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131.
The interfacial heat transfer coefficient (IHTC) is necessary for accurate simulation of the casting process. In this study,
a cylindrical geometry is selected for the determination of the IHTC between aluminum alloy casting and the surrounding sand
mold. The mold surface heat flux and temperature are estimated by two inverse heat conduction techniques, namely Beck’s algorithm
and control volume technique. The instantaneous cast and mold temperatures are measured experimentally and these values are
used in the theoretical investigations. In the control volume technique, partial differential heat conduction equation is
reduced to ordinary differential equations in time, which are then solved sequentially. In Beck’s method, solution algorithm
is developed under the function specification method to solve the inverse heat conduction equations. The IHTC was determined
from the surface heat flux and the mold surface temperature by both the techniques and the results are compared. 相似文献
132.
133.
The inclusive reaction a + b → c + X is calculated in a φ3 theory ladder model in the pionisation region. A Mellin transform method is used to obtain, without resorting to leading term approximations, a double Regge form for the > amplitude in this region, resulting in limiting pionisation. The Mellin transform method has to be applied with discretion here and is not a trivial extension of the same method as applied earlier to the fragmentation region. It is pointed out that these methods can also be applied to multiple-inclusive reactions, once again giving expected Regge-behaved results. 相似文献
134.
Abu-Nawwas AA Cano J Christian P Mallah T Rajaraman G Teat SJ Winpenny RE Yukawa Y 《Chemical communications (Cambridge, England)》2004,(3):314-315
The structure and magnetic properties of a dodecanuclear iron(III) wheel are reported, featuring a bridging zwitterionic ligand. 相似文献
135.
Collison D Murrie M Oganesyan VS Piligkos S Poolton NR Rajaraman G Smith GM Thomson AJ Timko GA Wernsdorfer W Winpenny RE McInnes EJ 《Inorganic chemistry》2003,42(17):5293-5303
The dodecametallic Cr(III) cluster [Cr(12)O(9)(OH)(3)(O(2)CCMe(3))(15)] has a ground spin state of S = 6 characterized by the spin Hamiltonian parameters g(ZZ)() = 1.965, g(XX)() = g(YY)() = 1.960, D(S=)()(6) = +0.088 cm(-)(1), and E(S=)()(6) = 0 (where D and E are the axial and rhombic zero-field splitting parameters, respectively) as determined by multifrequency EPR spectroscopy and magnetization studies. Micro-SQUID magnetization studies reveal steps due to the fine structure of the ground state, with the spacing between the steps in excellent agreement with the D(S=)()(6) value determined by EPR. Analysis of high-resolution optical data (MCD) allows us to determine the single-ion g values and D value (= -1.035 cm(-)(1)) of the constituent Cr(III) ions directly. A vector coupling analysis demonstrates that the cluster ZFS is almost entirely due to the single-ion component. Thus, the relative orientations of the local and cluster magnetic axes can lead to a cluster ZFS of opposite sign to the single-ion value, even when this is the only significant contribution. 相似文献
136.
We investigate a new class of dark matter: superweakly interacting massive particles (super-WIMPs). As with conventional WIMPs, super-WIMPs appear in well motivated particle theories with naturally the correct relic density. In contrast to WIMPs, however, super-WIMPs are impossible to detect in all conventional dark matter searches. We consider the concrete examples of gravitino and graviton cold dark matter in models with supersymmetry and universal extra dimensions, respectively, and show that super-WIMP dark matter satisfies stringent constraints from big bang nucleosynthesis and the cosmic microwave background. 相似文献
137.
138.
Three pathways for the reaction of bispidine-iron(II) complexes (where bispidine is a rigid tetradentate amine/pyridine ligand) with H2O2 have been studied by DFT calculations. For all oxidation states the high-spin and low-spin (intermediate-spin) forms have been optimized, and the computed data have been compared with the readily available experimental results. It is concluded that there is a direct conversion of the bispidine-iron(II)-hydrogen peroxide complex to the corresponding iron(IV)-dihydroxo compound, which is a novel possible oxidant for the dihydroxylation of olefins. 相似文献
139.
Prescimone A Wolowska J Rajaraman G Parsons S Wernsdorfer W Murugesu M Christou G Piligkos S McInnes EJ Brechin EK 《Dalton transactions (Cambridge, England : 2003)》2007,(45):5282-5289
Reaction of the dinuclear complex [Mn2O2(bpy)4](ClO4)3 with H3cht (cis,cis-l,3,5-cyclohexanetriol) in MeCN produces the complex [Mn3(Hcht)2(bpy)4](ClO4)3.Et2O.2MeCN (1.Et2O.2MeCN). Dc magnetic susceptibility measurements reveal the existence of weak ferromagnetic exchange between the three Mn ions, leading to a spin ground state of S = 7, with D = -0.23 cm(-1). W-Band (94 GHz) EPR measurements on restrained powdered crystalline samples confirm the S = 7 ground state and determine the ground state zero-field splitting (ZFS) parameters of D = -0.14 cm(-1) and B4(0)= +1.5 x 10(-5) cm(-1). The apparent 4th order behaviour is due to a breakdown of the strong exchange limit approximation (J approximately d, the single-ion ZFS). Single crystal dc relaxation decay and hysteresis loop measurements reveal the molecule to have an appreciable energy barrier to magnetization relaxation, displaying low temperature sweep rate and temperature-dependent hysteresis loops. Density functional studies confirm the ferromagnetic exchange coupling between the Mn ions. 相似文献
140.
Fractional reaction–diffusion equations serve as more relevant models for studying complex patterns in several fields of nonlinear sciences. In this paper, we have developed the wavelet methods to find the approximate solutions for the Fitzhugh–Nagumo (FN) and fractional FN equations. The proposed method techniques provide the solutions in rapid convergence series with computable terms. To the best of our knowledge, until now there is no rigorous wavelet solutions have been reported for the FN and fractional FN equations arising in gene propagation and model. With the help of Laplace operator and Legendre wavelets operational matrices, the FN equation is converted into an algebraic system. Finally, we have given some numerical examples to demonstrate the validity and applicability of the wavelet methods. The power of the manageable method is confirmed. Moreover, the use of the wavelet methods is found to be accurate, efficient, simple, low computation costs and computationally attractive. 相似文献