Synthesis and characterization of ZSM-8-type zeolite crystals

Procedure for hydrothermal synthesis of ZSM-8-type zeolite crystals, using TEA—OH as a template, in the system having molar composition 16.2 (Na₂O) — Al₂O₃ — 117 (SiO₂) — 4.8 (TEA)₂O — 3887 H₂O at 170 °C is described. Results of characterization of these crystals by XRD, IR, EDAX, SEM, TGA, and adsorption studies are described and discussed. X-ray diffraction studies establish that the crystals are ZSM-8-type with structure similar to that of ZSM-5-type crystals. Crystals have prismatic bipyramidal morphology with average size 18–25 microns. Degased calcined samples adsorb xylenes in the order p > m > 0. Pore length per unit cell, estimated from n-hexane adsorption studies, is 46 Å.     

Field dependence of hole mobility in TPD-doped polystyrene

Field and temperature dependence of hole mobility in N,N^′-diphenyl-N,N^′-bis(3-methylphenyl)-(1,1′-biphenyl)-4,4′-diamine (TPD) doped in polystyrene (PS) is studied using the transient photoconductivity technique. We observe both the positive and negative field dependence of mobility with increasing field and temperature. The field and temperature at which negative field dependence begins is low compared with earlier reports on similar systems (with 20 wt% dopant concentration). Results are discussed on the basis of the Gaussian disorder model (GDM), which predicts that the interplay of both the energetic and positional disorder of dopant molecules in the sample decides the slope of the logμ versus E^1/2 plot. The observed mobility dependence is rationalized on the basis of low energetic disorder in the sample. The reason for low energetic disorder is purely due to the film morphology of the sample. Even for a dopant concentration of 20 wt%, we observe clustering and chaining of TPD molecules, which may provide low energetic and positional disorder.     

Molecular constants for NSCl and NSF

The complete infrared spectrum of gaseous NSCl, including the hitherto unobserved ν₃, is reported. A set of force constants for gaseous NSCl consistent with a number of pieces of independent data such as the isotopic shifts (¹⁴N³²S³⁵Cl, ¹⁵N³²S³⁵Cl, ¹⁴N³²S³⁷Cl, ¹⁵N³²S³⁷Cl, ¹⁴N³⁴S³⁵Cl and ¹⁵N³⁴S³⁵Cl), centrifugal distortion constants (¹⁴N³²S³⁵Cl), and the inertia defect (¹⁴N³²S³⁵Cl) has been computed. Also, the force field of NSF has been redetermined using the vibrational frequencies and the centrifugal distortion constants.     

ZnS/Fe2O3/Ag Ternary Nanocomposite Photocatalyst for the Degradation of Dyes Under Visible Light

Russian Journal of Physical Chemistry A - Recently the researchers have shown great interest on photocatalysis, especially in dyes degradation by nanocomposites under visible light. In this work,...     

Novel Etodolac-Based 1,2,4-Triazole Derivatives as Antimicrobial Agents: Synthesis,Biological Evaluation,and Molecular Docking Study

Russian Journal of Organic Chemistry - A series of novel 1,2,4-triazole nonsteroidal anti-inflammatory drugs (NSAIDs) derived from etodolac were designed and synthesized. The synthesized compounds...     

Effect of random density irregularities on nonlinear evolution of Langmuir waves in interplanetary medium

The evolution of nonlinear Langmuir waves in the interplanetary medium is investigated by appropriately accounting for the random density irregularities of the medium. A pair of modified Zakharov equations, which describe these waves, is solved numerically as an initial value problem for large scale (≫ 10² km) initial pertubations. For an ion acoustic-Langmuir solitary wave, the random irregularities damp the Langmuir wave by way of scattering and let the ion density perturbation radiate away in a few days. However an initial solitary or shock-like Langmuir wave excites the ion density perturbations within a fraction of a second, and then itself gets damped. These effects will strongly decelerate the collapse of large scale Langmuir waves. The possibility of detecting these processes, by means of interplanetary scintillation, is discussed. The authors felicitate Prof. D S Kothari on his eightieth birthday and dedicate this paper to him on this occasion.     

Some results on λ‐designs with two block sizes

A λ‐design is a family ?? = {B₁, B₂, …, B_v} of subsets of X = {1, 2, …, v} such that |B_i∩B_j| = λ for all i≠jand not all B_i are of the same size. The only known example of λ‐designs (called type‐1 designs) are those obtained from symmetric designs by a certain complementation procedure. Ryser [J Algebra 10 (1968), 246–261] and Woodall [Proc London Math Soc 20 (1970), 669–687] independently conjectured that all λ‐designs are type‐1. Let g = gcd(r ? 1, r^* ? 1), where rand r^* are the two replication numbers. Ionin and Shrikhande [J Combin Comput 22 (1996), 135–142; J Combin Theory Ser A 74 (1996), 100–114] showed that λ‐designs with g = 1, 2, 3, 4 are type‐1 and that the Ryser–Woodall conjecture is true for λ‐designs on p + 1, 2p + 1, 3p + 1, 4p + 1 points, where pis a prime. Hein and Ionin [Codes and Designs—Proceedings of Conference honoring Prof. D. K. Ray‐Chaudhuri on the occasion of his 65th birthday, Ohio State University Mathematical Research Institute Publications, 10, Walter de Gruyter, Berlin, 2002, pp. 145–156] proved corresponding results for g = 5 and Fiala [Codes and Designs—Proceedings of Conference honoring Prof. D. K. Ray‐Chaudhuri on the occasion of his 65th birthday, Ohio State University Mathematical Research Institute Publications, 10, Walter de Gruyter, Berlin, 2002, pp. 109–124; Ars Combin 68 (2003), 17–32; Ars Combin, to appear] for g = 6, 7, and 8. In this article, we consider λ designs with exactly two block sizes. We show that in this case, the conjecture is true for g = 9, 11, 12, 13, 15, 16, 17, 19, 20, 21, and for g = 10, 14, 18, 22 with v≠4λ ? 1. We also give two results on such λ‐designs on v = 9p + 1 and 12p + 1 points, where pis a prime. © 2010 Wiley Periodicals, Inc. J Combin Designs 19:95‐110, 2011     

Physical properties of LiMn2O4 spinel prepared at moderate temperature

A moderate-temperature method of preparation of the spinel LiMn₂O₄ was developed around 500 °C. Physical features of the products were identified by X-ray photoelectron spectroscopy, X-ray diffractometry, Raman scattering and FTIR spectroscopy. The electronic conductivity of LiMn₂O₄ has been studied as a function of annealing temperature. The product LiMn₂O₄ is identified as a micron-sized powder and analysis of the local environment is in good accordance with the classical structural model of Fd3m space group. LiMn₂O₄ exhibits an electrical conductivity of 1.9×10⁻⁵ S/cm at room temperature with an activation energy of 0.16 eV which corresponds to an electron hopping mechanism between the two charge states of Mn³⁺ and Mn⁴⁺ ions. A first-order phase transition is observed at 292 K.     

Embeddings of anisotropic Sobolev spaces on unbounded domains

Summary Integral representations of junctions in the anisotropic Sobolev spaces on unbounded domains are used in the study of the embeddings of these spaces into Lebesgue spaces. Estimates of entropy numbers of the embedding are obtained, where k, p and q satisfy certain conditions and where is a certain type of quasibounded domain,