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Synthesis of Mesoporous Lithium Titanate Thin Films and Monoliths as an Anode Material for High‐Rate Lithium‐Ion Batteries
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Dr. Fadime Mert Balcı Ömer Ulaş Kudu Prof. Eda Yılmaz Prof. Ömer Dag 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(52):18873-18880
Mesoporous Li4Ti5O12 (LTO) thin film is an important anode material for lithium‐ion batteries (LIBs). Mesoporous films could be prepared by self‐assembly processes. A molten‐salt‐assisted self‐assembly (MASA) process is used to prepare mesoporous thin films of LTOs. Clear solutions of CTAB, P123, LiNO3, HNO3, and Ti(OC4H9)4 in ethanol form gel‐like meso‐ordered films upon either spin or spray coating. In the assembly process, the CTAB/P123 molar ratio of 14 is required to accommodate enough salt species in the mesophase, in which the LiI/P123 ratio can be varied between molar ratios of 28 and 72. Calcination of the meso‐ordered films produces transparent mesoporous spinel LTO films that are abbreviated as Cxx‐yyy‐zzz or CAxx‐yyy‐zzz (C=calcined, CA=calcined–annealed, xx=LiI/P123 molar ratio, and yyy=calcination and zzz=annealing temperatures in Celsius) herein. All samples were characterized by using XRD, TEM, N2‐sorption, and Raman techniques and it was found that, at all compositions, the LTO spinel phase formed with or without an anatase phase as an impurity. Electrochemical characterization of the films shows excellent performance at different current rates. The CA40‐350‐450 sample performs best among all samples tested, yielding an average discharge capacity of (176±1) mA h g?1 at C/2 and (139±4) mA h g?1 at 50 C and keeping 92 % of its initial discharge capacity upon 50 cycles at C/2. 相似文献
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We study the oscillation properties of a system of two first-order nonlinear equations on time scales. This form includes the classical Emden–Fowler differential and difference equations and many of its extensions. We generalize some well-known results of Atkinson, Belohorec, Waltman, Hooker, Patula and others and also describe the relation to solutions of a delay-dynamic system. 相似文献
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Stride-to-stride energy regulation for robust self-stability of a torque-actuated dissipative spring-mass hopper 总被引:1,自引:0,他引:1
In this paper, we analyze the self-stability properties of planar running with a dissipative spring-mass model driven by torque actuation at the hip. We first show that a two-dimensional, approximate analytic return map for uncontrolled locomotion with this system under a fixed touchdown leg angle policy and an open-loop ramp torque profile exhibits only marginal self-stability that does not always persist for the exact system. We then propose a per-stride feedback strategy for the hip torque that explicitly compensates for damping losses, reducing the return map to a single dimension and substantially improving the robust stability of fixed points. Subsequent presentation of simulation evidence establishes that the predictions of this approximate model are consistent with the behavior of the exact plant model. We illustrate the relevance and utility of our model both through the qualitative correspondence of its predictions to biological data as well as its use in the design of a task-level running controller. 相似文献
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Stereoselective Synthesis of 1,2,3‐Triazolooxazine and Fused 1,2,3‐Triazolo‐δ‐Lactone Derivatives
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The stereoselective synthesis of 1,2,3‐triazolooxazine and fused 1,2,3‐triazolo‐δ‐lactone by applying chemoenzymatic methods is described. trans‐2‐Azidocyclohexanol was successfully resolved by Novozyme 435 with an ee value of 99%. Installation of the alkyne moiety on the enantiomerically enriched azidoalcohol by O‐alkylation, followed by intramolecular azide? alkyne [3+2] cycloaddition resulted in the desired 1,2,3‐triazolooxazine derivative. Enantiomerically pure azidocyclohexanol was also subjected to the Huisgen 1,3‐dipolar cycloaddition reaction with dimethylacetylene dicarboxylate, followed by intramolecular cyclization of the corresponding cycloadduct, to furnish a fused 1,2,3‐triazolo‐δ‐lactone. 相似文献
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Olcay Mert Asgar Kayan 《Journal of inclusion phenomena and macrocyclic chemistry》2014,80(3-4):409-416
In this study, zirconium salicylate compounds (1–6) were prepared by reaction of zirconium(IV) propoxide with 5-chlorosalicylic acid, 4-hydroxysalicylic acid, and 5-nitrosalicylic acid in 1-propanol, respectively. All these compounds (1–6) were characterized by 1H, 13C NMR, FTIR, mass spectroscopy, elemental, and thermogravimetric analyses. These compounds were tested as catalysts in polymerization of ε-caprolactone and were effective. Polycaprolactone was characterized by 1H, 13C NMR, and gel permeation chromatography. The number of salicylate ligands (bonded to zirconium atom) effects and substituents (on salicylate ligands) effects on the polymerization reactions were investigated first time by this study. 相似文献