Piezoelectric and elastic properties of ZnF2–PbO–TeO2: TiO2 glass ceramics

Piezoelectric coefficients d₃₃ as well as ultrasonic velocities and elastic coefficients of ZnF₂–PbO–TeO₂ glasses crystallized with different concentrations of TiO₂ (0.5 to 2.0 wt.%) were measured. The contribution to the piezoelectric coefficients is attributed to presence of Pb₅Ti₃F₁₉, PbTiO₃ and PbTeO₃ ferroelectric crystal phases. The piezoelectric coefficients show substantial sensitivity to presence of TiO₂. The ultrasonic velocities and the related elastic coefficients in these glass ceramics as a functions of concentration of nucleating agent TiO₂ exhibited minimal effect at 1.0 wt.%. This is ascribed to the larger presence of titanium ions in Ti³⁺ states which act as modifiers and finally de-polymerize glass ceramic network. The results have been further discussed quantitatively within a framework of different oxidation states of titanium ions and the nature of the crystal phases ingrained in the glass ceramic.     

Modelling of gearbox dynamics under time-varying nonstationary load for distributed fault detection and diagnosis

Fault detection and diagnosis in mechanical systems during their time-varying nonstationary operation is one of the most challenging issues. In the last two decades or so researches have noticed that machines work in nonstationary load/speed conditions during their normal operation. Diagnostic features for gearboxes were found to be load dependent. This was experimentally confirmed by a smearing effect in the spectrum.In order to better understand the involved phenomena and to ensure agreement between simulation and experimental results, two models of gearboxes (a fixed-axis two-stage gearbox and a planetary gearbox) operating under varying load conditions are proposed. The models are based on two mechanical systems used in the mining industry, i.e. the belt conveyor and the bucket wheel excavator. An original transmission error function expressing changes in technical condition and load variation is presented.Energy based parameters (the signal RMS value or the arithmetic sum of the amplitudes of spectral gearmesh components) are adopted as the diagnostic features. Simulation results show a strong correlation between load values, changes in condition and the diagnostic features. The findings are key to condition monitoring. Thanks to the use of the models one can better understand the phenomena identified through an analysis of vibration signals captured from real machines.     

Electrocrystallization of silver nanoparticles from silver halides in polypyrrole evidenced by their SERS activity—thermodynamic and kinetic conditions

Journal of Solid State Electrochemistry - Silver(I) halide particles embodied in polypyrrole matrices are synthesized and further processed electrochemically to get nanoparticles of silver with...     

Time resolved photoluminescence near the “band gap” in amorphous silicon

Two broad luminescence bands in weakly hydrogenated (glow discharge) undoped amorphous silicon have been observed using time resolved spectroscopy on a nanosecond timescale. Whereas the luminescence decay of the low energy band has been found to be sample independent, the peak position of the luminescence does show a sample dependence. We propose an intrinsic origin of this luminescence.     

Diazo group electrophilicity in kinamycins and lomaiviticin A: potential insights into the molecular mechanism of antibacterial and antitumor activity

Theoretical and chemical studies of the reactivity of isoprekinamycin, the kinamycins, and the lomaiviticins support the proposal that these natural products exhibit enhanced diazonium salt character and may owe their antitumor antibiotic properties to their ability to act as electrophilic azo-coupling agents in vivo.     

Synthesis and molecular and electronic structure of an unusual paramagnetic borohydride complex Mo(NAr)2(PMe3)2(eta2-BH4)

Reaction of Mo(NAr)2Cl2(DME) (Ar=2,6-C6H3iPr2, DME=1,2-dimethoxyethane) with NaBH4 and PMe3 in THF formed the paramagnetic Mo(V) d1 borohydride complex Mo(NAr)2(PMe3)2(eta2-BH4) (1). Compound 1, which was characterized by EPR spectroscopy and X-ray diffraction analysis, provides a rare example both of a paramagnetic bis(imido) group 6 compound and a structurally characterized molybdenum borohydride complex. Density functional theory calculations were used to determine the electronic structure and bonding parameters of 1 and showed that it is best viewed as a 19 valence electron compound (having a primarily metal-based SOMO) in which the BH4- ligand behaves as a sigma-only, 2-electron donor.     

Ein stabilisiertes Netzgerät hoher Güte mit Transistoren

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