Dielectric Loss of Thin-Film SiO2 Samples on Al in THz–IR Range

Physics of the Solid State - The development of new dielectric materials for insulating layer of interconnects with low loss on high frequencies (low-k) is one of main directions of modern...     

Absorption and generation of electromagnetic waves by structural inhomogeneities of solid

The integrability conditions of the electromagnetic field equations in a continuum with defects and their wave solutions are found. The following dislocation effects on the electromagnetic wave propagation in a continuous medium are investigated: the change in the direction of the electromagnetic wave propagation in a continuous medium; the rotation of the polarization plane of electromagnetic field wave in a continuous medium; the excitation of longitudinal components of the electromagnetic wave in a continuous medium and the change in the electromagnetic wave intensity related to this phenomenon. The energy balance equation for the electromagnetic field in a continuum with a stationary distribution of dislocation is found and it is shown that an electromagnetic wave excites exciton modes localized at dislocations in the solid.     

Surface Morphology,Microstructure, and Piezoelectric Response of Perovskite Islands in Lead Zirconate Titanate Thin Films

Physics of the Solid State - Features of the microstructure and piezoelectric response of perovskite islands in a pyrochlore phase matrix in lead zirconate titanate thin films prepeared by the...     

Study of the photodegradation of brilliant green on mechanically activated powders of zinc oxide

A study of the photocatalytic activity of commercial and mechanically activated zinc oxide powders has been carried out based on the example of the decomposition of Brilliant Green. The goal of this work was to study the effect of the grinding time (0, 1, 3, 5, and 7 min) on the structure of zinc oxide and its photocatalytic activity under visible and ultraviolet (UV) radiation. It has been found that, when UV radiation is used, the constant of the dye oxidation rate for samples activated for 1 min increases compared with unactivated powders, whereas further mechanical activation leads to a decrease in the photocatalytic activity. When using visible radiation, samples activated for 1 min showed the minimum photocatalytic activity and further mechanical activation led to an increase in the efficiency of photocatalysis.     

Total External Reflection of X Rays from Polycrystal Solid Surface

Technical Physics - Total external reflection of X rays from surfaces of several polycrystalline metals is analyzed. The roentgenograms of total reflection and X-ray diffraction are comprehensively...     

Fluctuations and spectral relaxation in dispersion transfer over traps

Based on the self-consistent cluster approximation of an effective medium for random walk over a lattice with stochastically positioned traps in the dispersion regime, the kinetics of the spectral relaxation of the partial populations was analyzed and the self-averaging of the diffusion coefficient was studied. It was demonstrated that the relaxation of partial populations at long time occurs anomalously slow, according to a power law. It was shown that, in the one-dimensional case, no self-averaging of the diffusion coefficient occurs even at long time (its fluctuation amplitude remain comparable with its value) and that in the two- and three-dimensional cases, self-averaging proceeds very slowly, in accordance with a logarithmic and power dependence, respectively.     

Measurement of quasi-isentropic compressibility of helium and deuterium at pressures of 1500–2000 GPa

The quasi-isentropic compressibility of helium and deuterium plasmas at pressures of up to 1500?C2000 GPa has been measured using devices with spherical geometry and an X-ray diagnostic complex comprising three betatrons and a multichannel imaging system with electro-optic gamma detectors. A deuterium density of 4.5 g/cm³ and a helium density of 3.8 g/cm³ have been obtained at pressures of 2210 and 1580 GPa, respectively. The internal energy of a deuterium plasma at the indicated pressure is about 1 MJ/cm³, which is about 100 times greater than the specific energy of condensed chemical explosives. Analysis of the obtained data shows that the degree of helium ionization under the achieved plasma compression parameters is about 0.9.     

Cationic hexamethylbenzene-diene cobalt complexes

Cationic complexes [(diene)Co(??-C₆Me₆)]⁺ (diene is buta-1,3-diene (2a), 5-isopropyl-2-methylcyclohexa-1,3-diene (2b), cycloocta-1,3-diene (2c), and cyclohexa-1,5-diene (2d)) were synthesized by the reaction of [Co(??-C₆Me₆)₂]⁺ (1) with dienes in a CH₂Cl₂-Me₂CO mixture. In the absence of dienes, cation 1 undergoes hydrogenation to form [(1,2,3,4,5,6-HMCD-1,3)-Co(??-C₆Me₆)]⁺ (HMCD is hexamethylcyclohexadiene, 2e). Structures [2c?Ce]PF₆ were determined by X-ray diffraction analysis. According to the DFT calculations, the Co-C₆H₆ bond in the complexes with conjugated dienes is stronger than that in the complexes with nonconjugated dienes.     

Ion-beam modification of track membrane surface

An ion-beam method to modify the track membrane surface is suggested. An ion gun based on a magnetron sputterer is developed. This gun provides ion energies in the range of 5 eV–1 keV, ion current density up to 0.8 mA/cm², and an ion beam aperture of 90 mm. After the track membrane surface has been irradiated by argon ions with an energy of 50–100 eV, the angle of surface-water contact decreases from 65°–75° to 10°–25°. If the irradiating ion energy is 300–800 eV, the angle of contact increases from 65°–75° to 90°–100°.