Zur Darstellung von Oxiden cyclischer,sekundärer Arsine

Hydrolysis of 1-chloro-arsolane, C₄H₈AsCl, and 1-chloro-arsenane, C₅H₁₀AsCl, leads to oxides C₈H₁₀As₂O and C₁₀H₂₀As₂O, respectively. On direct alkylation of arsenic trioxide with 1.4-butane- and 1.5-pentane-bis-magnesium bromide these oxides are formed only in trifling amounts. Better results are gained by alkylation of N,N-dimethylaminodichloroarsane into amino-arsolane and amino-arsenane, which are also transformed into these oxides by hydrolysis. By hydrolysis of 1.4-dichloro-diarsenane only a small amount of 1.4-epoxo-arsenane is formed, whereas mainly a dimer of this oxide results. Solvolysis of 2.6-dichloro-diarsa-[3.3.0]-bicyclooctane with water, hydrogen sulphide or methylamine leads to 7-oxa-, 7-thia- and 7-methylaza-2.5-diarsa-noradamantane, respectively.     

1. Elementaranalyse

Ohne Zusammenfassung     

I. Allgemeine analytische Methoden, Apparate und Reagentien

Ohne Zusammenfassung     

Derivatives of (2R)-N-Glyoxylbornane-10,2-sultam and Their Use as auxiliaries in the diastereoselective spirocyclization of 2-substituted tryptamines

A crude hydrate 6 and a crystalline hemiacetal 7 of glyoxylamide 4 were prepared from crotonamide 5 (Scheme 2). Particularly hemiacetal 7 , but also 6 and the ‘dimer’ 8 (obtained from 7 ) may serve as homochiral auxiliaries. The structure of 8 was determined by X-ray analysis. By arenesulfonyl halides, tryptimines 12–14 of 4 were diastereoselectively transformed into spirotricycles 15–17 and 19 .     

CaNa[Cr(OH)6] – A Layered Hydroxochromate(III) with Ordered Brucite Structure and its Thermal Decomposition

Green single-crystals of the hydroxochromate(III) CaNa[Cr(OH)₆] were grown under highly alkaline hydrothermal conditions at about 200 °C. The starting materials Ca(NO₃)₂ · 6H₂O and Cr(NO₃)₃ · 9H₂O were reacted in a mixture of water and sodium hydroxide with the molar ratio of 2.8:1. CaNa[Cr(OH)₆] crystallizes in the non-centrosymmetric trigonal space group R3 with the lattice parameters a = 583.86(2) pm and c = 1428.73(6) pm [T = 100(1) K]. Characteristically, the crystals are reverse-obverse as well as inversion twins. The crystal structure is a stack of uncharged metal hydroxide layers, which can be regarded as a cation-ordered rhombohedral variant of the Mg(OH)₂ (brucite) structure type. The oxidation state of chromium(III) and its coordination by hydroxide groups was confirmed by UV/Vis and IR spectroscopy, respectively. Temperature-dependent magnetic measurements revealed paramagnetic behavior with an effective moment of 3.82 μ_B per chromium atom. The thermal decomposition of CaNa[Cr(OH)₆] takes place at about 225 °C, where the fast elimination of 1.5 equivalents of water is followed by the oxidation of chromium(III) to chromium(VI). Upon further heating to 1000 °C and 1200 °C, the intermediate decomposition products CaCrO₄ and Na₂CrO₄ transform into the oxochromates(V) Ca₅(CrO₄)₃O_0.5 and Ca₃(CrO₄)₂, respectively.     

Distillation, on-line RP C18 preconcentration and HPLC-UV-PCO-CVAAS as a new combination for the determination of methylmercury in sediments and fish tissue

 Distillation as a way of sample digestion has been combined with on-line RP C18 preconcentration and HPLC-UV-PCO-CVAAS (high performance liquid chromatography – ultra violet – post column oxidation – cold vapour atomic absorption spectrometry) for the determination of methylmercury at background levels in sediments, soils and fish tissue. To prove the accuracy of this method, it was applied to sediment and fish tissue reference materials. The results correspond with the reference values within their error ranges. Excellent recoveries (92–95%) were obtained for the sediment samples by means of the standard addition method. The standard deviations of the sediment samples were within an acceptable range (7.2–12.5%), those of the fish samples were substantially lower (3.4–5.0%). The detection limit is 0.04 ng/g for 1 g sample weight. Received: 23 November 1995/Revised: 16 April 1996/Accepted: 20 April 1996     

Investigation of potential-sensitive fluorescent dyes for application in nitrate sensitive polymer membranes

The applicability of various potential-sensitive dyes (PSD) for optical sensing of anions is reported. Specifically, nitrate-responsive polymer membranes have been developed which are composed of a plasticized polymer, an anion exchange catalyst, and a fluorescent dye. On exposure to nitrate, the fluorescence intensity of such membranes increases, while the wavelengths of the excitation and emission maxima remain virtually unchanged. The membranes typically are 2–4 μm thick and exhibit highest sensitivity to nitrate in the 2 to 200 mgl^–1 range. Signal changes on exposure to 100 mmol/l nitrate can be as high as +300%. The detection limit is 0.2 mgl^–1. The cationic PSD octadecyl acridine organe was tested in combination with a tin-organic and an indium-organic anion carrier rather than with tridodecylmethylammonium chloride, but both carriers were found to display no improved selectivity. Received: 2 December 1995 / Revised: 28 March 1996 / Accepted: 5 April 1996