全文获取类型
收费全文 | 2415篇 |
免费 | 94篇 |
国内免费 | 1篇 |
专业分类
化学 | 1456篇 |
晶体学 | 15篇 |
力学 | 110篇 |
数学 | 539篇 |
物理学 | 390篇 |
出版年
2023年 | 15篇 |
2022年 | 17篇 |
2021年 | 39篇 |
2020年 | 39篇 |
2019年 | 42篇 |
2018年 | 60篇 |
2017年 | 54篇 |
2016年 | 75篇 |
2015年 | 80篇 |
2014年 | 111篇 |
2013年 | 208篇 |
2012年 | 183篇 |
2011年 | 191篇 |
2010年 | 112篇 |
2009年 | 76篇 |
2008年 | 169篇 |
2007年 | 168篇 |
2006年 | 143篇 |
2005年 | 111篇 |
2004年 | 90篇 |
2003年 | 75篇 |
2002年 | 78篇 |
2001年 | 25篇 |
2000年 | 27篇 |
1999年 | 24篇 |
1998年 | 21篇 |
1997年 | 6篇 |
1996年 | 25篇 |
1995年 | 19篇 |
1994年 | 19篇 |
1993年 | 13篇 |
1992年 | 10篇 |
1991年 | 9篇 |
1990年 | 11篇 |
1989年 | 6篇 |
1987年 | 5篇 |
1986年 | 6篇 |
1985年 | 18篇 |
1984年 | 10篇 |
1983年 | 7篇 |
1982年 | 9篇 |
1981年 | 10篇 |
1980年 | 12篇 |
1979年 | 11篇 |
1978年 | 12篇 |
1977年 | 6篇 |
1976年 | 11篇 |
1974年 | 7篇 |
1973年 | 5篇 |
1966年 | 4篇 |
排序方式: 共有2510条查询结果,搜索用时 0 毫秒
61.
Kyoung-Sook?MoonEmail author Anders?Szepessy Raúl?Tempone Georgios E.?Zouraris 《Numerische Mathematik》2003,96(1):131-152
Summary A variational principle, inspired by optimal control, yields a simple derivation of an error representation, global error=local errorweight, for general approximation of functions of solutions to ordinary differential equations. This error representation is then approximated by a sum of computable error indicators, to obtain a useful global error indicator for adaptive mesh refinements. A uniqueness formulation is provided for desirable error representations of adaptive algorithms.
Mathematics Subject Classification (2000):65L70, 65G50This work has been supported by the EU–TMR project HCL # ERBFMRXCT960033, the EU–TMR grant # ERBFMRX-CT98-0234 (Viscosity Solutions and their Applications), the Swedish Science Foundation, UdelaR and UdeM in Uruguay, the Swedish Network for Applied Mathematics, the Parallel and Scientific Computing Institute (PSCI) and the Swedish National Board for Industrial and Technical Development (NUTEK). 相似文献
62.
Raúl Machado 《Frontiers of Physics》2014,9(4):490-510
The influence of the use of the generalized Hermite polynomial on the Hermite-based lattice Bofiz- mann (LB) construction approach, lattice sets, the thermal weights, moments and the equilibrium distribution function (EDF) are addressed. A new moment system is proposed. The theoretical possibility to obtain a unique high-order Hermite-based singel relaxation time LB model capable to exactly inatch some first hydrodynamic inoments thermally i) on-Cartesian lattice, ii) with thermal weights in the EDF, iii) whilst the highest possible hydrodynamic moments that are exactly reatched are obtained with the shortest on-Cartesian lattiee sets with some fixed real-valued temperatures, is also analyzed. 相似文献
63.
Hamid-Reza Fanaï 《Geometriae Dedicata》2000,80(1-3):187-200
In this text, we consider the solvmanifolds obtained by an abelian extension of two-step nilmanifolds and obtain Einstein metrics (with negative scalar curvature) near to the symmetric spaces. 相似文献
64.
Motivated by the long-standing unresolved enigma of the relaxor ferroelectric ground state, we performed a high-resolution heat capacity and polarization study of the field-induced phase transition in the relaxor ferroelectric single crystal Pb(Mg_{1/3}Nb_{2/3})O_{3} (PMN) oriented along the [110] direction. We show that the discontinuous evolution of polarization as a function of the electric field or temperature is a consequence of a true first order transition from a glassy to ferroelectric state, which is accompanied by an excess heat capacity anomaly and released latent heat. We also find that in a zero field there is no ferroelectric phase transition in bulk PMN at any temperature, indicating that the nonergodic dipolar glass phase persists down to the lowest temperatures. 相似文献
65.
The purpose of this paper is to investigate the eight-dimensional non-associative unital division algebras {0}≠A over finite fields, admitting elementary abelian 2-group of automorphisms E≤Aut(A), of order 8, using tools from algebraic geometry. 相似文献
66.
A novel method for cobalt preconcentration by cloud point extraction with on-line phase separation in a PTFE knotted reactor and further determination by electrothermal atomic absorption spectrometry (ETAAS) is proposed. The cloud point system was formed in the presence of non-ionic micelles of polyethyleneglycolmono-p-nonylphenylether (PONPE 7.5) and it was retained on the inner walls of a knotted reactor (KR). The surfactant rich-phase was removed from the knotted reactor with 75 microL of methanol acidified with 0.8 mol L(-1) nitric acid, directly into the dosing hole of the L'Vov graphite tube. An enrichment factor of 15 was obtained with a preconcentration time of 60 s, with respect to the direct determination of cobalt by ETAAS in aqueous solutions. The value of the detection limit for the preconcentration of 5 mL of sample solution was 10 ng L(-1). The precision, expressed as the relative standard deviation (R.S.D.), for 10 replicate determinations at 0.5 microg L(-1) Co level was 4.5%. Verification of the accuracy was carried out by analysis of a standard reference material (NIST SRM 1640e "Trace elements in natural water"). The method was successfully applied to the determination of cobalt in drinking water samples. 相似文献
67.
[structures: see text] We studied the conformation of a series of primary amides in a solution of chloroform. Classical NMR tools such as dilution experiments, influence of DMSO, and 2D-NOESY, together with X-ray diffraction, were combined with an analysis of the difference of the chemical shift Deltadelta between the geminal amidic protons. This study was addressed in order to understand the conformation adopted by hydrazino acetamides 1a and 1b as model compounds for aza-beta3-peptides. In this manner, it was possible to show that the amidic group of these compounds acts as a H-bond donor and interacts with two different H-bond acceptors. We concluded that the hydrazinoturn, a specific bifurcated H-bond system observed in the solid state, is also the preferred conformation of hydrazino acetamides 1a and 1b in solution. Our results show that the short-range interaction with the N(alpha)-nitrogen lone pair not only stabilizes the C8 pseudocycle but could also contribute to the folding process of aza-beta3-peptides. In light of this, it could explain why aza-beta3-peptides develop a different H-bond network in comparison to their isosteric beta3-peptides analogues. Our work is in keeping with the recent interest of hydrazino peptides as an extension of the beta-peptide concept. 相似文献
68.
Dr. Sarah Desmons Yu Zhou Dr. Dan Zhang Dr. Carlos Jarava-Barrera Dr. Anaïs Coffinet Dr. Antoine Simonneau Dr. Laure Vendier Prof. Dr. Gen Luo Dr. Sébastien Bontemps 《European journal of organic chemistry》2023,26(30):e202300525
The hydroboration of CO2 into bis(boryl)acetal (BBA) compounds is an important transformation, since it enabled to selectively reduce CO2 by 4e- and to subsequently use the BBA compounds as C1 and Cn sources. However, the influence of the nature of the boryl moieties on the reactivity of BBA compounds has not been evaluated so far. In the present study, four BBA compounds – including two new ones – were reacted with 2,6-diisopropylaniline to afford the expected imine. Significant differences in the rate of the reaction from minutes to weeks have been observed depending on the BBA used, showing the importance of the nature of the boryl moieties. Theoretical investigations enabled to propose a mechanism involving the addition of the aniline to the BBA as the rate-determining step and to determine that the steric hindrance of the BBA compounds is the main factor driving the rate of this condensation reaction. 相似文献
69.
Hernández C Fernández M Quejido AJ Sánchez DM Morante R Martín R 《Analytica chimica acta》2006,571(2):279-287
Isotope dilution-thermal ionisation mass spectrometry (ID-TIMS) analysis has been applied to the determination of tin in a fly ash sample supplied by the EC Joint Research Centre (Ispra, Italy). The proposed procedure includes the silica gel/phosphoric acid technique for tin thermal ionisation activation and a strict heating protocol for isotope ratio measurements. Instrumental mass discrimination factor has been previously determined measuring a natural tin standard solution. Spike solution has been prepared from 112Sn-enriched metal and quantified by reverse isotope dilution analysis. Two sample aliquots were spiked and tin was extracted with 4.5 M HCl during 25 min ultrasound exposure time. Due to the complex matrix of this fly ash material, a two-step purification stage using ion-exchange chromatography was required prior TIMS analysis. Obtained results for the two sample-spike blends (10.11 ± 0.55 and 10.50 ± 0.64 μmol g−1) are comparable, both value and uncertainty. Also a good reproducibility is observed between measurements. The proposed ID-TIMS procedure, as a primary method and due to the lack of fly ash reference materials certified for tin content, can be used to validate more routine methodologies applied to tin determination in this kind of samples. 相似文献
70.
Guiffo-Soh G Hernandez B Coïc YM Boukhalfa-Heniche FZ Fadda G Ghomi M 《The journal of physical chemistry. B》2008,112(4):1282-1289
Circular dichroism (CD) and Raman scattering were applied to the aqueous solution of minimalist LK peptides constructed with successive KL repeats leading to the following generic primary sequence: (KL)nK. Three peptides of this family, a 3-mer (n=1), a 9-mer (n=4), and a 15-mer (n=7), are analyzed in this report. Raman spectra of the 3-mer (KLK, a random chain) and its labile-hydrogen deuterated species yield a set of interesting information for analyzing longer peptides of this series. Although the CD spectrum of the 9-mer (KLKLKLKLK) reveals a signal traditionally assigned to a random structure, the corresponding Raman spectrum allows finding a mixture of conformations in solution, adopting predominantly beta-type structures. This fact proves the utility of Raman spectroscopy to eliminate eventual ambiguity concerning conformational assignments in peptides based only on the use of CD technique. Finally, the 15-mer (KLKLKLKLKLKLKLK) gives rise to CD and Raman spectra clearly assignable to a beta-type structure. On the basis of all the observed results on the 15-mer, we can confirm that this peptide may exist as isolated beta-strands at low concentration (sub-micromolar), flat-oriented at the air/water interface, whereas at high concentrations (millimolar), non-H-bonded immersible aggregates might be formed. A hypothetical model for these beta-strand aggregates could be proposed as stabilized by an interior hydrophobic core and a hydrophilic external face, formed by leucine and lysine side chains, respectively. 相似文献