Synthesis and Structural Characterization of a Polyphosphazeneas Photoconductive Material

The synthesis of a novel polyorganophosphazene that contains charge-transporting agent as side chains for photoconductive application is reported. Structural characterization for the high polymer was presented by 1H-NMR, infrared spectrosocopy, gel permeation chromatography ( GPC ).     

Hydrothermal Synthesis, Crystal Structure and Luminescence Properties of a New 2D Cadmium Complex Based on the 4,4'-Bis(benzimidazol-1-ylmethy1)biphenyl and Glutaric Acid Ligands

A new polymeric complex {Cd2(bbmb)2(gt)2·(H2O)2}n (bbmb = 4,4'-bis(benzimidazol-1-ylmethy1)biphenyl, H2gt = glutaric acid) has been obtained by hydrothermal method and structurally characterized by elemental analysis, IR, XRD, TGA and single-crystal X-ray diffraction. The complex belongs to the triclinic system, space group P1 with a = 10.2417(15), b = 13.752(2), c = 22.201(3), α = 73.899(2), β = 88.416(2), γ = 78.305(2)°, V = 2940.4(7)3 , Z = 2, C66H56Cd2N8O8 , Mr = 1313.99, Dc = 1.484 g/cm3 , F(000) = 1336 and μ= 0.787 mm-1 , and features a 2D network. In the solid state at room temperature, the cadmium(Ⅱ) complex exhibits strong fluorescence absorption at 435 nm (λmax).     

超支化聚芴的合成与性能研究

采用2,7-二(4-羟基苯基)-9,9-二烷基芴(A2)与四对甲基苯磺酸季戊四醇酯(B4)通过A2+B4型缩聚反应合成了一系列共轭型超支化聚合物.利用紫外和荧光谱对聚合物予以表征,结果表明,此类聚合物均可发出稳定、纯正的蓝光.DSC和TGA显示,4种聚合物在150℃以下没有明显的相态变化,300℃以内无明显的热分解现象,这表明此类聚合物具有良好的热稳定性,有利于材料的发光效率及发光稳定性.     

Statistical Analysis of the Random Convective Dispersion Models

The convective dispersion models are derived by the material balance method in an infinitesimal volume. In comparison with the derivation process by the Markov method, they indicate statistical foundation of random particle movement. By numerical method, the mass transport laws are analyzed comparatively for the models.     

合成盐酸芬戈莫德的工艺改进

以溴苯为原料,经Wurtz偶联反应、Friedel-Crafts反应、烷基化反应等合成了免疫抑制剂盐酸芬戈莫德,总收率23.6%,其结构经1H NMR,IR和ESI-MS确证。     

在大学物理教学中应加强科学素养的案例剖析——纪念黄祖洽先生

通过具体的案例分析,探讨了在大学物理课程中对学生科学素养的培养.在大学物理课堂教学中引入批判性思维能力训练,激发学生发现科学问题,利用科学方法论解决问题.阐述了怎样更有效地在大学物理课堂教学中培育学生求真、求实、创新的科学精神.     

时间测度链上一类具阻尼项的二阶非线性中立型动力方程的振荡准则（英文）

利用广义的Riccati变换及不等式分析技巧,获得时间测度链T上的一类具有阻尼项的二阶非线性变时滞泛函动力方程[A(t)Ф(yΔ(t))]Δ+b(t)Ф(yΔ(t))+P(t)F(Ф(x(δ(t))))=0振荡性的一些充分条件,这里y(t)=x(t)+B(t)g(x(τ(t)))且Ф(u)=u|u|λ-1(λ0).这些结果推广并改进了一些已知的结论,并通过例子来说明这些结果的重要性.     

Joint empirical likelihood confidence regions for a finite number of quantiles under strong mixing samples

In this paper, we obtain the joint empirical likelihood confidence regions for a finite number of quantiles under strong mixing samples. As an application of this result, the empirical likelihood confidence intervals for the difference of any two quantiles are also obtained.     

两类新的最优变重量光正交码

变重量光正交码用于光码分多址通信系统以满足不同服务质量用户需求.给出当u≥5为素数时,最优(16u,{3,5},1,{2/3,1/3))交重量光正交码的具体构造.同时证明了当u≥5为素数时,存在一个最优(25u,{3,4,5},1,{1/4,2/4,1/4})变重量光正交码.这将改进变重量光正交码的存在性结果.     

突发事件下多因素同时扰动的闭环供应链协调策略

针对突发事件下销售价格敏感系数、回收价格敏感系数、制造成本和再制造成本同时扰动,研究了闭环供应链系统的生产(回收)策略、销售价格(回收价格)策略与协调机制,给出了不同扰动条件下生产(回收)调整策略与销售价格(回收价格)调整策略,并设计了新的回馈与惩罚契约,使得闭环供应链能够在突发事件前后都能够实现协调应对,最后通过数值实例验证了结论的正确性.研究表明:闭环供应链受突发事件的影响很大,但通过对回馈与惩罚契约的调整及其相对应的制造(回收)策略与销售价格(回收价格)策略的调整,可有效减少突发事件对闭环供应链利润的损失.