Microstructural effects on shear instability and shear band spacing

A constitutive relation that accounts for the thermally activated dislocation motion and microstructure interaction is used to study the stability of a homogeneous solution of equations governing the simple shearing deformations of a thermoviscoplastic body. An instability criterion and an upper bound for the growth rate of the infinitesimal deformations superimposed on the homogeneous solution are derived. By adopting Wright and Ockendon's postulate, i.e., the wavelength of the dominant instability mode with the maximum growth rate determines the minimum spacing between shear bands, the shear band spacing is computed. The effect of the initial dislocation density, the nominal strain-rate, and parameters describing the initial thermal activation and the initial microstructure interaction on the shear band spacing are delineated.     

Cluster model electronic structure calculations for the ideal and hydrogen chemisorbed Si (100) surfaces

The electronic structure of the ideal and hydrogen chemisorbed Si(100) surfaces is calculated using the self-consistent scattered-wave cluster model. The results are presented for total and local density of states. These are compared with experiments and other calculations, where available.     

Mechanoluminescence excitation in alkali halide crystals and colouration decay in microcrystalline powders

The mechanoluminescence (ML) of NaCl, NaBr, NaF, LiCl and LiF crystals ceases at 105, 58, 170, 151 and 175°C respectively. Both the temperatureT _c at whichML disappears and the temperatureT _s required to induce a particular percentage of colouration decay in a given time, decreases with increasing nearest neighbour distance in alkali halide crystals. This perhaps suggests that similar processes cause the disappearance ofml in alkali halide crystals and the colouration decay in their microcrystalline powders. It is shown that mobile dislocations may cause the leakage of surface charge and the decay of colouration in microcrystalline powders.     

Adsorbate band formation: The chemisorption of CO on Pd (100)

In ordered overlayers of adsorbed gases on metal surfaces, high coverage situations can lead to overlap between orbitals on adjacent species and hence to adsorbate band formation. We conclusively demonstrate the existence of this effect in chemisorption by examining the dispersion of the 4α level in the u.v. photoelectron spectrum of the CO/Pd (100) system. The results agree well with a first principles extended tight binding calculation of the two-dimensional band structure.     

Impedance response of polycrystalline tungsten oxide

Polycrystalline tungsten oxide (WO₃) pellets were prepared by conventional ceramic processing technology. The ac small-signal electrical data acquired in the frequency (f) range 100 Hz≤f≤1 MHz at temperature (T) ranging the 31-100 °C revealed distinct semicircular relaxation in the impedance plane. This relaxation indicates device behavior originating from the grain boundaries. The lumped grain impedance associated with the device action remained too small to detect when the large resistance scale is realized. The semicircular relaxation is thermally activated indicating 0.58 eV as the activation energy for the relaxation time.     

Local ferromagnetic resonance imaging with magnetic resonance force microscopy

We report nanoscale scanned probe ferromagnetic resonance force microscopy (FMRFM) imaging of individual ferromagnetic microstructures. This reveals the mechanism for high spatial resolution in FMRFM imaging: the strongly inhomogeneous local magnetic field of the cantilever mounted micromagnetic probe magnet used in FMRFM enables selective, local excitation of ferromagnetic resonance (FMR). This approach, demonstrated here in individual permalloy disks, is straightforwardly extended to excitation of localized FMR modes, and hence imaging in extended films.     

Analytical solution of the contact problem of a rigid indenter and an anisotropic linear elastic layer

We use the Stroh formalism to study analytically generalized plane strain deformations of a linear elastic anisotropic layer bonded to a rigid substrate, and indented by a rigid cylindrical indenter. The mixed boundary-value problem is challenging since the a priori unknown deformed indented surface of the layer contacting the rigid cylinder is to be determined as a part of the solution of the problem. For a rigid parabolic prismatic indenter contacting either an isotropic layer or an orthotropic layer and a flat rigid punch indenting a half space, the computed solutions are found to agree well with those available in the literature. Parametric studies have been conducted to delimit the length and the thickness of the layer for which the derived relation between the axial load and the indentation depth caused by the rigid cylinder is valid. The indentation of a face centered cubic crystal with the plane of indentation oriented differently from the principal planes of symmetry has also been studied to illustrate the applicability of the technique to general layers made of anisotropic materials. Results presented herein can serve as benchmarks with which to compare solutions obtained by other methods.     

Self-chemical ionization of diethylzinc

The self-chemical ionization of diethylzinc is examined by Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry and semiempirical molecular orbital calculations. Electron impact of diethylzinc neutral produces the radical cation, C(4)H(15)Zn(+) (m/z x 122), which reacts further with the neutral (C(2)H(5))(2)Zn to give the following product ions: Zn(+) (m/z x 64), C(2)H(5)Zn(+) (m/z x 93), C(4)H(9)Zn(+) (m/z x 121), C(4)H(11)Zn(2)(+) (m/z x 187), and C(6)H(15)Zn(2)(+) (m/z x 215). To determine the structure and pathways for production of these ions, monoisotopic (12)C(4)H(15)(64)Zn(+), (64)Zn(+) and (12)C(2)H(5)(64)Zn(+) were individually isolated and reacted with the neutral background. We also performed semiempirical molecular orbital calculations (ZINDO/1). The molecular orbital calculations and experimental data are consistent in predicting that the ethyl group on the diethylzinc cation carries the positive charge. Copyright 1999 John Wiley & Sons, Ltd.