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71.
Monte‐Carlo simulations predict that a local correlated disorder is responsible for many of the novel transport and magnetic properties of colossal magnetoresistance (CMR) materials such as manganites. One important prediction of these models is that the resistivity at the metal–insulator transition (MIT) in manganites depends strongly on the correlated quenched disorder. However, experimental confirmation has been challenging since it is difficult to control the amount of disorder in these compounds. We carried out experiments on Sm0.55Sr0.45MnO3, a prototypical CMR manganite with a sharp MIT, whereby the oxygen‐related disorder is systematically enhanced by low temperature thermal activation. We observe dramatic changes in the temperature dependence of resistivity at the MIT as the amount of quenched disorder is increased, occurring in a manner that is in agreement with theoretical predictions.
72.
Antonio L. Braga Ricardo S. Schwab Syed M. Salman Juliano B. Azeredo 《Tetrahedron letters》2009,50(20):2309-1982
A set of chiral β-seleno amines were prepared by the ring-opening reaction of unprotected aziridines. Under acid conditions diaryl or dialkyl diselenides were reduced by zinc and treated with unprotected aziridines to produce the desired products in good yields. Chiral β-telluro amine was also obtained using this method. 相似文献
73.
Bespechansky E Portnov A Zwielly A Rosenwaks S Bar I 《The Journal of chemical physics》2006,125(13):133301
H and D photofragments produced via vibrationally mediated photodissociation of jet-cooled normal ethene (C2H4), 1,2-trans-d2-ethene (HDCCDH), and 1,1-d2-ethene (CH2CD2), initially excited to the fourth C-H stretch overtone region, were studied for the first time. H and D vibrational action spectra and Doppler profiles were measured. The action spectra include partially resolved features due to rotational cooling, while the monitored room temperature photoacoustic spectra exhibit only a very broad feature in each species. Simulation of the spectral contours allowed determination of the band types and origins, limited precision rotational constants, and linewidths, providing time scales for energy redistribution. The H and D Doppler profiles correspond to low average translational energies and show slight preferential C-H over C-D bond cleavage in the deuterated variants. The propensities toward H photofragments emerge even though the energy flow out of the initially prepared C-H stretch is on a picosecond time scale and the photodissociation occurs following internal conversion, indicating a more effective release of the light H atoms. 相似文献
74.
In this paper, the Nonlinear Normal Modes (NNMs) analysis for the case of three-to-one (3:1) internal resonance of a slender simply supported beam in presence of compressive axial load resting on a nonlinear elastic foundation is studied. Using the Euler?CBernoulli beam model, the governing nonlinear PDE of the beam??s transverse vibration and also its associated boundary conditions are extracted. These nonlinear motion equation and boundary condition relations are solved simultaneously using four different approximate-analytical solution techniques, namely the method of Multiple Time Scales, the method of Normal Forms, the method of Shaw and Pierre, and the method of King and Vakakis. The obtained results at this stage using four different methods which are all in time?Cspace domain are compared and it is concluded that all the methods result in a similar answer for the amplitude part of the transverse vibration. At the next step, the nonlinear normal modes are obtained. Furthermore, the effect of axial compressive force in the dynamic analysis of such a beam is studied. Finally, under three-to-one-internal resonance condition the NNMs of the beam and the steady-state stability analysis are performed. Then the effect of changing the values of different parameters on the beam??s dynamic response is also considered. Moreover, 3-D plots of stability analysis in the steady-state condition and the beam??s amplitude frequency response curves are presented. 相似文献
75.
Irfan Anjum Badruddin N. J. Salman Ahmed Abdullah A. A. A. Al-Rashed Jeevan Kanesan Sarfaraz Kamangar H. M. T. Khaleed 《Transport in Porous Media》2012,91(2):697-715
The present study is intended to study heat and mass transfer in a vertical annular cylinder embedded with saturated porous
medium. The inner surface of cylinder is maintained at uniform wall temperature and uniform wall concentration. The governing
partial differential equations are non-dimensionalised and solved by using finite element method (FEM). The porous medium
is discritised using triangular elements with uneven element size. Large number of smaller-sized elements are placed near
the walls of the annulus to capture the smallest variation in solution parameters. The results are reported for both aiding
and opposing flows. The effects of various non-dimensional numbers such as buoyancy ratio, Lewis number, Rayleigh number,
aspect ratio, etc on heat and mass transfer are discussed. The temperature and concentration profiles are presented. 相似文献
76.
Ali Asghar Mohammadi Salman Taheri Arman Amini Reza Ahdenov 《Molecular diversity》2018,22(4):999-1006
Triamide derivatives have been synthesized in good yields in a novel, one-pot, five-component, and efficient process by the reaction of Z-oxazolone, water, primary amines, aldehydes, isocyanides, in the presence of catalytic amount of KAl(SO4)2·12H2O (alum) as a non-toxic, reusable, inexpensive, and easily available reagent via Ugi reaction in aqueous solution. 相似文献
77.
Salman Nisar Sohaib Z. Khan Muhammad Ali Lin Li Mohammed A. Sheikh 《Journal of Russian Laser Research》2014,35(2):182-192
Laser cutting of glass using the controlled fracture technique leads to cut path deviation at the leading and trailing edges of the float glass sheet. In this technique, thermal stresses are used to induce the crack, and the material is separated along the cutting path by extending the crack. We show that the cut path deviation is partly due to high magnitudes of thermal stresses generated near the sheet edges. The absorption of intense radiation from the CO2 and diode laser beams in the glass causes local temperature increases and consequently generates different thermal fields and stress distributions due to surface and volumetric heat absorption. In this paper, we report the effect of the CO2 and diode laser wavelength interaction with the float glass and its effect on the magnitudes of thermal stresses generated near the edges of the glass sheet. We simulate the distribution of the thermal stress and temperature using finite-element analysis software Abaqus and validate it against the experimental data. We show that the CO2 laser produces a lower surface quality and a larger cut path deviation at the leading and trailing edges of the glass sheet as compared to the diode laser. 相似文献
78.
Saraya Roshdy E. Hassan Yasser F. Eltukhi Walid E. Salman Baher I. 《Journal of fluorescence》2022,32(5):1725-1732
Journal of Fluorescence - Vonoprazan (VON) has been approved recently via US-FDA in 2015 as the first in class of potassium competitive acid blocker group. VON is used for management of... 相似文献
79.
Novel steroidal (6R)‐spiro‐1,3,4‐thiadiazoline derivatives have been synthesized by the cyclization of steroidal thiosemicarbazones. Thiosemicarbazones have been synthesized by the reaction of steroidal ketones with thiosemicarbazide. All the compounds have been characterized by IR, 1H NMR, mass and elemental analyses. The antibacterial activities of these compounds have been first tested in vitro by the disk diffusion assay against two Gram‐positive and two Gram‐negative bacteria, and then the minimum inhibitory concentration (MIC) values have been determined with the reference of standard drug amoxicillin. The results showed that steroidal thiadiazoline derivatives exhibited better antibacterial activity than the steroidal thiosemicarbazone derivatives. Chloro and acetoxy substituents on the 3β‐position of the steroidal thiadiazoline ring increased the anti‐bacterial activity. Among all the compounds, compounds 7 and 8 were found better inhibitors as compared to the respective drug amoxicillin. 相似文献
80.
Syed Hamad Bukhari Muhammad Iqbal Hussain Salman Naeem Khan Muhammad Ashfaq Ahmad 《Optik》2012,123(24):2288-2291
Nonclassical features of Schrödinger cat state with two-mode superposition state based on two coherent states π out of phase by fixing the relative phase equal to average photon number are discussed. Study of two-mode quadrature squeezing, oscillatory and sub-Poissonian photon statistics show that nonclassicality exists for these states. However, it is observed that the considered states do not violates the Cauchy–Schwarz inequality. Furthermore, simultaneously existence of quadrature squeezing and sub-Poissonian photon statistics shows that these states have more nonclassical features than that of famous even and odd coherent states. 相似文献