全文获取类型
收费全文 | 615篇 |
免费 | 26篇 |
国内免费 | 2篇 |
专业分类
化学 | 390篇 |
晶体学 | 6篇 |
力学 | 15篇 |
数学 | 46篇 |
物理学 | 186篇 |
出版年
2023年 | 3篇 |
2022年 | 13篇 |
2021年 | 8篇 |
2020年 | 8篇 |
2019年 | 18篇 |
2018年 | 9篇 |
2017年 | 11篇 |
2016年 | 20篇 |
2015年 | 17篇 |
2014年 | 19篇 |
2013年 | 43篇 |
2012年 | 45篇 |
2011年 | 57篇 |
2010年 | 28篇 |
2009年 | 21篇 |
2008年 | 32篇 |
2007年 | 41篇 |
2006年 | 34篇 |
2005年 | 30篇 |
2004年 | 22篇 |
2003年 | 18篇 |
2002年 | 23篇 |
2001年 | 2篇 |
2000年 | 4篇 |
1999年 | 9篇 |
1998年 | 7篇 |
1997年 | 10篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1994年 | 4篇 |
1993年 | 5篇 |
1992年 | 9篇 |
1991年 | 5篇 |
1990年 | 7篇 |
1989年 | 3篇 |
1988年 | 6篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1980年 | 2篇 |
1979年 | 7篇 |
1978年 | 4篇 |
1977年 | 8篇 |
1974年 | 1篇 |
1973年 | 3篇 |
1972年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有643条查询结果,搜索用时 31 毫秒
11.
Summary Microgram amounts of metal ions have been separated using stannic antimonate paper. Most of the separations can be accomplished within 15 minutes.
Zusammenfassung Unter Verwendung von Zinn(IV)antimonat-Papier lassen sich Mikromengen zahlreicher Metallionen trennen. Die meisten Trennungen lassen sich innerhalb 15 min durchführen.相似文献
12.
S. Padmaja V. Ramakrishnan J. Rajaram J. C. Kuriacose 《Journal of Chemical Sciences》1988,100(4):297-303
The borate radical is produced by the flash photolysis of an aqueous alkaline solution of NaBO2 and K2S2O8. The absorption spectrum of the transient borate radical shows two maxima. The self decay of this radical is second order.
Rate constants for the reactions of this radical with some organic substrates have been determined. 相似文献
13.
Various computational approaches, using molecular mechanics (Amber), semiempirical (AM1), density functional (B3LYP), and various ONIOM methods, have been comparatively investigated for the structure of Escherichia coli NifS CsdB protein. The structure of the entire monomer containing 407 amino acid residues and 579 surrounding water molecules has been optimized. The full geometry optimization in the "active site-only" approach (including only active site atoms) has been found to give the largest root-mean-square (RMS) deviation from the X-ray structure; a much better agreement has been achieved by keeping the atoms leading to the backbones of some amino acids frozen in their positions in the X-ray structure. The best agreement has been attained by including the surrounding protein in the calculations using the two-layer ONIOM (B3LYP:Amber) approach. The results presented in this study conclusively demonstrate the importance of the protein/active-site interaction on the active-site structure of the enzyme. The present theoretical study represents the largest system studied at the ONIOM level to date, containing 7992 atoms, including 84 atoms in the QM region and rest in the MM region. 相似文献
14.
In a previous DFT study a mechanism for the reductive half-reaction of pea seedling amine oxidase (PSAO) was suggested. In many of the suggested steps a lysine at the active site plays an important role. However, this lysine is not found in other amine oxidases. The primary aim of the present DFT study is therefore to investigate alternative mechanisms for those amine oxidases (CAO) where the lysine residue is not present. One of the most important roles suggested for the lysine in PSAO was to protonate the O2-site of TPQ before the critical Cbond;H bond cleavage of the substrate. In the absence of lysine the O2-site of TPQ is now suggested to be protonated by a water ligand on the copper metal complex, in line with experimental suggestions. In other steps the role of lysine is taken over by an asparagine. All results are compared with experimental observations and good agreement is generally found. 相似文献
15.
Jung Kwon Oh Jun Wu Mitchell A. Winnik Gary P. Craun Jude Rademacher Rajeev Farwaha 《Journal of polymer science. Part A, Polymer chemistry》2002,40(17):3001-3011
We describe the synthesis and characterization of three new polymerizable benzophenone derivatives [2‐acryloxy‐5‐methyl benzophenone ( 8 ), 4′‐dimethylamino‐2‐acryloxy‐5‐methyl benzophenone ( 9 ), and 4′‐dimethylamino‐2‐(β‐acryloxyethyl)oxy‐5‐methyl benzophenone ( 10 )]. We show that these monomers can successfully be incorporated into vinyl acetate (VAc) copolymer latex particles. These particles were prepared by semicontinuous emulsion polymerization and mini‐emulsion polymerization of VAc with butylacrylate (BA) for VAc/BA = 4/1 by weight. The two monomers 9 and 10 bearing the 4′‐dimethylamino group satisfy the important spectroscopic criteria required of a dye to serve as an acceptor chromophore for nonradiative energy transfer from phenanthrene (Phe) as the donor. Their UV absorption spectra suggest significant overlap with the emission spectrum of Phe, which can be incorporated into P(VAc‐co‐BA) latex through copolymerization with 9‐acryloxymethyl Phe ( 2 ). In addition, these chromophores provide a window in their absorption spectra for excitation of the Phe chromophore at 300 nm. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 3001–3011, 2002 相似文献
16.
S. Selvasekarapandian R. Sivakumar N. M. Manikandan V.M. Ragjunath V. Kannan S. Rajaram 《Journal of Radioanalytical and Nuclear Chemistry》2002,252(2):345-347
The gas collection measurement method was employed to determine radon activity concentrations in the water of Coonoor. Open well water, dam water and stream water have been investigated for their radon concentrations. It is observed that the highest radon concentration is in the open well water and the lowest in stream water. From these measurements, the corresponding annual effective ingestion dose is determined. 相似文献
17.
18.
K. J. Tony V. Mahadevan J. Rajaram C. S. Swamy 《Reaction Kinetics and Catalysis Letters》1997,62(1):105-116
Thetrans-dioxo ruthenium (VI) complex, [P(C6H5)3C6H5CH2]+[Ru(O)2OAcCl2] or tetrapropylammonium perruthenate catalyzes the oxidation of secondary alcohols to ketones byN-methylmorpholine-N-oxide (NMO). Kinetic studies showed the formation of a complex between catalyst and substrate (alcohol) as the first step
in the mechanism. 相似文献
19.
20.
Multi-ligand self-assembly to attain the AgI-N-heterocyclic carbene (NHC)-built hexanuclear organometallic cages of composition [Ag6( 3 a , b )4](PF6)6 from the reaction of benzimidazole-derived tris(azolium) salts [H3- 3 a , b ](PF6)3 with Ag2O was achieved. The molecular structures of the cages were established by X-ray diffraction studies along with NMR and MS analyses. The existence of a single assembly in solution was supported by diffusion-ordered spectroscopy (DOSY) 1H NMR spectra. Further, transmetalation reactions of these self-assembled complexes, [Ag6( 3 a , b )4](PF6)6, with CuI/AuI-ions provided various coinage metal-NHC complexes having diverse molecular compositions, which included the first example of a hexanuclear CuI-dodecacarbene complex, [Cu6( 3 b )4](PF6)6. 相似文献