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941.
Huimin He Fengman Liu Haiyun Xue Haidong Wang Delong Qiu 《Fiber and Integrated Optics》2016,35(5-6):212-229
With the development of the multicore processor, the bandwidth and capacity of the memory, rather than the memory area, are the key factors in server performance. At present, however, the new architectures, such as fully buffered DIMM (FBDIMM), hybrid memory cube (HMC), and high bandwidth memory (HBM), cannot be commercially applied in the server. Therefore, a new architecture for the server is proposed. CPU and memory are separated onto different boards, and optical interconnection is used for the communication between them. Each optical module corresponds to each dual inline memory module (DIMM) with 64 channels. Compared to the previous technology, not only can the architecture realize high-capacity and wide-bandwidth memory, it also can reduce power consumption and cost, and be compatible with the existing dynamic random access memory (DRAM). In this article, the proposed module with system-in-package (SiP) integration is demonstrated. In the optical module, the silicon photonic chip is included, which is a promising technology to be applied in the next-generation data exchanging centers. And due to the bandwidth–distance performance of the optical interconnection, SerDes chips are introduced to convert the 64-bit data at 800 Mbps from/to 4-channel data at 12.8 Gbps after/before they are transmitted though optical fiber. All the devices are packaged on cheap organic substrates. To ensure the performance of the whole system, several optimization efforts have been performed on the two modules. High-speed interconnection traces have been designed and simulated with electromagnetic simulation software. Steady-state thermal characteristics of the transceiver module have been evaluated by ANSYS APLD based on finite-element methodology (FEM). Heat sinks are placed at the hotspot area to ensure the reliability of all working chips. Finally, this transceiver system based on silicon photonics is measured, and the eye diagrams of data and clock signals are verified. 相似文献
942.
Chemical‐Bonding‐Directed Hierarchical Assembly of Nanoribbon‐Shaped Nanocomposites of Gold Nanorods and Poly(3‐hexylthiophene)
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Shuang Pan Luze He Prof. Juan Peng Prof. Feng Qiu Prof. Zhiqun Lin 《Angewandte Chemie (International ed. in English)》2016,55(30):8686-8690
Nanoribbon‐shaped nanocomposites composed of conjugated polymer poly(3‐hexylthiophene) (P3HT) nanoribbons and plasmonic gold nanorods (AuNRs) were crafted by a co‐assembly of thiol‐terminated P3HT (P3HT‐SH) nanofibers with dodecanethiol‐coated AuNRs (AuNRs‐DDT). First, P3HT‐SH nanofibers were formed due to interchain π–π stacking. Upon the addition of AuNRs‐DDT, P3HT‐SH nanofibers were transformed into nanoribbons decorated with the aligned AuNRs on the surface (i.e., nanoribbon‐like P3HT/AuNRs nanocomposites). Depending on the surface coverage of the P3HT nanoribbons by AuNRs, these hierarchically assembled nanocomposites exhibited broadened and red‐shifted absorption bands of AuNRs in nIR region due to the plasmon coupling of adjacent aligned AuNRs and displayed quenched photoluminescence of P3HT. Such conjugated polymer/plasmonic nanorod nanocomposites may find applications in fields, such as building blocks for complex superstructures, optical biosensors, and optoelectronic devices. 相似文献
943.
Synthesis,Crystal Structure,and Electrochemical Properties of a Simple Magnesium Electrolyte for Magnesium/Sulfur Batteries
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Dr. Wanfei Li Shuang Cheng Jian Wang Dr. Yongcai Qiu Zhaozhao Zheng Dr. Hongzhen Lin Sanjay Nanda Qian Ma Yan Xu Dr. Fangmin Ye Dr. Meinan Liu Lisha Zhou Prof. Yuegang Zhang 《Angewandte Chemie (International ed. in English)》2016,55(22):6406-6410
Most simple magnesium salts tend to passivate the Mg metal surface too quickly to function as electrolytes for Mg batteries. In the present work, an electroactive salt [Mg(THF)6][AlCl4]2 was synthesized and structurally characterized. The Mg electrolyte based on this simple mononuclear salt showed a high Mg cycling efficiency, good anodic stability (2.5 V vs. Mg), and high ionic conductivity (8.5 mS cm?1). Magnesium/sulfur cells employing the as‐prepared electrolyte exhibited good cycling performance over 20 cycles in the range of 0.3–2.6 V, thus indicating an electrochemically reversible conversion of S to MgS without severe passivation of the Mg metal electrode surface. 相似文献
944.
Speech intelligibility in classrooms affects the learning efficiency of students directly, especially for the students who are using a second language. The speech intelligibility value is determined by many factors such as speech level, signal to noise ratio, and reverberation time in the rooms. This paper investigates the contributions of these factors with subjective tests, especially speech level, which is required for designing the optimal gain for sound amplification systems in classrooms. The test material was generated by mixing the convolution output of the English Coordinate Response Measure corpus and the room impulse responses with the background noise. The subjects are all Chinese students who use English as a second language. It is found that the speech intelligibility increases first and then decreases with the increase of speech level, and the optimal English speech level is about 71 dBA in classrooms for Chinese listeners when the signal to noise ratio and the reverberation time keep constant. Finally, a regression equation is proposed to predict the speech intelligibility based on speech level, signal to noise ratio, and reverberation time. 相似文献
945.
从理论上研究了共轭高聚物链中在电场作用下极化子运动的热效应.基于SSH模型以及通过绝热动力学演化的方法,模拟了共轭高聚物链中极化子在电场作用下从链左端向右端运动的过程.晶格受到的热扰动作用假设为通过局域的晶格范围内原子位移的随机涨落来实现.结果发现,晶格中的局域热涨落对于运动中的极化子而言等效于一个势垒.势垒高度由高分子中受到热扰动的区域的范围大小以及该区域与其周围环境的温差来决定.当分子中存在热吸收不均匀的现象时,链内极化子迁移率在低电场范围内随电场的变化遵循对数曲线变化规律. 相似文献
946.
947.
Xiaogang Sun Jun Xing Jingping Qiu 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2016,90(6):1151-1156
A series of boron and sulfur co-doped titanium dioxide (TiO2) photocatalysts were prepared by a sol-gel method using boric acid, thiourea and tetrabutyl titanate [Ti(OC4H9)4] as precursors. The photoabsorbance of as-prepared photocatalysts was measured by UV–Vis diffuse reflectance spectroscopy (DRS), and its microstructure was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and N2 adsorption-desorption measurements. The prepared photocatalysts consisted of the anatase phase mainly in the form of spherical particles. The photocatalytic performance was studied by photodegradation of methyl blue (MB) in water under UV and visible light irradiation. The calcination temperature and the codoping content influenced the photoactivity. The synergistic effect of boron and sulfur co-doping played an important role in improving the photocatalytic activity. In addition, the possibility of cyclic usage of codoped TiO2 was also confirmed, the photocatalytic activity of TiO2 remained above 91% of that of the fresh sample after being used four times. It was shown that the co-doped TiO2 could be activated by visible light and could thus be potentially applied for the treatment of water contaminated by organic pollutants. 相似文献
948.
A Facile Synthesis of Novel Allenylphosphinates Containing Multi Potential Asymmetric Centers
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Lan Yao Si‐Yu Ji Zhong‐Yuan Xu Yong‐Ming Sun Chang‐Qiu Zhao 《Journal of heterocyclic chemistry》2016,53(4):1155-1158
The novel allenylphosphinates containing up to three axial and phosphorus asymmetric centers were prepared in excellent yields via the reactions of 6‐chloro‐6H‐dibenzo[c,e][1,2]oxaphosphinine to propargyl alcohols. During the process, the configuration of phosphorus determined the biphenyl axial chirality, stereospecifically forming (l)‐stereomers but did not influence the chirality of allenyl axis. 相似文献
949.
950.
A Copper‐Catalyzed Decarboxylative Amination/Hydroamination Sequence: Switchable Synthesis of Functionalized Indoles
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Tian‐Ren Li Bei‐Yi Cheng Ya‐Ni Wang Mao‐Mao Zhang Prof. Dr. Liang‐Qiu Lu Prof. Dr. Wen‐Jing Xiao 《Angewandte Chemie (International ed. in English)》2016,55(40):12422-12426
A copper‐catalyzed decarboxylative amination/hydroamination sequence of propargylic carbamates with various nucleophiles is described for the first time. It features an earth‐abundant metal catalyst, mild reaction conditions, and high efficiency. Further treatments of the resultant key intermediates using an acid or a base in one pot enable the controllable and divergent synthesis of two types of functionalized indoles. Moreover, experiments to demonstrate the synthetic potential of this methodology are performed. 相似文献