The Effect of OMMT on the Morphology and Mechanical Properties of PVC/ABS Blends

Poly(vinyl chloride) (PVC)/acrylonitrile-butadiene-styrene (ABS) blends containing organically modified montmorillonite (OMMT) were prepared using a twin-screw extruder followed by injection molding. The OMMT dispersion was evaluated by X-ray diffraction and transmission electron microscopy. The clay was preferentially situated in the PVC phase and across the interfaces of PVC/ABS. The effect of the addition of OMMT on the morphology and mechanical properties was also evaluated. Scanning electron microscopy revealed a large reduction in domain size when OMMT was used. The mechanical properties were studied through tensile and impact tests. The yield stress increased when an appropriate amount of OMMT was used without impairing the impact strength.     

Interaction Between Neuroglobin and Caffeine by Multispectroscopic Methods

The interaction between neuroglobin (Ngb) and caffeine was studied by spectroscopy. UV-Vis spectra revealed that caffeine did not influence the native hexa-coordinated heme structure of neuroglobin. Fluorescence spectra indicated that caffeine could quench the intrinsic fluorescence of neuroglobin through static quenching mechanisms. The calculated thermodynamic parameters showed that the electrostatic force was the main intermolecular force in the reaction. Results also indicated that the microenvironmental changes of tryptophan and tyrosine residues within neuroglobin are inapparent. Furthermore, the circular dichroism (CD) spectra implied that caffeine could induce the formation of α-helix structure of neuroglobin.     

Lipschitz局部严格伪压缩映象的迭代逼近

设Ｋ是一致光滑Ｂａｎａｃｈ空间Ｋ的非空子集，Ｔ：Ｋ→Ｘ是Ｌｉｐｓｃｈｉｔｚ局部严格伪压缩映象。本文给出一个迭代序列强收敛到Ｔ的唯一不动点，并给出一个涉及Ｌｉｐｓｃｈｉｔｚ局部强增殖映象Ｔ的非线性方程Ｔｘ＝ｆ的解的迭代逼近。     

基于流函数模型的矢量海流生成方法

提出了一种基于海洋流函数模型的双站高频地波雷达径向流生成矢量流算法.该算法避免了传统矢量合成法将径向流进行插值带来的误差,而且符合海洋动力学原理,生成的流场更接近实际分布.通过计算机仿真发现,流函数算法的容错、容差能力比矢量合成法更强.在径向流探测标准误差为10 cm.s-1时,新算法反演结果的均方根误差减小了约5 cm.s-1.应用到雷达实测数据中,与海流计实测结果比较表明,新算法比传统算法的平均误差减小了2 cm.s-1.     

Enhanced Terahertz Phonon Polariton in Lithium Niobate Chip

Terahertz (THz) phonon polaritons, fundamental quasi-particles that couple lattice vibrations with electromagnetic fields at THz frequencies, are found in a variety of materials that offer the potential for a wide range of THz optoelectronic devices and on-chip integrated systems. However, these compact devices and on-chip systems are hampered by the absence of on-chip powerful THz phonon polariton sources. In this study, the efficient generation and amplification of THz phonon polaritons are proposed and directly visualized on a lithium niobate (LN) chip via a tilted pulsefront phase matching technique. By combining lateral pumping and phase matching schemes, two orders of magnitude are successfully attained in the interaction distance between the pump light and the LN chip, accompanied by a substantial amplification of generated THz phonon polariton. The results of this study may lead to abundant potential applications in chip scale THz photonic devices and systems based on LN materials and its integrated heterostructures.     

用于SCA ASIC测试的数字读出模块设计

高速开关电容阵列(SCA)具有高速采样、低功耗的特点,基于SCA的高速波形数字化是目前高精度时间测量的一个重要研究方向。为此,我们开展SCA芯片的研究,目前已设计完成原型ASIC设计,并正在进行后续版本的改进设计。为便于未来多版本ASIC的测试和评估,需设计具有一定通用性的数字读出模块,本论文工作主要介绍此模块的设计工作以及相应的数据读出软件。数字读出模块基于FPGA实现对待测ASIC的控制、配置及数据读出,采用DDR3片外存储芯片,使用USB3.0等接口进行数据传输;上位机软件基于Python3.7设计,实现了数据采集与波形绘制等功能。目前已使用设计完成的数字读出模块对第2版SCA ASIC进行了初步的测试,测试结果表明,此读出模块工作正常,且SCA芯片输出结果符合预期。     

Fast Liquid Phase Epitaxial Growth for Perovskite Single Crystals

Semiconductors grown by the solution-processed method have shown low-cost,facile fabrication process and comparable performance.However,there are many reasons why it is difficult to achieve high quality films.For example,lattice constant mismatch is one of the problems when photovoltaic devices made of organ metallic perovskites.In this work,MAPbBr^{MA=CH3NH3^+}perovskites single crystals grown on the surface of MAPbBr2.5 CI0.5 perovskites single crystals via liquid epitaxial growth method is demonstrated.It is found that when the lattice constants of the two perovskite single crystals are matched,another crystal can be grown on the surface of one crystal by epitaxial growth.The whole epitaxy growth process does not require high heating temperature and long heating time.X-ray diffraction method is used to prove the lattice plane of the substrate and the epitaxial grown layer.A scanning electron microscope is used to measure the thickness of the epitaxial layer.Compared with perovskite-based photodetectors without epitaxial growth layer,perovskite-based photodetectors with epitaxial growth layer have lower dark current density and higher optical responsibility.     

石墨烯纳米网电导特性的能带机理：第一原理计算

通过第一原理电子结构计算来研究有序多孔纳米网的电导特性变化的能带机理.能带结构分析结果表明:石墨烯纳米网超晶格(3m,3n)(m和n为整数)的电子本征态在布里渊区中心点发生四重简并;碳空位孔洞规则排列形成的石墨烯纳米网具有由简并态分裂形成的宽度可调带隙,无论石墨烯的两个子晶格是否对等.在具有磁性网孔阵列的石墨烯纳米网中,反铁磁耦合使对称子晶格的反演对称性增加了一项量子限制条件,导致能带结构在K点的二重简并态分裂成带隙.通过控制网孔密度能够有效调节石墨烯纳米网的带隙宽度,为实现新一代石墨烯纳米电子器件提供了理论依据.     

NO分子宏观气体热力学性质的理论研究

采用量子统计系综理论,研究了基态NO分子宏观气体摩尔熵、摩尔内能、摩尔热容等热力学性质.首先应用课题组前期建立的变分代数法(variational algebraic method, VAM)计算获得了基态NO分子的完全振动能级,得到的VAM振动能级作为振动部分,结合欧拉-麦克劳林渐进展开公式的转动贡献,应用于经典的热力学与统计物理公式中,从而计算得到了1000-5000 K温度范围内NO宏观气体的摩尔内能、摩尔熵和摩尔热容.将不同方法计算得到的摩尔热容结果分别与实验值进行比较,结果表明基于VAM完全振动能级获得的结果优于其他方法获得的理论结果.振动部分采用谐振子模型对无限能级求和计算热力学性质的方法有一定的局限性,应当使用有限的完全振动能级进行统计求和.