Studies on efficiencies of electrochemiluminescence of rubrene

The electrochemiluminescence efficiencies of rubrene system has been obtained by using the transient method in a variety of solvents. The efficiencies are in the range of 0·11 × 10^?3?4·1×10^?2. The mixed system efficiencies are less at least by an order of magnitude in all the solvents except in dimethylsulphoxide. The variation in efficiencies of the pure and mixed systems is explained on the basis of mechanistic differences. In the applied magnetic field, the electrochemiluminescence efficiency of the pure system increases by about 7% and of the mixed system by about 18–25%.     

Finite-dimensional quantum mechanics of a particle. II

The finite-dimensional quantum mechanics (FDQM) based on Weyl’s form of Heisenberg’s canonical commutation relations, developed for the case of one-dimensional space, is extended to three-dimensional space. This FDQM is applicable to the physics of particles confined to move within finite regions of space and is significantly different from the current quantum mechanics in the case of atomic and subatomic particles only when the region of confinement is extremely small—of the order of nuclear or even smaller dimensions. The configuration space of such a particle has a quantized eigenstructure with a characteristic dependence on its rest mass and dimension of the region of confinement, and the current Schrödinger-Heisenberg formalism of quantum mechanics becomes an asymptotic approximation of this FDQM. As an example, a spherical harmonic oscillator with a particular radius of confinement is considered.     

A study of daily variation in cosmic ray intensity during high/low amplitude days

A detailed study has been conducted on the long-term changes in the diurnal, semi-diurnal and tri-diurnal anisotropies of cosmic rays in terms of the high/low amplitude anisotropic wave train events (HAE/LAE) during the period 1981–94 using the neutron monitor data from Deep River Neutron Monitoring Station. In all, 38 HAE and 28 LAE cases have been studied. An inter-comparison of the first three harmonics during these events has been made so as to understand the basic reason for the occurrence of these types of events. It has been observed that the phase of diurnal anisotropy shifts towards earlier hours for HAEs and it shifts towards earlier hour as compared to 18-h direction for LAEs. For semi-diurnal anisotropy, phase remains statistically the same for both HAE and LAE. In the case of tri-diurnal anisotropy, phase is evenly distributed for both types of events. The interplanetary magnetic field (IMF) and solar wind plasma (SWP) parameters during these events are also investigated. It has also been observed that HAE/LAEs are weakly dependent on high-speed solar wind velocity. The two types of solar wind streams (corotating streams and flare-generated streams) produce significant deviations in cosmic ray intensity during HAE/LAE.      

Recent Advances in the Preparation and Applications of Organo‐functionalized Porous Materials

Organo‐functionalized materials with porous structure offer unique adsorption, catalytic and sensing properties. These unique properties make them available for various applications, including catalysis, CO₂ capture and utilization, and drug delivery. The properties and the performance of these unique materials can be altered with suitable modifications on their surface. In this review, we summarize the recent advances in the preparation and applications of organo‐functionalized porous materials with different structures. Initially, a brief historical overview of functionalized porous materials is presented, and the subsequent sections discuss the recent developments and applications of various functional porous materials. In particular, the focus is given on the various methods used for the preparation of organo‐functionalized materials and their important roles in the heterogenization of homogeneous catalysts. A special emphasis is also given on the applications of these functionalized porous materials for catalysis, CO₂ capture and drug delivery.     

Thermodynamics of binary liquid mixtures of cyclopentane with 2-propanol, 1-butanol and 2-butanol at different temperatures

Densities and speeds of sound of the cyclopentane with 2-propanol, 1-butanol and 2-butanol are measured over the whole composition range at different temperatures in the range 288.15–308.15 K and atmospheric pressure using Anton Paar DSA 5000 densimeter. The experimental densities and speeds of sound have been used to calculate excess molar volumes, excess molar isentropic compressibilities and excess intermolecular free length. The partial molar volumes and apparent molar volumes at infinite dilution have also been calculated. The mixing quantities like (∂V _m^E/∂T)_P and (∂H _m^E/∂P)_T have been calculated at T = 298.15 K and these values are compared with the values calculated from Flory’s theory at equimolar composition.     

Structure and rheology of reverse micelles in dipentaerythrityl tri-(12-hydroxystearate)/oil systems

We report the formation of reverse rod-like micelles and their rheological properties in novel nonionic surfactant, dipentaerythrityl tri-(12-hydroxystearate) (designated as WO-6)/oil systems without external water addition. Small-angle X-ray scattering (SAXS) was used to investigate the structure of the micelles and their flow properties were studied by rheological measurements. We found that WO-6 spontaneously self-assembles into reverse micelles in a variety of organic solvents at ambient conditions, their structure depending on solvent molecular architecture, surfactant concentration, and temperature. Rod-like micelles with a maximum length of ca. 12 nm and a cross section diameter of ca. 2 nm were observed in cyclohexane. When cyclohexane was replaced with a linear chain octane, the length and the cross section diameter were simultaneously increased. With a further increase of hydrocarbon chain length of solvent oils from octane to hexadecane, the rod-like micelles grew axially, keeping the cross section diameter (ca. 3 nm) virtually constant. Increasing surfactant concentration also favored one-dimensional micellar growth. On the other hand, micelles shrunk with the rise of temperature, which is similar to a rod-to-sphere transition, and is essentially the opposite temperature dependence to that often observed in aqueous micellar systems. A structural picture drawn by SAXS is well supported by rheology; the relative (zero-shear) viscosity of the WO-6/oil systems was found to be markedly greater than that expected for a dispersion of spherical particles due to the elongated micellar structure, despite quantitative inconsistency with semi-empirically predicted values for rigid rod-like particles.     

Novel semisquaraine regioisomers: isolation, divergent chemical reactivity and photophysical properties

A zwitterionic semisquaraine 1,3-regioisomer which exhibits distinct photophysical properties and chemical reactivity was isolated. Uniquely, this isomer has been identified as the reactive intermediate in the squaraine dye formation reaction rather than the neutral 1,2-isomer and opens up new avenues for the synthesis of novel dyes for optoelectronic applications.     

Monodisperse sub-10 nm gold nanoparticles by reversing the order of addition in Turkevich method--the role of chloroauric acid

The Turkevich method for synthesizing gold nanoparticles, using sodium citrate as the reducing agent, is renowned for its ability to produce biocompatible colloids with mean size >10 nm. Here we show that monodisperse gold nanoparticles in the 5-10 nm size range can be synthesized by simply reversing the order of addition of reactants, i.e. adding chloroauric acid to citrate solution. Kinetic studies and electron microscopic characterization revealed that the reactivity of chloroauric acid, initial molar ratio of citrate to chloroauric acid (MR), and reaction mixture pH play an important role in producing monodisperse gold nanoparticles. Reversing the order of addition also enhanced the stabilization of nanoparticles at high MR values. Remarkably, the system exhibits a 'memory' of the order of addition, even when the timescale of mixing is much shorter than the timescale of synthesis.     

Synthesis,Photoluminescence Behavior of Green Light Emitting Tb(III) Complexes and Mechanistic Investigation of Energy Transfer Process

A series of five new terbium(III) ion complexes with 4,4-difluoro-1-phenylbutane-1,3-dione (HDPBD) and anciliary ligands was synthesized. The composition and properties of complexes were analyzed by elemental analysis, IR, NMR, powder X-ray diffaraction, TG-DTG and photoluminescence spectroscopy. These complexes exhibited ligand sensitized green emission at 546 nm associated with ⁵D₄?→?⁷F₅ transitions of terbium ion in the emission spectra. The photoluminescence study manifested that the organic ligands act as antenna and facilitate the absorbed energy to emitting levels of Tb(III) ion efficiently. The enhanced luminescence intensity and decay time of ternary C2-C5 complexes observed due to synergistic effect of anciliary ligands. The CIE color coordinates of complexes came under the green region of chromaticity diagram. The mechanistic investigation of intramolecular energy transfer in the complexes was discussed in detail. These terbium(III) complexes can be thrivingly used as one of the green component in light emitting material and in display devices.

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Graphical Abstract Illustrate the sensitization process of the Tb ion and intramolecular energy transfer process in the Tb³⁺ complex.

     

Bhabha Equations for Unique Mass and Spin

Linear relativistic wave equations of Bhabha's type are discussed. Conditions for unique mass and unique spin are analysed in detail. It is shown that if one relaxes the diagonalisability of β_o by a weaker block form one gets a class of equations describing a spin-half particle. Several algebras which emerge and their representations are studied. The existence or otherwise of the hermitianising matrix in such cases is explicitly discussed. The properties of the new equations in the presence of minimally coupled electro-magnetic field are discussed.