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Comparative characterization of thermal isomerization rates of 6‐phenyl‐1,5‐diazabicyclo[3.1.0]hexane at convection and microwave heating 下载免费PDF全文
Tatiana A. Kornilova Rafael R. Kostikov Alexander F. Khlebnikov Igor G. Zenkevich 《Journal of Physical Organic Chemistry》2018,31(7)
Rate constants of thermal isomerization of 6‐phenyl‐1,5‐diazabicyclo[3.1.0]hexane into 1‐(benzyl)‐4,5‐dihydro‐1H‐pyrazole at convection and microwave heating in toluene and chlorobenzene (solvents) were determined within the temperature range 90°C to 120°С. These data were used for the calculation of activation parameters of isomerization. It is shown that microwave heating increases the rate constants at the same temperature by a factor of 2 to 2.5 as compared with those using convection heating. The reason is that the effective temperature of microwave heating exceeds that of convection heating by 6°C to 9°С in toluene and by 12°C to 20°С in chlorobenzene as solvent. 相似文献
13.
Rafael D. Sorkin 《Communications in Mathematical Physics》1988,115(3):421-434
The normal correlation between spin and statistics is shown to be valid for arbitrary kinks, among them theSU(n) Skyrmions forn3. It is assumed in the proof that no gauge-ambiguity attaches to the values of the underlying scalar field, and that conversely each configuration of this field is represented quantum mechanically by a Hilbert subspace of dimension precisely one.Supported in part by NSF Grant No. PHY 83-18350 相似文献
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da Silva Pedro Rafael Sena Laís Cristina Santana Silva Rubens Pedro Lorena de Santana Danielle Cristine Almeida Silva de Santana Fernando José Malagueño 《Analytical and bioanalytical chemistry》2019,411(16):3447-3461
Analytical and Bioanalytical Chemistry - This study aimed to determine simultaneously five major street cocaine adulterants (caffeine, lidocaine, phenacetin, diltiazem, and hydroxyzine) in human... 相似文献
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Nonlinear Dynamics - Introduction of stiffness nonlinearities to broaden the frequency bandwidth of vibratory energy harvesters has the adverse influence of complicating the response behavior of... 相似文献
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Guimaraes Giulia A. A. Lacerda Janiny N. Xing Yutao Ponzio Eduardo A. Pacheco Wagner F. Semaan Felipe S. Dornellas Rafael M. 《Journal of Solid State Electrochemistry》2020,24(8):1769-1779
Journal of Solid State Electrochemistry - This work presents the development and characterization of an electrochemical sensor of tin hexacyanoferrate (SnHCF), produced from the modification by... 相似文献
18.
Background
Marlin-1 is a microtubule binding protein that associates specifically with the GABAB1 subunit in neurons and with members of the Janus kinase family in lymphoid cells. In addition, it binds the molecular motor kinesin-I and nucleic acids, preferentially single stranded RNA. Marlin-1 is expressed mainly in the central nervous system but little is known regarding its cellular and subcellular distribution in the brain. 相似文献19.
Rafael O. Ruggiero 《Bulletin of the Brazilian Mathematical Society》1994,25(2):139-172
LetM be a compact Riemannian manifold with no conjugate points such that its geodesic flow is expansive. Then we show that the universal Riemannian covering ofM is a hyperbolic geodesic space according to the definition of M. Gromov. This allows us to extend a series of relevant geometric and topological properties of negatively curved manifolds toM and in particular, geometric group theory applies to the fundamental group ofM. 相似文献
20.
Lucas C. Céleri Rafael M. Gomes Radu Ionicioiu Thomas Jennewein Robert B. Mann Daniel R. Terno 《Foundations of Physics》2014,44(5):576-587
We describe a new class of experiments designed to probe the foundations of quantum mechanics. Using quantum controlling devices, we show how to attain a freedom in temporal ordering of the control and detection of various phenomena. We consider wave–particle duality in the context of quantum-controlled and the entanglement-assisted delayed-choice experiments. Then we discuss a quantum-controlled CHSH experiment and measurement of photon’s transversal position and momentum in a single set-up. 相似文献