耐高温含氟磺化聚苯并咪唑的合成及表征

采用5-磺酸钠间苯二甲酸、双(苯甲酸)六氟丙烷与3,3',4,4'-四氨基联苯在多聚磷酸中通过共缩聚反应, 合成了一系列磺化度(定义为100个重复单元中所含的磺酸基个数, SD)可控的含氟磺化聚苯并咪唑(sPBI), 并利用红外光谱、核磁共振、凝胶色谱和热失重分析等手段对其结构、分子量与热稳定性进行了表征, 还考察了其溶解性和成膜性. 结果表明, sPBI的数均分子量(M_n)为61300～86000, 多分散指数介于1.96～2.34之间, 并且sPBI具有良好的成膜性和优异的热稳定性能, 其5%和10%热失重对应温度均随着SD的增加而有所提高, 在SD为70%时分别为549和576 ℃. 此类聚合物在质子交换膜材料方面具有一定的应用前景.     

Modified H-R mixed variational principle for magnetoelectroelastic bodies and state-vector equation

Based upon the Hellinger-Reissner (H-R) mixed variational principle for three-dimensional elastic bodies, the modified H-R mixed variational theorem for magnetoelectroelastic bodies was established. The state-vector equation of magnetoelectroelastic plates was derived from the proposed theorem by performing the variational operations. To lay a theoretical basis of the semi-analytical solution applied with the magnetoelectroelastic plates, the state-vector equation for the discrete element in plane was proposed through the use of the proposed principle. Finally, it is pointed out that the modified H-R mixed variational principle for pure elastic, single piezoelectric or single piezomagnetic bodies are the special cases of the present variational theorem.     

考虑耗散效应的金属杆受扰动后的非线性动力学现象分析

研究在周期外载荷作用及Neumann边界条件下,考虑Peierls-Nabarro效应的有限长一维金属杆的运动,以位移表达杆的控制方程,是受扰动的类sine-Gordon方程．利用空间四阶精度,时间二阶精度的有限差分格式模拟系统的动力响应．对于一定特征尺寸及物理性质的金属杆,研究了初始呼吸子及周期载荷幅值对杆动力行为的影响,结果显示了4种典型的动力行为:与空间位置无关的简谐运动、单波的简谐运动、单波的准周期运动和单空间模态的时间混沌运动．通过Poincaré截面和功率谱确定系统的运动特征．     

Preparation of 9,13-dicis double bonds locked retinoids

Synthesis of two retionids in which the 9, 13-dicis double bonds were locked in cycloalkene or thiophene was described. The key steps were the Wittig olefination of phosphonium salt 3 and 23 with aldehyde 14, followed by carbonylation of vinyl bromide 17 and 24 with carbon monoxide in the presence ofPd(PPh3)4.     

对氯苯酚提取-液相色谱法分析烟草中的磷酸腺苷

建立了新鲜烟叶中三磷酸腺苷(ATP)、二磷酸腺苷(ADP)和单磷酸腺苷(AMP)3种磷酸腺苷同时测定的方法。烟草样品经过对氯苯酚提取、纯化后,采用三乙胺缓冲液作为流动相洗脱,经C18色谱柱分离,在259 nm波长对样品进行检测。与高氯酸(PCA)法,以及DNA常用的苯酚提取法进行了比较,结果均表明:低温下以对氯苯酚提取的效果较佳,使用三乙胺缓冲液流动相具有分离效率高、检出灵敏的优点。在线性范围(5~200μg/mL)内,磷酸腺苷浓度与峰面积具有很好的相关系数(r>0.9999),检出限达到纳克级水平,氯苯酚法对ATP,ADP和AMP的平均回收率分别为96.8%,97.2%和93.3%,RSD均小于5%。     

Total-coloring of Sparse Graphs with Maximum Degree 6

Acta Mathematicae Applicatae Sinica, English Series - Given a graph G = (V, E) and a positive integer k, a k-total-coloring of G is a mapping φ: V?E → {1, 2, ?, k} such that...     

一种中低精度捷联惯测装置的不开箱标定方法研究

针对中低精度捷联惯测装置提出了一种实用的不开箱条件下的标定方法．该方法所需测试设备简单，用一套精度较高的惯测装置来标定低精度的惯测装置。文中给出了一套六位置测试方法，理论分析表明，该方法通过最小二乘法能有效的分离了陀螺和加速度计的各项误差。     

2<Emphasis Type="Italic">T</Emphasis>-periodic solution for<Emphasis Type="Italic">m</Emphasis> order neutral type differential equations with time delays

Periodic solution of m order linear neutral equations with constant coefficient and time delays was studied. Existence and uniqueness of 2 T-periodic solutions for the equation were discussed by using the method of Fourier series. Some new necessary and sufficient conditions of existence and uniqueness of 2T-periodic solutions for the equation are obtained. The main result is used widely. It contains results in some correlation paper for its special case, improves and extends the main results in them. Existence of periodic solution for the equation in larger number of particular case can be checked by using the result, but cannot be checked in another paper. In other words, the main result in this paper is most generalized for (1), the better result cannot be found by using the same method. Foundation item: the Natural Science Foundation of Yunnan Education Committee (990002) Biography: ZHANG Bao-sheng (1962-)     

非对称铺层复合材料层合板的双稳态特性半解析研究

非对称铺层的复合材料层合板在存在热残余应力的情况下，具有双稳态性质．层合板的两个稳态之间仅需要一个适当的激励就可以互相转化，因此该结构在变体飞机上应用广泛．基于经典层合板理论，本文引入几何大变形建立了具有双稳态性质的复合材料层合板的能量泛函，提出了一个高阶的位移场函数，用瑞利里兹法推导出一组关于位移场函数系数的非线性方程组．结合牛顿迭代法和消元法求解非线性方程组，得到了层合板面外位移场．同时利用有限元软件ABAQUS，对复合材料层合板双稳态机理进行了数值模拟．选取了几组具有代表性的铺层进行计算，以有限元结果为基准，比较了本文的位移场结果与前人的结果，验证了高阶位移场函数的准确性．     

一种新的激光雷达距离像噪声抑制方法

主要针对激光雷达距离像的距离反常噪声抑制问题,阐述了激光雷达距离像的噪声原理,分析了应用传统中值滤波方法抑制距离反常噪声的缺陷,提出了基于包围准则的自适应中值滤波算法。该方法首先根据包围准则检测噪声,对5×5滤波窗口内的像素值进行排序差分;然后选择低于门限长度最长的连续差分值对应的像素值作为距离正常值;最后运用中值滤波和加权均值滤波进行噪声抑制。实验结果表明,该方法有效抑制了距离反常噪声,且较好地保护了距离图像中目标的边缘细节,均方根误差分别比3×3和5×5窗口中值滤波法减少了27.1%和9.1%。