Prediction of nanofluid viscosity using multilayer perceptron and Gaussian process regression

Journal of Thermal Analysis and Calorimetry - More than a decade, a numerous experimental and theoretical studies of thermophysical properties of nanofluids are conducted to reveal its heat...     

Synthesis of Zinc Oxide Nanoparticles Using Rubus fairholmianus Root Extract and Their Activity against Pathogenic Bacteria

Recently, the biosynthesis of zinc oxide nanoparticles (ZnO NPs) from crude extracts and phytochemicals has attracted much attention. Green synthesis of NPs is cost-effective, eco-friendly, and is a promising alternative for chemical synthesis. This study involves ZnO NPs synthesis using Rubus fairholmianus root extract (RE) as an efficient reducing agent. The UV spectrum of RE-ZnO NPs exhibited a peak at 357 nm due to intrinsic bandgap absorption and an XRD pattern that matches the ZnO crystal structure (JCPDS card no: 36-1451). The average particle size calculated from the Debye–Scherrer equation is 11.34 nm. SEM analysis showed that the RE-ZnO NPs spherical in shape with clusters (1–100 nm). The antibacterial activity of the NPs was tested against Staphylococcus aureus using agar well diffusion, minimum inhibitory concentration, and bacterial growth assay. The R. fairholmianus phytochemicals facilitate the synthesis of stable ZnO NPs and showed antibacterial activity.     

Neuroprotective Effect and Antioxidant Potency of Fermented Cultured Wild Ginseng Root Extracts of Panax ginseng C.A. Meyer in Mice

Wild ginseng has better pharmacological effects than cultivated ginseng. However, its industrialization is limited by the inability to grow wild ginseng on a large scale. Herein, we demonstrate how to optimize ginseng production through cultivation, and how to enhance the concentrations of specific ginsenosides through fermentation. In the study, we also evaluated the ability of fermented cultured wild ginseng root extract (HLJG0701-β) to inhibit acetylcholinesterase (AChE), as well as its neuroprotective effects and antioxidant activity. In in vitro tests, HLJG0701-β inhibited AChE activity and exerted neuroprotective and antioxidant effects (showing increased catalyst activity but decreased reactive oxygen species concentration). In in vivo tests, after HLJG0701-β was orally administered at doses of 0, 125, 250, and 500 mg/kg in an animal model of memory impairment, behavioral evaluation (Morris water maze test and Y-maze task test) was performed. The levels of AChE, acetylcholine (ACh), blood catalase (CAT), and malondialdehyde (MDA) in brain tissues were measured. The results showed that HLJG0701-β produced the best results at a dose of 250 mg/kg or more. The neuroprotective mechanism of HLJG0701-β was determined to involve the inhibition of AChE activity and a decrease in oxidative stress. In summary, both in vitro and in vivo tests confirmed that HJG0701-β administration can lead to memory improvement.     

Enhanced Electrocatalytic Activity of Methanol and Ethanol Oxidation in Alkaline Medium at Bimetallic Nanoparticles Electrochemically Decorated Fullerene-C60 Nanocomposite Electrocatalyst: An Efficient Anode Material for Alcohol Fuel Cell Applications

Direct alcohol fuel cells (DAFCs) have been recently playing a pivotal role in electrochemical energy sources and portable electronics. Research in DAFCs has proceeded to engage major attention due to their high catalytic activity, long-term stability, portability, and low cost. Herein, we present a facile surfactant-free route to anchor bimetallic Pd−W nanoparticles supported fullerene-C₆₀ catalyst (Pd-W@Fullerene-C₆₀) for high-performance electrooxidation of alcohols (methanol & ethanol) for DAFCs applications. Structural, elemental composition, and morphological analysis of the proposed catalyst were carried out using UV-Vis spectroscopy, X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and energy-dispersive x-ray spectroscopy (EDX). Electrochemical properties such as electrochemical activity, electrochemical active surface area (ECSA), and long-term stability of the Pd-W@Fullerene-C₆₀ catalyst for ethanol and methanol oxidation in the alkaline medium were explored by using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and chronoamperometry (CA). Results revealed that the proposed catalyst showed enlarged ECSA, tremendous electrocatalytic activity, high poison tolerance limit, good reproducibility, and enhanced long-term stability as compared to the monometallic catalyst and commercially available catalyst (Pt/C) towards ethanol and methanol oxidation reaction. This enhanced potentiality of the Pd-W@Fullerene-C₆₀ catalyst is due to the synergistic effect of W−Pd nanoparticles and excellent electron kinetic from fullerene support material. These findings strongly suggest the Pd-W@Fullerene-C₆₀ catalyst as potential anode material for the alcohol oxidation reaction.     

Nickel and Tungsten Bimetallic Nanoparticles Modified Pencil Graphite Electrode: A High-performance Electrochemical Sensor for Detection of Endocrine Disruptor Bisphenol A

In this work, an economically viable, very low cost, indigenous, ubiquitously available electrochemical sensor based on bimetallic nickel and tungsten nanoparticles modified pencil graphite electrode (NiNP-WNP@PGE) was fabricated for the sensitive and selective detection of bisphenol A (BPA). The NiNP-WNP@PGE sensor was prepared by a facile electrochemical one step co-deposition method. The prepared nanocomposite was morphologically characterized by scanning electron microscopy (SEM), energy dispersive X-ray (EDX), X-ray diffraction (XRD), electrochemically by cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The proposed sensor displayed high electrocatalytic activity towards electro-oxidation of BPA with one irreversible peak. The fabricated sensor displayed a wide detection window between 0.025 μM and 250 μM with a limit of detection of 0.012 μM. PGE sensor was successfully engaged for the detection of BPA in bottled water, biological, and baby glass samples.     

Development of Pen-type Portable Electrochemical Sensor Based on Au-W Bimetallic Nanoparticles Decorated Graphene-chitosan Nanocomposite Film for the Detection of Nitrite in Water,Milk and Fruit Juices

The development and fabrication of a simple, portable, and sensitive detection tool to precisely monitor nitrite level is of growing importance in electrochemistry research, given the strong interest in the protection of drinking water quality, treatment of wastewater, food production, and control of remediation processes. This work describes the fabrication of a simple, cost-effective, pen-type electrochemical sensor based on bimetallic gold and tungsten nanoparticles electrochemically decorated on graphene-chitosan modified pencil graphite electrode (PGE) for the trace detection of nitrite in real samples. The prepared nanocomposite was characterized using XRD, SEM, and EDS. The electrochemical behavior of the sensor was evaluated by cyclic voltammetry (CV) and impedance electrochemical spectroscopy (EIS). Results revealed that the proposed sensor displayed excellent electrocatalytic activity towards electro-oxidation of nitrite with an irreversible redox reaction. The AuNPs-WNPs@Gr-Chi/PGE sensor exhibited excellent analytical performance with a wide linear range from 10 to 250 μM towards nitrite. The LOD and LOQ were calculated to be 0.12 μM and 0.44 μM, respectively. The designed electrochemical sensor was successfully applied for the detection of nitrite in water, milk, and natural fruit juice samples.     

Green Synthesis of Cuprous Oxide Nanoparticles Using Andean Capuli (Prunus serotina Ehrh. var. Capuli) Cherry

Journal of Cluster Science - Copper oxide nanoparticles have gained considerable attention in the past two decades due to their simplicity and exhibit a range of potentially useful physical...     

Biological Applications of Synthesized ZnO Nanoparticles Using Pleurotus djamor Against Mosquito Larvicidal,Histopathology, Antibacterial,Antioxidant and Anticancer Effect

The present study pertained to biosynthesis, characterization and biomedical application (larvicidal, histopathology, antibacterial, antioxidant and anticancer activity) of Zinc oxide nanoparticles (ZnONPs) from Pleurotus djamor. The synthesized NPs were characterized using spectral and microscopic analyses and further confirmed by UV–Visible spectrophotometer with apeak of 350 nm. The ZnONPs showed strong antioxidant property (DPPH, H₂O₂ and ABTS⁺ radical assay) and expressed good larval toxicity against Ae. aegypti and Cx. quinquefasciatus (IVth instar larvae) with the least LC₅₀ and LC₉₀ values (10.1, 25.6 and 14.4, 31.7 mg/l) after 24 h treatment, respectively. We noticed the morphological changes (damaged anal papillae area and the cuticle layers) in the treated larvae. For the antibacterial assay, the highest growth inhibition zone was recorded in C. diphteriae (28.6?±?0.3 mm), followed by P. fluorescens (27?±?0.5 mm) and S. aureus (26.6?±?1.5 mm). The in vitro cytotoxicity assay depicted a significant level of cytotoxic effects (LC₅₀ values 42.26 μg/ml) of ZnONPs against the A549 lung cancer cells, even at low dose. The overall findings of the study suggest that P. djamor had the ability for the biosynthesis of ZnONPs and could act as an alternative biomedical agent for future therapeutic applications in medical avenues.

     

Observation of two resonant structures in e+ e- -->pi+ pi- psi(2S) via initial-state radiation at Belle

The cross section for e+ e- --> pi+ pi- psi(2S) between threshold and sqrt[s]=5.5 GeV is measured using 673 fb(-1) of data on and off the Upsilon(4S) resonance collected with the Belle detector at KEKB. Two resonant structures are observed in the pi+ pi- psi(2S) invariant-mass distribution, one at 4361 +/- 9 +/- 9 MeV/c2 with a width of 74 +/- 15 +/- 10 MeV/c2, and another at 4664 +/- 11 +/- 5 MeV/c2 with a width of 48 +/- 15 +/- 3 MeV/c2, if the mass spectrum is parametrized with the coherent sum of two Breit-Wigner functions. These values do not match those of any of the known charmonium states.