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排序方式: 共有329条查询结果,搜索用时 31 毫秒
51.
Roberts CC Rao RR Loewenberg M Brooks CF Galambos P Grillet AM Nemer MB 《Lab on a chip》2012,12(8):1540-1547
A thin flow-focusing microfluidic channel is evaluated for generating monodisperse liquid droplets. The microfluidic device is used in its native state, which is hydrophilic, or treated with OTS to make it hydrophobic. Having both hydrophilic and hydrophobic surfaces allows for creation of both oil-in-water and water-in-oil emulsions, facilitating a large parameter study of viscosity ratios (droplet fluid/continuous fluid) ranging from 0.05 to 96 and flow rate ratios (droplet fluid/continuous fluid) ranging from 0.01 to 2 in one geometry. The hydrophilic chip provides a partially-wetting surface (contact angle less than 90°) for the inner fluid. This surface, combined with the unusually thin channel height, promotes a flow regime where the inner fluid wets the top and bottom of the channel in the orifice and a stable jet is formed. Through confocal microscopy, this fluid stabilization is shown to be highly influenced by the contact angle of the liquids in the channel. Non-wetting jets undergo breakup and produce drops when the jet is comparable to or smaller than the channel thickness. In contrast, partially-wetting jets undergo breakup only when they are much smaller than the channel thickness. Drop sizes are found to scale with a modified capillary number based on the total flow rate regardless of wetting behavior. 相似文献
52.
Mn inclusion in the oxide based diluted magnetic semiconductor Zn1−x
Mn
x
O (x = 0.04, 0.06, 0.08, and 0.10) grown by standard high temperature solid state reaction technique has been studied. The local
and average structure of Zn1−x
Mn
x
O was characterized by the super resolution technique maximum entropy method and pair distribution function analysis using
the X-ray powder data. Magnetic studies on this material using a Vibrating Sample Magnetometer were also carried out to ascertain
the doping level in Zn1−x
Mn
x
O. 相似文献
53.
C. V. Durgadas C. P. Sharma W. Paul M. R. Rekha K. Sreenivasan 《Journal of nanoparticle research》2012,14(9):1-12
A certified reference material, ERM-FD100, for quality assurance and validation of various nanoparticle sizing methods, was developed by the Institute for Reference Materials and Measurements. The material was prepared from an industrially sourced colloidal silica containing nanoparticles with a nominal equivalent spherical diameter of 20?nm. The homogeneity and stability of the candidate reference material was assessed by means of dynamic light scattering and centrifugal liquid sedimentation. Certification of the candidate reference material was based on a global interlaboratory comparison in which 34 laboratories participated with various analytical methods (DLS, CLS, EM, SAXS, ELS). After scrutinising the interlaboratory comparison data, 4 different certified particle size values, specific for the corresponding analytical method, could be assigned. The good comparability of results allowed the certification of the colloidal silica material for nanoparticle size analysis. 相似文献
54.
A heated semiconductor light-emitting diode at low forward bias voltage V相似文献
55.
R. K. Kotnala Rekha Gupta Jyoti Shah M. Abdullah Dar 《Journal of Sol-Gel Science and Technology》2012,64(1):149-155
Nano-crystals of Li0.35Zn0.3Fe2.35O4 ferrite have been synthesized using citrate precursor method. The sample synthesized was sintered at different temperatures in order to vary their crystallite size. The average crystallite size was found in the range 24?C57?nm by varying the temperature from 300 to 1,100?°C. X-ray diffraction measurements confirmed the formation of cubic spinel structure at all the sintering temperatures in this work. The high frequency performance of the ferrite samples were estimated by measuring the frequency dispersion of the dielectric constant, dielectric loss and ac electrical conductivity. The dielectric constant has been observed to show normal behavior with frequency and decreases with the decrease in crystallite size. It is also observed that decrease in dielectric constant depends on sintering temperature because of lithium evaporation at higher temperature. A low value of dielectric constant and dielectric loss has been found, which makes them applicable for high frequency applications by decreasing the skin effect. The impedance spectroscopy technique has been used to study the effect of grain and grain boundary on the electrical properties of Li0.35Zn0.3Fe2.35O4 ferrite. The analysis of data shows only one semi-circle corresponding to the grain boundary volume suggesting that the conduction mechanism takes place predominantly through grain boundary volume in the prepared samples. 相似文献
56.
Nagappanpillai Adarsh Madhesh Shanmugasundaram Dr. Rekha R. Avirah Dr. Danaboyina Ramaiah 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(40):12655-12662
A new series of aza‐BODIPY derivatives ( 4 a – 4 c , 5 a , c , and 6 b , c ) were synthesized and their excited‐state properties, such as their triplet excited state and the yield of singlet‐oxygen generation, were tuned by substituting with heavy atoms, such as bromine and iodine. The effect of substitution has been studied in detail by varying the position of halogenation. The core‐substituted dyes showed high yields of the triplet excited state and high efficiencies of singlet‐oxygen generation when compared to the peripheral‐substituted systems. The dye 6 c , which was substituted with six iodine atoms on the core and peripheral phenyl ring, showed the highest quantum yields of the triplet excited state (ΦT=0.86) and of the efficiency of singlet‐oxygen generation (ΦΔ=0.80). Interestingly, these dyes were highly efficient as photooxygenation catalysts under artificial light, as well as under normal sunlight conditions. The uniqueness of these aza‐BODIPY systems is that they are stable under irradiation conditions, possess strong red‐light absorption (620–680 nm), exhibit high yields of singlet‐oxygen generation, and act as efficient and sustainable catalysts for photooxygenation reactions. 相似文献
57.
B.J. Hwang R. Santhanam C.R. Wu Y.W. Tsai 《Journal of Solid State Electrochemistry》2001,5(4):280-286
In this work, the nucleation and growth mechanism for the electropolymerization of aniline was investigated at higher potentials
on highly oriented pyrolytic graphite by potentiostatic current-time transient and atomic force microscopic (AFM) measurements.
The electrochemical data fitted to the theoretical curves for the nucleation and growth suggest that electropolymerization
of aniline follows the three-dimensional growth and progressive nucleation mechanism. These results were also compared with
the results obtained at lower potentials. The results obtained from transient analysis, at higher potentials, were in good
agreement with the results of AFM images.
Electronic Publication 相似文献
58.
Joe Willis Ivona Bravi Rekha R. Schnepf Karen N. Heinselman Bartomeu Monserrat Thomas Unold Andriy Zakutayev David O. Scanlon Andrea Crovetto 《Chemical science》2022,13(20):5872
Phosphides are interesting candidates for hole transport materials and p-type transparent conducting applications, capable of achieving greater valence band dispersion than their oxide counterparts due to the higher lying energy and increased size of the P 3p orbital. After computational identification of the indirect-gap semiconductor CaCuP as a promising candidate, we now report reactive sputter deposition of phase-pure p-type CaCuP thin films. Their intrinsic hole concentration and hole mobility exceed 1 × 1020 cm−3 and 35 cm2 V−1 s−1 at room temperature, respectively. Transport calculations indicate potential for even higher mobilities. Copper vacancies are identified as the main source of conductivity, displaying markedly different behaviour compared to typical p-type transparent conductors, leading to improved electronic properties. The optical transparency of CaCuP films is lower than expected from first principles calculations of phonon-mediated indirect transitions. This discrepancy could be partly attributed to crystalline imperfections within the films, increasing the strength of indirect transitions. We determine the transparent conductor figure of merit of CaCuP films as a function of composition, revealing links between stoichiometry, crystalline quality, and opto-electronic properties. These findings provide a promising initial assessment of the viability of CaCuP as a p-type transparent contact.We synthesize air-stable, p-type CaCuP thin films with high hole concentration and high hole mobility as potential p-type transparent conductors. We study their optoelectronic properties in detail by advanced experimental and computational methods. 相似文献
59.
Journal of Thermal Analysis and Calorimetry - Energetic and exergetic performance for an automotive radiator with wavy fin configuration has been investigated and compared for water-based 1% vol.... 相似文献
60.
The high/low amplitude anisotropic wave-train events (HAE/LAE) in cosmic-ray intensity have been investigated during the period 1991-94, using the neutron monitor data for different latitudes. In all, 16 HAE and 13 LAE cases have been studied. An inter-comparison of the first three harmonics during these events has been made so as to understand the basic reason causing the occurrence of these types of events. It has been observed that the phase of diurnal anisotropy shifts towards earlier hours for HAEs; similarly, it shifts towards earlier hour as compared to 18-Hr direction for LAEs. For semi-diurnal anisotropy phase remains statistically the same for both HAE as well as for LAE. Further in case of tri-diurnal anisotropy phase is evenly distributed for both types of events. The interplanetary magnetic field and solar-wind plasma parameters during these events are also investigated. It has been also observed that HAE/LAEs are weakly dependent on solar-wind velocity. 相似文献