5,5-Diaryldipyrromethanes: syntheses and anion binding properties

A two-step synthesis of 5,5-diaryldipyrromethanes in good yields is described. The adopted synthetic strategy can be used to tune the substituent at the meso-carbon very easily by choosing the Grignard reagent of interest. Further, the influence of the incorporation of various diaryl units at the meso-carbon atom in the inherent anion binding affinities of the dipyrromethanes through hydrogen bonding was discussed.     

A Facile Photochemical Synthesis of 12H-Benzothiazolo [2,3-b]Quinazolin-12-Ones

The photochemical synthesis of 12H-benzothiazolo [2,3-b]quinazolin-12-ones (4) by the irradiation of 2-thioquinazolinediones 1 and disulphide 5 are described.     

Localized coherent structures of (2+1) dimensional generalizations of soliton systems

We briefly review the recent progress in obtaining (2+1) dimensional integrable generalizations of soliton equations in (1+1) dimensions. Then, we develop an algorithmic procedure to obtain interesting classes of solutions to these systems. In particular using a Painlevé singularity structure analysis approach, we investigate their integrability properties and obtain their appropriate Hirota bilinearized forms. We identify line solitons and from which we introduce the concept of ghost solitons, which are patently boundary effects characteristic of these (2+1) dimensional integrable systems. Generalizing these solutions, we obtain exponentially localized solutions, namely the dromions which are driven by the boundaries. We also point out the interesting possibility that while the physical field itself may not be localized, either the potential or composite fields may get localized. Finally, the possibility of generating an even wider class of localized solutions is hinted by using curved solitons.     

Incorporating Mathematics into the Science Program of Students Labeled “At‐Risk”

Twenty three at‐risk high school female students who had failed mathematics and science in a traditional school setting were the subjects of this study that integrated mathematics and science lessons over a period of four weeks. Using a combination of direct instruction, calculations, graphing, hands‐on projects, and discussion, the topic of mechanical advantage was studied, to find out how well students understood the topic. The study found that these students who initially knew very little about mechanical advantage, and who did not see any need to use mathematics in the study of science, indicated an increased understanding of mechanical advantage, and also seemed to realize that integrating mathematics and science enhanced learning.     

Some open problems in the physics of disordered systems

Some problems in the physics of disordered systems are pointed out; most of these arise from experiments.     

Comparing stimulus-frequency otoacoustic emissions measured by compression, suppression, and spectral smoothing

Stimulus-frequency otoacoustic emissions (SFOAEs) have been measured in several different ways, including (1) nonlinear compression, (2) two-tone suppression, and (3) spectral smoothing. Each of the three methods exploits a different cochlear phenomenon or signal-processing technique to extract the emission. The compression method makes use of the compressive growth of emission amplitude relative to the linear growth of the stimulus. The emission is defined as the complex difference between ear-canal pressure measured at one intensity and the rescaled pressure measured at a higher intensity for which the emission is presumed negligible. The suppression method defines the SFOAE as the complex difference between the ear-canal pressure measured with and without a suppressor tone at a nearby frequency. The suppressor tone is presumed to substantially reduce or eliminate the emission. The spectral smoothing method involves convolving the complex ear-canal pressure spectrum with a smoothing function. The analysis exploits the differing latencies of stimulus and emission and is equivalent to windowing in the corresponding latency domain. Although the three methods are generally assumed to yield identical emissions, no equivalence has ever been established. This paper compares human SFOAEs measured with the three methods using procedures that control for temporal drifts, contamination of the calibration by evoked emissions, and other potential confounds. At low stimulus intensities, SFOAEs measured using all three methods are nearly identical. At higher intensities, limitations of the procedures contribute to small differences, although the general spectral shape and phase of the three SFOAEs remain similar. The near equivalence of SFOAEs measured by compression, suppression, and spectral smoothing indicates that SFOAE characteristics are not mere artifacts of measurement methodology.