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981.
Leszek Natkaniec Mikołaj F. Rudolf Bogusława Jeźowska-Trzebiatowska 《Theoretical chemistry accounts》1973,28(2):193-199
Results of SCCC MO calculations for the dimeric oxygen double-bridged [Mo2O4Cl4(H2O)2]2–ion are reported. On the basis of these results the previously reported spectra and magnetic properties may be explained. The strong direct molybdenum — molybdenum interaction in the Mo2O
4
2+
core was proved to exist.
Zusammenfassung Die Ergebnisse von SCCC MO-Rechnungen für das zweikernige Ion [Mo2O4Cl4(H2O)2]2– mit zweifacher Sauerstoffbrücke werden mitgeteilt. Danach können die früher angeführten magnetischen und spektralen Eigenschaften dieses Ions verstanden werden. Die Existenz starker unmittelbarer Molybdän-Molybdän Wechselwirkungen innerhalb des Mo2O 4 2+ Kerns wird nachgewiesen.
Résumé Résultats de calculs SCCCMO pour l'ion dimère Mo2O4Cl4(H2O) 2 2– . Sur la base de ces résultats les propriétés spectrales et magnétiques précédemment obtenues peuvent être expliquées. L'existence d'une forte interaction directe molybdène-molybdène dans le coeur Mo2O 4 2+ est clairement démontrée.相似文献
982.
Triphenylphosphine - iodine complex was found to be an effective reagent for deoxygenation of trisubstituted steroidal epoxides. The mechanism of the reaction is proposed. 相似文献
983.
The spectrum of internal bremsstrahlung photons has been measured for the unique first-forbidden decay of 41Ca. The experimental shape factor essentially deviates from the theoretical ones. Also, the overall photon intensity per K-capture is higher than predicted. 相似文献
984.
Ewa Skrzypczak-Jankun Andrzej Hoser Elżbieta Grzesiak Zygmunt Kałuski Maria D. Rozwadowska 《Journal of chemical crystallography》1979,9(5):233-244
Both of the title compounds crystallize in the monoclinic system: C23H17NO2 (Ib),P21/c,a = 8.970(1),b = 22.629(5),c = 9.101(1) Å, = 106.08(1) °,Z = 4,D
x
= 1.27 Mg m–3; C19H17NO2 (Ic),P21/a,a = 15.225(2),b = 6.429(1),c = 17.190(1) Å, = 112.99(1) °,Z = 4,D
x
= 1.25 Mg m–3. The structures were solved and refined by standard methods, both toR 0.04. In compound Ib, a weak intramolecular interaction is observed between the nitrogen atom from the isoquinoline ring and the carbon atom from the carbonyl group, with the N(2) . C(18)distance being 2.98 Å. In compound Ic, the PhCO2 -fragment is twisted in the opposite direction to that in compound Ib, without hydrogen bonding. The pK
a
and IR data were considered in the light of the results of the X-ray investigation. 相似文献
985.
The coalescence and reseparation model has been used to calculate trajectories of the 12C + 40Ca, 9Be + 40Ca and 6Li + 40Ca collisions which lead to symmetric splitting. A fusion-fission mechanism is suggested by the model. Comparison with experimental data locates the reaction angular momentum window in the region of superdeformed nuclei. 相似文献
986.
Jan J. Skławianowski 《Reports on Mathematical Physics》1985,22(3):323-371
We present some philosophical and physical arguments supporting the hypothesis that the most fundamental self-interacting field in an amorphous space-time is the field of linear frames, i.e. the quadruple of vector bosons. We construct a wide class of Lagrangian dynamical models invariant under the total group of diffeomorphisms and under the natural action of the proper linear group GL+ (4, R) on the tetrad field. There exist some links between these models and the Hamiltonian dynamical systems on GL+ (3, R) (the mechanics of affinely-rigid bodies [23] [27]). We present the general form of field equations, conservation laws and Bianchi identities. There exist some formal similarities between our Lagrangians and those used in non-linear electrodynamics, in particular in the Born–Infeld theory [21]. We also give a few rough remarks concerning models invariant under natural subgroups of GL+ (4, R), i.e. under SL(4, R) and SO(1, 3; R) (special linear group and Lorentz group). The latter class includes the conventional Einstein relativity and the more general metrical-parallelism models. It turns out that there are GL+ (4, R)-invariant Lagrangians which are structurally alike the conventional Einstein Lagrangian.We have not derived as yet either mathematical or physical consequences of the presented model. Nevertheless, it seems to follow from our discussion that, a priori, the GL+ (4, R)-invariant tetrad models could be competitive with the Einstein theory. The next thing to be done would be a careful mathematical analysis of these models and attempts to compare their consequences with those of the Einstein relativity and of other field theories. 相似文献
987.
988.
T. Bałaban 《Communications in Mathematical Physics》1985,98(1):17-51
Usually renormalization group transformations are defined by some averaging operations. In this paper we study such operations for lattice gauge fields and for gauge transformations. We are interested especially in characterizing some classes of field configurations on which the averaging operations are regular (e.g., analytic). These results will be used in subsequent papers on the renormalization group method in lattice gauge theories.Research supported in part by the National Science Foundation under Grant PHY-82-03669 相似文献
989.
Michał Praszałowicz 《Physics letters. [Part B]》1985,158(3):264-269
We find that the realistic baryon mass spectrum in the SU(3) Skyrme model with massive 0? mesons can be obtained only for Fπ < 70 MeV. We fit mΛ and and obtain baryon masses within the limits of ± 16% of the experimental val ues, but at the expense of very low ifFπ=46.32 MeV. 相似文献
990.
J. Zioło 《Chemical physics letters》1980,70(3):563-564
The results of measurements of Δ/E2 as a function of concentration for CCl4 solutions of iodobenzene are given and compared with earlier results for CCl4 solutions of fluoro-, chloro- and bromo-benzene. Terms contributing to the molar saturation constant for pure halogeno-derivatives of benzene have been calculated, using Kielich's theory. The change of sign of Δ/E2 for bromo- and iodo-benzene is explained. 相似文献