(1,2-μ2-L1)(1,2-μ2-L2)十羰基合三锇振动光谱的理论计算[L1, L2=H, Cl, Br, I]

用密度泛函理论和从头计算(abinitio)方法,在B3LYP CEP 4G ,B3LYP LanL2DZ和RHF CEP 4G ,RHF LanL2DZ水平上,全优化计算了(1,2 μ2 H) (1,2 μ2 L)Os3(CO) 1 0 (L :Cl,Br,I)的分子几何构型和电子结构;在RHF CEP 4G水平上,全优化计算了(1,2 μ2 L) 2 Os3(CO) 1 0 (L :H ,Cl,Br,I)的分子几何构型和电子结构。计算结果表明,在这些体系中,电子由Os(CO) 3向Os(CO) 4转移。用RHF CEP 4G对这七个簇合物进行了简正振动频率分析,在计算得到振动频率及吸收强度的基础上,模拟了稳定平衡结构的红外光谱图,并对计算结果进行了比较和讨论。     

细菌视紫红质激发态动力学过程的实验与数值分析

本文采用差异吸收光谱法对化学增强型细菌视紫红质的状态变化进行了实验研究.发现在585 nm处明显存在一个稳定的中间过程.从分子动力学和实验出发,提出了一个适用于差异吸收光谱研究方法的数学模型,对菌紫质受激以后的动力学过程进行了模拟与数值分析.     

Study of decay mechanisms in B--->Lambdac+ppi- decays and observation of low-mass structure in the Lambdac+p system

Using a sample of 152 x 10(6) BB pairs accumulated with the Belle detector at the KEKB e+e- collider, we study the decay mechanism of three-body charmed decay B- --> Lambdac+ ppi-. The intermediate two-body decay B--->Sigmac (2455)0 p is observed for the first time with a branching fraction of (3.7 +/- 0.7 +/- 0.4 +/- 1.0) x 10(-5) and a statistical significance of 8.4sigma. We also observe a low-mass enhancement in the (Lambdac+p) system, which can be parametrized as a Breit-Wigner function with a mass of (3.35(-0.02)(+0.01) +/-0.02) GeV/c2 and a width of (0.07(-0.03)(+0.04) +/-0.04) GeV/c2. We measure its branching fraction to be (3.9(-0.7)(+0.8) +/- 0.4 +/- 1.0) x 10(-5) with a statistical significance of 6.2sigma. The errors are statistical, systematic, and that of the Lambdac+-->pK- pi+ decay branching fraction.     

Improved constraints on D0-D0 mixing in D0 --> K+ pi- decays from the Belle detector

We report the results of a search for D0-D0 mixing in D0 --> K+ pi- decays based on 400 fb(-1) of data accumulated by the Belle detector at KEKB. Both assuming CP conservation and allowing for CP violation, we fit the decay-time distribution for the mixing parameters x and y, as well as for the parameter R(D), the ratio of doubly Cabibbo-suppressed decays to Cabibbo-favored decays. The 95% confidence level region in the (x'2,y') plane is obtained using a frequentist method. Assuming CP conservation, we find x'2 < 0.72 x 10(-3) and -9.9 x 10(-3) < y' < 6.8 x 10(-3) at the 95% confidence level; these are the most stringent constraints on the mixing parameters to date. The no-mixing point (0,0) has a confidence level of 3.9%. Assuming no mixing, we measure R(D) = (0.377 +/- 0.008 +/- 0.005)%.     

The electron transport characters in a nanostructure with the periodic magnetic-electric barriers

This paper detailedly studies the transmission probability, the spin polarization and the conductance of the ballistic electron in a nanostructure with the periodic magnetic-electric barriers. These observable quantities are found to be strongly dependent not only on the magnetic configuration, the incident electron energy and the incident wave vector, but also on the number of the periodic magnetic-electric barriers. The transmission coefficient and the spin polarization show a periodic pattern with the increase of the separation between two adjacent magnetic fields, and the resonance splitting increases as the number of periods increases. Surprisingly, it is found that a polarization can be achieved by spin-dependent resonant tunnelling in this structure, although the average magnetic field of the structure is zero.     

Restoration of solar and star images with phase diversity-based blind deconvolution

The images recorded by a ground-based telescope are often degraded by atmospheric turbulence and the aberration of the optical system. Phase diversity-based blind deconvolution is an effective post-processing method that can be used to overcome the turbulence-induced degradation. The method uses an ensemble of short-exposure images obtained imultaneously from multiple cameras to jointly estimate the object and the wavefront distribution on pupil. Based on signal estimation theory and optimization theory, we derive the cost function and solve the large-scale optimization problem using a limited memory Broyden-Fletcher-Goldfarb-Shanno (L-BFGS) method. We apply the method to the urbulence degraded images generated with computer, the solar images acquired with the swedish vacuum solar telescope (SVST, 0.475m) in La Paima and the star images collected with 1.2-m telescope in Yunnan Observatory. In order to avoid edge effect in the restoration of the solar images, a modified Hanning apodized window is adopted.The star image till can be estored when the defocus distance is measured inaccurately. The restored results demonstrate that the method is efficient for removing the effect of turbulence and reconstructing the point-like or extended objects.     

基于微光机电系统的微光学自适应微镜的研究

提出了一种利用热应力改变镜面曲率的可调焦微光学自适应微镜。与传统自适应微镜相比,采用该原理制作的微镜具有驱动电压低和驱动力较大的优点,而且制作简单。以硅为基底进行了表面热氧化、光刻显影、HF酸刻蚀、KOH湿法刻蚀,溅射铝膜等微加工工艺的研究,获得硅铝双金属可调焦微反射镜4×4阵列,单元尺寸3 mm×3 mm,单晶硅基底厚60μm,硅表面溅射的铝膜厚150 nm。该微镜的镜面填充率为100%,可变形镜面占总镜面面积的79%。利用激光波面干涉仪对可调焦微反射镜的动态性能进行了测试。实验表明,该微镜可产生单向连续变形,最大变形量15.8μm,非线性滞后27%,工作电压0~2.5V,可调焦范围∞~0.036 m。     

钢铁检测微型光谱仪的研制

针对国内光电直读型钢铁检测微型光谱仪研究的不足,提出基于Czerny-Turner结构的系统设计方法,讨论了优化方法及验证方法,并加工出了光谱仪。光谱仪采用三次多项式拟合标定波长,实测分辨率在436 nm~608 nm全谱段达0.225 nm、中心谱段达0.135 nm,基本满足钢铁检测要求。提出一种基于多帧判断的定性分析方法,7种待测元素检出限优于1.5%,通过建立拟合光谱数据库实现半定量分析,25种样品检测精度达2%,为钢铁牌号识别提供重要参考。     

中和颗粒可压缩性颗粒层模型

本文针对可压缩颗粒层建立了二维数值模型.首先利用颗粒层中颗粒间的相互位置关系,建立了每一个颗粒的力平衡方程,获得了每一个颗粒的受力大小,然后提出了颗粒层坍塌判据,在此基础上,建立了描述颗粒层的沉积-压缩-沉积的动态过程的可压缩颗粒层模型,模型计算结果表明,颗粒层压缩现象主要发生在下部区域,过滤速度越高、范德华力越小,颗粒层越易坍塌,并且颗粒层的压降出现了脉动,模型结果符合已知的实验结果.