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排序方式: 共有193条查询结果,搜索用时 140 毫秒
21.
B. Ravindran G. Madhurambal M. Mariappan K. Ramamurthi S. C. Mojumdar 《Journal of Thermal Analysis and Calorimetry》2011,104(3):909-914
Single crystals of mercury cinnamate were grown by slow evaporation of methanol solution at room temperature. The effect of
mercury on the electronic structure of cinnamic acid was studied. The grown mercury cinnamate single crystals were characterized
by UV, FTIR and TG-DTA. TG curve of mercury cinnamate exhibits higher thermal stability compared with cinnamic acid which
was also confirmed by DTA curve. The spectroscopic studies give evidences of the distribution of the electronic charge in
molecule, the delocalisation of π electrons and the reactivity of metal complexes. The Second harmonic generation efficiency
is more pronounced in the presence of mercury dopant in the growth medium. 相似文献
22.
23.
Thin films of antimony doped tin oxide (SnO2:Sb) were prepared by spray pyrolysis technique using SnCl2 as precursor with the various antimony doping levels ranging from 1 to 4 wt%. The XRD analysis showed that the undoped SnO2 films grow in (211) preferred orientation whereas the Sb doped films grow in (200) plane. Scanning electron microscopy studies indicated that the surface of the films prepared with lower doping level (1 wt%) consists of larger grains whereas those prepared with higher doping levels (>1 wt%) consist of smaller grains. The sheet resistance has been found to be reduced considerably (2.17 Ω/□) for Sb doped films. To the best of our knowledge this is the lowest sheet resistance obtained for Sb doped SnO2 thin films. 相似文献
24.
Athar Ata Joe Ackerman Abdelhamid Bayoud Parvataneni Radhika 《Helvetica chimica acta》2004,87(3):592-597
From the methanolic extract of Cladiella sp., collected from the Andaman Island, India, a new sesquiterpene, cladidiol ( 2 ), and three known diterpenes, cladiellaperoxide ( 3 ), (6E)‐2α,9α‐epoxyeunicella‐6,11(12)‐dien‐3β‐ol ( 4 ), and polyanthellin A ( 5 ) were isolated. The structures of these compounds were established by extensive spectroscopic studies. Compound 2 exhibited modest acetylcholinesterase‐inhibition activity, and compounds 3 – 5 showed antibacterial activities against Streptococcus pyogenes, Escherichia coli, and Pseudomonas aeruginosa. 相似文献
25.
The notion of a split coloring of a complete graph was introduced by Erd?s and Gyárfás [ 7 ] as a generalization of split graphs. In this work, we offer an alternate interpretation by comparing such a coloring to the classical Ramsey coloring problem via a two‐round game played against an adversary. We show that the techniques used and bounds obtained on the extremal (r,m)‐split coloring problem of [ 7 ] are closer in nature to the Turán theory of graphs rather than Ramsey theory. We extend the notion of these colorings to hypergraphs and provide bounds and some exact results. © 2002 Wiley Periodicals, Inc. J Graph Theory 40: 226–237, 2002 相似文献
26.
The base-catalyzed condensation of p-tbutylphenol and formaldehyde, which yields a cyclic octamer (I, n=8) as the major product, has been shown to also yield a cyclic tetramer (I, n=4) and a bischomooxa cyclic tetramer (II). 相似文献
27.
Nor Aiyyuhal Jemali Hasan Abu Kassim V. Radhika Devi Keshav N. Shrivastava 《Journal of Non》2008,354(15-16):1744-1750
We have used the density functional theory to make the models of GexSe1?x glass for which the energy is a minimum. The clusters, Ge2Se2, Ge2Se3, Ge3Se, Ge3Se2, Ge4Se, GeSe3, GeSe4, chain mode zig-zag Ge4Se3, corner sharing GeSe4, and edge sharing Ge2Se6, have been made successfully and their vibrational spectra have been calculated from the first principles. We are able to optimize the bond distances as well as the bond angles. The calculated values of the frequencies of vibrations of the various clusters have been compared with those obtained from the experimental Raman spectra of actual glasses, GexSe1?x(0 < x < 0.3). The local concentration, x within 0.25 nm is nonuniform in the amorphous material. When the same cluster occurs in two stable configurations, low frequency vibrations of frequency, ν < 100 cm?1, are found. The corner sharing GeSe4 has low frequency modes at 54 cm?1 and 93 cm?1 whereas these modes disappear in the pyramidal configuration. The low frequency modes are therefore associated with the breaking of C4 symmetry of the pyramidal configuration. The computed vibrational frequencies of clusters Ge3, Ge4Se3, Ge2Se3, GeSe3 and Ge3Se2 are actually present in the Raman spectra of the glass, GexSe1?x(0 < x < 0.3). 相似文献
28.
Russian Journal of Organic Chemistry - The present work describes the synthesis of 4-amino-6-(2-benzylidenehydrazinyl)-pyrimidine-5-carbonitrile derivatives,... 相似文献
29.
Balakrishnan T Babu RR Ramamurthi K 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2008,69(4):1114-1118
Single crystals of gamma-glycine were grown from a mixture of glycine, water and lithium bromide. Single crystal X-ray diffraction analysis confirmed the growth of gamma-glycine phase. Presence of various functional groups of gamma-glycine was identified by FTIR spectrum. Optical absorbance spectrum recorded in the wavelength range of UV-vis-NIR revealed that this crystal has good optical transparency in the range 250-1500 nm. Vickers microhardness values were estimated on the prominent (100) face. Thermogravimetric and differential scanning calorimetric analyses were carried out to study the thermal properties of gamma-glycine. Second harmonic generation efficiency of the crystal measured by Kurtz's powder method using Nd:YAG laser is about three times that of KDP. 相似文献
30.
Glycolic acid was polymerized under vacuum in the presence and absence of nano sized clay.The added clay catalyzed the condensation polymerization which can be confirmed by recording FTIR spectroscopy and intrinsic viscosity (Ⅳ)values.The relative intensity of C=O/CH is increased while increasing the amount of clay.DSC showed the appearance of multiple endotherms of poly(glycolic acid).TGA showed the percentage weight residue remain above 750℃for polymer-nano composite system was 21% and hence proved the... 相似文献