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991.
Vibrational spectroscopy techniques can be applied to identify a susceptibility-to-adenocarcinoma biochemical signature. A sevenfold difference in incidence of prostate adenocarcinoma (CaP) remains apparent amongst populations of low- (e.g. India) compared with high-risk (e.g. UK) regions, with migrant studies implicating environmental and/or lifestyle/dietary causative factors. This study set out to determine the biospectroscopy-derived spectral differences between risk-associated cohorts to CaP. Benign prostate tissues were obtained using transurethral resection from high-risk (n = 11, UK) and low-risk (n = 14, India) cohorts. Samples were analysed using attenuated total reflection Fourier-transform infrared (FTIR) spectroscopy, FTIR microspectroscopy and Raman microspectroscopy. Spectra were subsequently processed within the biochemical cell region (1,800−1–500 cm–1) employing principal component analysis (PCA) and linear discriminant analysis (LDA) to determine whether wavenumber–absorbance/intensity relationships might reveal biochemical differences associated with region-specific susceptibility to CaP. PCA-LDA scores and corresponding cluster vector plots identified pivotal segregating biomarkers as 1,582 cm−1 (Amide I/II trough); 1,551 cm−1 (Amide II); 1,667 cm−1 (Amide I); 1,080 cm−1 (DNA/RNA); 1,541 cm−1 (Amide II); 1,468 cm−1 (protein); 1,232 cm−1 (DNA); 1,003 cm−1 (phenylalanine); 1,632 cm−1 [right-hand side (RHS) Amide I] for glandular epithelium (P < 0.0001) and 1,663 cm−1 (Amide I); 1,624 cm−1 (RHS Amide I); 1,126 cm−1 (RNA); 1,761, 1,782, 1,497 cm−1 (RHS Amide II); 1,003 cm−1 (phenylalanine); and 1,624 cm−1 (RHS Amide I) for adjacent stroma (P < 0.0001). Primarily protein secondary structure variations were biomolecular markers responsible for cohort segregation with DNA alterations exclusively located in the glandular epithelial layers. These biochemical differences may lend vital insights into the aetiology of CaP.  相似文献   
992.
A new and sensitive procedure for the graphite furnace-atomic absorption spectrophotometric (GF-AAS) determination of Pd in soil at nanogram level is described. The method is based on prior separation and enrichment of the metal as Pd(II)-SnCl3- -N-butylacetamide (BAA) complex into 1-pentanol (PN) by solvent extraction method. The value of the molar absorptivity of the complex in three solvents, i.e. ethyl acetate, 1-pentanol, chloroform, lie in the range of (0.70-2.75) x 10(4) L mol(-1) cm(-1) at lambda(max) 360-440 nm. The metal could be enriched into organic solvent, i.e. PN, up to 10-folds. The sensitivity (A = 0.0044) of the method in the term of the peak height was 0.5 ng Pd/mL of the aqueous solution at an enrichment factor (EF) of 5. Optimization of analytical variables during enrichment and GF-AAS determination of the metal are discussed. The method has been applied for the analysis of Pd to soil samples derived from roads and highways in Germany.  相似文献   
993.
994.
Nanocrystalline HgS thin films were synthesized by using an electrochemical route under galvanostatic conditions. Quantum size effects have resulted in the change of the semi-metallic behavior of bulk β-HgS (Eg=-0.5 eV) to semiconducting behavior with an absorption onset around 1.4 eV as confirmed from optical absorption studies. Glancing angle X-ray diffraction analysis confirms the presence of β-HgS (zinc-blend structure) with prominent crystallographic planes of (200), (220) and (311) in the deposit. This is consistent with results obtained from transmission electron diffraction studies. The Raman scattering measurements identified a broad 1LO confined phonon mode at 247 cm-1 which suggests that the crystalline sizes are small. PACS 61.10.Nz; 63.22.+n; 81.07.Bc  相似文献   
995.
We compute the catenary degree of elements contained in numerical monoids generated by arithmetic sequences. We find that this can be done by describing each element in terms of the cardinality of its length set and of its set of factorizations. As a corollary, we find for such monoids that the catenary degree becomes fixed on large elements. This allows us to define and compute the dissonance number- the largest element with a catenary degree different from the fixed value. We determine the dissonance number in terms of the arithmetic sequence’s starting point and its number of generators.  相似文献   
996.
Here, free vibrations and transient dynamic response analyses of laminated cross-ply oval cylindrical shells are carried out. The formulation is based on higher order theory that accounts for the transverse shear and the transverse normal deformations, and includes zig-zag variation in the in-plane displacements across the thickness of the multi-layered shells. The contributions of inertia effect due to in-plane and rotary motions, and the higher order function arising from the assumed displacement models are included. The governing equations obtained using Lagrangian equations of motion are solved through finite element approach. A detailed parametric study is conducted to bring out the influence of different shell geometry, ovality parameter, lay-up and loading environment on the vibration characteristics related to different modes of vibrations of oval shell.  相似文献   
997.
We present some recent results from studies of light nuclei using exotic beams from ATLAS at Argonne National Laboratory. Light nuclei far from stability provide ideal testing grounds for modern theoretical methods, and may provide information about astrophysical environments. We focus on the nuclei 9Li and 7He, populated with the (d,p) and (d,3He) reactions.  相似文献   
998.
An efficient synthetic strategy has been developed for the synthesis of pyrazolyl‐1,2,3‐thiadiazoles via Hurd–Mori cyclization reaction. The reaction of various pyrazolyl‐phenylethanones with semicarbazide hydrochloride in the presence of sodium acetate/methanol gave the corresponding semicarbazones ( 3a – i ). These semicarbazones were further reacted with thionyl chloride via the Hurd–Mori cyclization conditions to accomplish the title products ( 4a – i ). The present protocol favored for the formation of both pyrazolyl semicarbazone derivatives and pyrazolyl‐1,2,3‐thiadiazole derivatives by forming C─S, N─S, and C═N bonds in excellent yields with variety of substrates. The final compounds were characterized by analytical and spectral studies.  相似文献   
999.
Polyaniline coated on particles of celite is used as support to load palladium catalyst. This heterogenized Celite?PANI?Pd system, is used as an efficient catalyst for chemoselective hydrogenation reactions. The catalyst is characterized by usual spectral, analytical techniques and studied for hydrogenation reactions at ambient conditions. The mild reaction conditions allow the control over the reactions and excellent selectivity is achieved in number of conversions. Hydrogenation of a carbon–carbon double bond was favored over other polar π‐bond systems, while labile functional groups such as benzyl ether, benzyl esters, cyano, nitro and halogen remained unaffected. Primary amines were converted to N,N‐dimethyl amines with formaldehyde, the double bond of coumarin was selectively hydrogenated without opening of the lactone functionality.  相似文献   
1000.
Phenacyl bromides are used as a building blocks in synthetic organic chemistry, which serves as a key model for the development of various biologically important heterocyclic compounds and other industrially important scaffolds. This review covers recent synthetic advances in the preparation of heterocyclic compounds utilizing various phenacyl bromides. A wide range of five- and six-membered heterocyclic compounds as well as fused heterocyclic compounds were synthesized efficiently from the phenacyl bromide precursors through one-pot multicomponent reactions.  相似文献   
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