变量有界半定最小二乘问题

<正>1引言设A_i∈S~n,i=1,…,m,定义线性算子A:S~n→R~m,AX=(A_1·X,…,A_m·X)~T,其相应的伴随算子为A~*:R~m→S~n,且A~*y=sum from i=1 to my_iA_i.X∈S~n,b∈R~m.Malick.J在[6]中讨论了如下标准半定最小二乘问题(SDLS):     

沉积物内多氯联苯测定中有机氯农药的排除及质量控制/质量保证研究

报道了沉积物样品中多氯联苯(PCBs)的分析方法及质量控制/质量保证(QA/QC)研究,结果表明多级复合硅胶柱对有机氯农药去除效果良好.采用25种PCBs同族体标样PCB25对分析方法进行了QA/QC研究,PCBs的平均回收率在97%～118%之间.用本方法测定25种多氯联苯同族体的检测限范围在0.5～1.4ng/g之间.     

聚吡咯/纳米SiO_2复合材料的制备及氧化性能

采用化学氧化法制备聚吡咯/纳米Si O2(PPy/n Si O2)复合材料,通过扫描电子显微镜和红外光谱对其进行表征,并将其应用到对苯二酚的氧化反应中.结果表明,PPy/n Si O2复合材料中,PPy较均匀地负载在纳米Si O2表面.在弱酸性介质中,PPy/n Si O2对对苯二酚具有很好的氧化性能.反应2 h内,对苯二酚的氧化过程符合表观一级反应动力学.结合紫外-可见光谱法分析表明,聚吡咯通过与对苯二酚之间的氢键相互作用形成聚吡咯活性中间体,将对苯二酚氧化为对苯醌,聚吡咯具有氧化剂和催化剂的双重功能.     

Simple Method in Diagnosing Cancer Cells by a Novel Fluorescence Probe BMVC

Different cellular accumulations with distinct fluorescence properties of BMVC in cancer cells from normal cells allow us to establish a simple and economic method for the diagnosis of cancer cells. With using a light emitting diode to excite the BMVC molecule, microarray fluorescence analysis of a cell‐based glass chip provides an easy method towards the detection of a limited number of cancer cells.     

Enhanced mechanical performance and biological evaluation of a PLGA coated β-TCP composite scaffold for load-bearing applications

Porous β-tricalcium phosphate (β-TCP) has been used for bone repair and replacement in clinics due to its excellent biocompatibility, osteoconductivity, and biodegradability. However, the application of β-TCP has been limited by its brittleness. Here, we demonstrated that an interconnected porous β-TCP scaffold infiltrated with a thin layer of poly(lactic-co-glycolic acid) (PLGA) polymer showed improved mechanical performance compared to an uncoated β-TCP scaffold while retaining its excellent interconnectivity and biocompatibility. The infiltration of PLGA significantly increased the compressive strength of β-TCP scaffolds from 2.90 to 4.19 MPa, bending strength from 1.46 to 2.41 MPa, and toughness from 0.17 to 1.44 MPa, while retaining an interconnected porous structure with a porosity of 80.65%. These remarkable improvements in the mechanical properties of PLGA-coated β-TCP scaffolds are due to the combination of the systematic coating of struts, interpenetrating structural characteristics, and crack bridging. The in vitro biological evaluation demonstrated that rat bone marrow stromal cells (rBMSCs) adhered well, proliferated, and expressed alkaline phosphatase (ALP) activity on both the PLGA-coated β-TCP and the β-TCP. These results suggest a new strategy for fabricating interconnected macroporous scaffolds with significantly enhanced mechanical strength for potential load-bearing bone tissue regeneration.     

调质42CrMo钢的棘轮-疲劳交互作用及其耦合损伤粘塑性本构模型

对调质42CrMo钢的棘轮-疲劳交互作用的实验结果进行了分析,揭示了材料在非对称应力循环下的全寿命棘轮变形特征和低周疲劳损伤演化特性.在统一粘塑性循环本构模型框架下,基于连续损伤力学理论,提出一个耦合损伤的牯塑性本构模型.该模型中将损伤分为宏观弹性损伤和塑性损伤两部分,并采用不同的损伤演化方程来描述这两类损伤.针对材料不同的失效模式,分别采用损伤变量门槛值和最大应变作为失效判据.将模型应用于调质42CrMo钢单轴应力循环下全寿命棘轮行为的描述和低周疲劳寿命预测中,模拟结果和实验结果吻合较好.     

液体石蜡体系中CdSeS三元量子点的制备及性能

采用液体石蜡为反应溶剂, 油酸为Cd源的溶剂和配体, 在无磷条件下通过用高温热解法合成了高质量的CdSeS三元合金量子点. 用透射电子显微镜(TEM), X射线粉末衍射仪(XRD)和能量色散X射线分析仪(EDX)等对产物的性能进行了表征. 结果表明, 反应温度、 反应时间和Se与S的比例等因素均对量子点的生长过程及光学性能产生影响. 采用该方法制得的CdSeS三元合金量子点均为立方闪锌矿结构, 且形成了一种内富S外富Se的成分梯度结构, 其最大发射波长可在370~595 nm(近紫外~橙红色)范围内连续可调, 量子效率最高可达65%. 该体系下制备的CdSeS三元量子点具有良好的热稳定性和光稳定性.     

Generalized Aifantis strain gradient plasticity model with internal length scale dependence on grain size,sample size and strain

Sediment-water interfaces are important interfaces for lakes, which are related to most environmental and ecological problems. Wind-induced waves cause secondary pollution via sediment resuspension. Since the coupling mechanism of water, resuspended sediments, and phosphorus affects the release of phosphorus (P) near the interface, a coupled model was explored for two sediment types with different adsorption-desorption capabilities to examine sediment resuspension and P release. The relationships among wind speed, wave characteristics, sediment distribution and P concentration were obtained. For different sediments, the unit sediment desorption release is negatively correlated with wind speed. When sediments are resuspended under low or moderate wind speed, the P concentration in the overlying water increases abruptly, hampering diffusion. P release exhibits the characteristics of concentrated release in a small region and changes the water environment rapidly.

     

大跨度斜拉桥非线性振动模型与理论研究进展

斜拉桥的非线性动力学问题一直都是力学、结构和桥梁领域的研究热点.随着新材料(如碳纤维增强聚合物索)和新施工工艺的发展,斜拉桥的跨越能力不断得到提高,从而在桥梁建设中更具有竞争力.然而,斜拉桥跨度的增大和新材料的应用使结构变得更轻和更柔,使结构的非线性振动问题比以往更为突出,可能危及桥梁安全.基于课题组近年来对斜拉桥非线性动力学的研究,围绕大跨度斜拉桥的非线性建模理论及动力学问题,较为详细地评述近十年来国内外的研究进展情况.主要从斜拉索非线性动力学模型、梁的非线性动力学模型、索-梁组合结构的非线性动力学模型、斜拉桥整体非线性动力学模型与理论、以及斜拉桥的非线性振动实验等几个方面对斜拉桥非线性建模方法、力学模型、数学模型、求解方法及相应研究成果进行评述和讨论.研究结果表明,斜拉桥由于多柔性索和大跨度梁的耦合问题,以及环境载荷的复杂性,导致其具有丰富的非线性动力学行为.同时由于高维非线性系统求解方法的欠缺,整体斜拉桥非线性动力学行为又相当复杂,深入研究面临很大困难.最后,基于未来斜拉桥的发展趋势和可能面临的突出问题,对斜拉桥非线性振动问题今后的发展方向进行了探讨和展望.