电流信号进行分析,研究了等离子体尾迹流场.通过对相关维、Renyi熵和最大Lyapunov指数的分析,得到了近尾流场的分层结构.利用最大Lyapunov指数,观测到了在x>10D以后的远尾流场与自由流场相似.结合探针信号的自相关函数,研究流场湍流结构,发现近尾可能存在大涡拟序结构,而在远尾则没有湍流.观察到了流场具有一定的间歇特征,认为这种间歇性与湍流有关.结果还表明,混沌动力学的分析方法对信号中非周期成分十分敏感,在研究等离子体尾迹流场这一类非线性系统时,它具有明显的优越性 关键词： 混沌动力学 尾迹 等离子体湍流 静电探针     

低温胁迫下香蕉叶片Chla荧光动力学参量的变化及其品种差异性

低温胁迫下,广东2号香蕉品种和巴西香蕉品种Williams的叶绿素(Chla)荧光动力学参量F_Ⅴ/F_m、ΔF_Ⅴ/F_T以及williams品种的F_IV/F_Ⅴ均呈下降趋势,两个品种的荧光上升半时间T_1/2及广东2号的F_IV/F_Ⅴ呈上升趋势.其中,Williams的F_Ⅴ/F_m、ΔF_Ⅴ/F_T和T_1/2的变化幅度小于广东2号,表明低温胁迫通过抑制光合电子传递速度和PSⅡ无活性中心含量的提高使香蕉叶片PSⅡ原初光能转换效率下降,相同低温对广东2号的影响大于对Williams的影响.F_Ⅴ/F_m和ΔF_Ⅴ/F_T可以作为评价香蕉幼苗抗冷性的物理指标.     

Tunable local surface plasmon resonance in liquid-crystal-coated Ag nanoparticles

The far-field and near-field properties of a spherical nematic liquid crystal (NLC) coated metal nanoparticle (NPs) have been investigated in an external field, basing on the quasistatic theory. The resonant wavelength is tunable by varying metallic material of core, anisotropy extent and thickness of liquid crystals (LCs). The field enhancement is along the incident polarization near the outer surface of the shell. The direction of field is reverse in the inner surface comparing with the one if outer shell. In contrast to isotropy shell, the surface plasmon resonance (SPR) shows an obvious red shift and field enhancement near outer surface of the shell always is stronger.     

Supercapacitive electrochemical performance of graphene-containing carbon aerogel prepared using polyethyleneimine-modified graphene oxide

Graphene-containing carbon aerogel was prepared by a sol–gel polymerization of resorcinol-formaldehyde (RF) method using polyethyleneimine (PEI)-modified chemically exfoliated grapheme oxide, and its electrochemical performance as an electrode for supercapacitor was examined. The effect of PEI in the preparation of RFGO (resorcinol-formaldehyde and graphene oxide) solution on the physicochemical and electrochemical properties of graphene-containing carbon aerogel (CAPG) was investigated. For comparison, graphene-containing carbon aerogel was prepared using PEI-free graphene oxide (CAG). Graphene-free carbon aerogel (CA) was also prepared. CAPG showed the highest BET surface area (792 m²/g) and the largest pore volume (1.64 cm³/g) with well-developed porous structure. Various electrochemical measurements revealed that CAPG showed high specific capacitance (205 F/g), low equivalent series resistance (0.55 Ω), and superior capacitive behavior. The PEI-modified graphene oxide played an important role in enhancing physicochemical properties and supercapacitive electrochemical performance of CAPG.     

Fabrication of textured KNNT ceramics by reactive template grain growth using NN templates

Lead-free non-stoichiometric (K_0.470Na_0.545)(Nb_0.55Ta_0.45)O₃ (KNNT) textured ceramics were prepared by a reactive templated grain growth method using NaNbO₃ (NN) templates. The Plate-like NaNbO₃ (NN) templates were synthesized from bismuth layer-structured Bi_2.5Na_3.5Nb₅O₁₈ (BNN) particles by a topochemical microcrystal conversion (TMC) method. Using 5 wt% of NN templates, textured KNNT ceramics were fabricated, and their crystal structure, microstructure, dielectric and piezoelectric properties were compared with non-textured KNNT ceramics prepared by a conventional solid state reaction method. The textured KNNT ceramics exhibited high grain orientation and high dielectric constant. In addition, piezoelectric properties of textured KNNT ceramics were improved, giving a high piezoelectric coefficient d₃₃ = 390 pC/N and piezoelectric coupling coefficient k_p = 0.60.     

Ordinary dislocation configurations in high Nb-containing TiAl alloy deformed at high temperatures

Abstract

High Nb-containing TiAl (Nb–TiAl) alloys possess mechanical properties at elevated temperatures superior to conventional TiAl alloys. However, the strengthening mechanisms induced by Nb addition have been discussed controversial for a long time. In the present study, the dislocation structures in a polycrystalline high Nb–TiAl alloy after tensile tests at 700 and 900 °C were investigated by transmission electron microscope (TEM) observation. The results show that abundant double cross slip of ordinary dislocations is activated in the samples deformed at 700 °C. The dislocations are pinned at the jogs and numerous dipoles are observed. Debris can be commonly observed in the vicinity of screw dislocations. Trace analysis shows that the cross-slip plane is (1?1?0)γ at 700 °C but (1?1?1)γ octahedral plane at 900 °C. Three-dimensional (3D) dislocation structures, caused by cross-slip and annihilation of ordinary dislocations, were observed along the screw orientation. The dipoles and debris produced by high-temperature cross slip can be important for the strengthening of high Nb–TiAl alloys.     

Numerical ray-tracing approach with laser intensity distribution for LIDAR signal power function computation

We have developed a new numerical ray-tracing approach for LIDAR signal power function computation, in which the light round-trip propagation is analyzed by geometrical optics and a simple experiment is employed to acquire the laser intensity distribution. It is relatively more accurate and flexible than previous methods. We emphatically discuss the relationship between the inclined angle and the dynamic range of detector output signal in biaxial LIDAR system. Results indicate that an appropriate negative angle can compress the signal dynamic range. This technique has been successfully proved by comparison with real measurements.     

Responsive mechanism of 2-(2'-hydroxyphenyl)benzoxazole-based two-photon fluorescent probes for zinc and hydroxide ions

Response theory is used to investigate one- and two-photon absorption(TPA) as well as the emission properties of a series of potential zinc ion and pH sensitive materials containing 2-(2’-hydroxyphenyl)benzoxazole(HPBO) end groups.Special emphasis is placed on the evolution of their optical properties upon combining with zinc ions or deprotonation.Our calculated results indicate that upon combining with zinc ions or deprotonation,these HPBO derivatives show drastic changes in their one-photon absorption(OPA),emission,and TPA properties.Moreover,the mechanisms of the probes are analyzed and found to be an intramolecular charge transfer.These compounds are thus proved to be excellent candidates for two-photon fluorescent zinc and pH probes.