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A method of analysis of dynamic NMR spectra for A3B2 ? C3D2 spin systems is proposed. This method is based upon the assumption that the shape of the A–C part of the spectrum is the same as for the AB2 ? CD2 spin system and the shape of the B–D part is the same as for the A3B ? C3D system. By means of this simplification the iterative total line shape analysis of dynamic NMR spectra by the use of the least-squares method becomes feasible. The method proposed is applied to the determination of the thermodynamic parameters of activation for internal rotation in N,N-diethylbenzamide in CD3CN (ΔG = 62.6 kJ mol?1 ΔH≠ = 62 kJ mol?1, ΔS≠ = ?1 J/mol?1 K?1). The determination of natural line widths is discussed in detail and a method of estimation of the effect of systematic errors on the results is proposed. 相似文献
65.
M. Wiśniewski M. B. Bogacki J. Szymanowski 《Journal of Radioanalytical and Nuclear Chemistry》1996,208(1):195-206
The extraction of sulphuric acid from solutions containing hydroxylamine sulphate and ammonium sulphate with Cyanex 923 and the acid stripping from loaded Cyanex 923 are studied at 20 and 50°C. The effect of the numbers of extraction and stripping stages and the volume phase ratios in extraction and stripping upon sulphuric acid recovery is discussed. The process can be design to obtain a high or low recovery of sulphuric acid but with its low or high concentration, respectively. 相似文献
66.
Grzyska PK Czyryca PG Golightly J Small K Larsen P Hoff RH Hengge AC 《The Journal of organic chemistry》2002,67(4):1214-1220
Previous work by Kirby and co-workers revealed a significant acceleration of the rate of hydrolysis of p-nitrophenyl phosphate by added dipolar solvents such as DMSO. Activation parameters and kinetic isotope effects have been measured to ascertain the origin of this effect. The generality of this phenomenon was examined with a series of esters with more basic leaving groups. Computational analyses of the effects of desolvation of dianionic phosphate monoesters were carried out, and the possible effect of the transfer from water to the active site of alkaline phosphatase was modeled. The results are consistent with a desolvation-induced weakening of the P-O ester bond in the ground state. Other aryl phosphate esters show similar rate accelerations at high fractions of DMSO, but phenyl and methyl phosphates do not, and their hydrolysis reactions are actually slowed by these conditions. 相似文献
67.
M.B. Bogacki A. Jakubiak K. Prochaska J. Szymanowski 《Colloids and surfaces. A, Physicochemical and engineering aspects》1996,110(3):263-272
The interfacial tension of individual methyl 8-pyridyloctanoates containing the hydrophobic group at different positions of the pyridine ring was measured at the tolune/water interface. The extraction of copper(II) fom chloride solutions with these reagents was studied. Considering solvent extraction, methyl 8-(2-pyridyl)octanoate had a worse orientation at the interface than methyl 8-(3-pyridyl)octanoate and methyl 8-(4-pyridyl)octanoate. PM3 semiempirical quantum chemical computing indicates that the oxygen of the carbonyl group forms hydrogen bonds with water molecules more easily than the second oxygen atom and the nitrogen in the pyridine ring. However, at the adsorption layer, this hydration is possible only for methyl 8-(2-pyridyl)octanoate. Methyl 8-(3-pyridyl)octanoate and methyl 8-(4-pyridyl)octanoate are strong copper extractants from chloride solutions, while extraction is not observed for methyl 8-(2-pyridyl)octanoate. 相似文献
68.
van Wijngaarden J Shnitko I Batalov A Kolek P Fulara J Maier JP 《The journal of physical chemistry. A》2005,109(25):5553-5559
Electronic absorption spectra of C3Cl, C3Cl+, C3Cl-, C4Cl, and C4Cl+ have been recorded in 6 K neon matrices following mass selection. Ab initio calculations were performed (CCSD(T) and CASSCF) to identify the ground and accessible excited states of each molecule. The estimated excitation energies and transition moments aid the assignment. The absorptions observed for C3Cl are the 5(2)A' <-- X(2)A' and 3(2)A' <-- X(2)A' transitions of the bent isomer and the (2)A1 <-- X(2)B2 transition of the cyclic form in the UV (336.1 nm), visible (428.7 nm), and near-IR (1047 nm) regions, respectively. The band systems for bent C3Cl- (435.2 nm) and linear C3Cl+ (413.2 nm) are both in the visible region and correspond to 2(1)A' <-- X(1)A' and (1)pi <-- X(1)sigma+ type transitions. The C4Cl and C4Cl+ chains are linear, and the band origins of the 2(2)pi <-- X(2)pi and 2(3)pi <-- X(3)pi electronic transitions are at 427.0 and 405.7 nm. The spectral assignments are supported by analysis of the vibrational structure associated with each electronic transition. 相似文献
69.
Dr. Przemyslaw Dopieralski Dr. Jordi Ribas‐Arino Dr. Padmesh Anjukandi Dr. Martin Krupicka Prof. Dr. Dominik Marx 《Angewandte Chemie (International ed. in English)》2016,55(4):1304-1308
Understanding the impact of tensile forces on disulfide bond cleavage is not only crucial to the breaking of cross‐linkers in vulcanized materials such as strained rubber, but also to the regulation of protein activity by disulfide switches. By using ab initio simulations in the condensed phase, we investigated the response of disulfide cleavage by β‐elimination to mechanical stress. We reveal that the rate‐determining first step of the thermal reaction, which is the abstraction of the β‐proton, is insensitive to external forces. However, forces larger than about 1 nN were found to reshape the free‐energy landscape of the reaction so dramatically that a second channel is created, where the order of the reaction steps is reversed, turning β‐deprotonation into a barrier‐free follow‐up process to C?S cleavage. This transforms a slow and force‐independent process with second‐order kinetics into a unimolecular reaction that is greatly accelerated by mechanical forces. 相似文献
70.
Przemyslaw Mielczarek Piotr Suder Igor Kotsan Anna Bodzon-Kulakowska 《Journal of mass spectrometry : JMS》2023,58(4):e4916
Imaging mass spectrometry is a powerful technique for the molecular analysis of tissue sections. As in many analytical methods, sample preparation is one of the main and most important steps to obtain results of good quality. Usually, the matrix concentration and solvent composition in different studies are taken for granted without any further consideration. In our studies, we aimed to find how matrix concentration and a type of solvent influence the signal. Moreover, we also aimed to find the relationship between these parameters, how they influence the spectra, and how they influence obtained ion maps. In our experiments, we used SunCollect®, which is a commercially available wet-interface system for matrix deposition. We decided to choose two matrix concentrations (2,5-dihydroxybenzoic acid [DHB]: 15 and 25 mg/mL; 9-aminoacridine [9AA]: 7 and 5 mg/mL) and two different water solutions of solvents in two different percentages for the matrices (DHB: 50% and 70% of methanol [MeOH] and acetonitrile [ACN]; 9AA 70% and 50% of ethanol [EtOH] and MeOH). In the end, the influence of these parameters on obtained spectra and ion maps was assessed. 相似文献