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141.
V.P. Gupta P. Agarwal A. Gupta V.K. Srivastava 《Journal of Physics and Chemistry of Solids》1982,43(3):291-295
Using Phillips and Van Vechten's theory the homopolar gap (Eh), ionic gap (Ec) and Penn gap (Ep) have been derived for the layered compound semiconductors SnS2 and SnSe2. The values of Ep so derived have been found to be in agreement with the values obtained from the Grimes-Cowley modification of the Penn model, and also with the reflectance spectra of the respective materials. Using the above data the Phillips ionicity has been calculated and the octahedral coordination of SnS2 and SnSe2 has been discussed on the basis of the calculated value of ionicity. The bond electronic polarizability has been evaluated using Chemla's approach and the values so obtained have been found in agreement with the values obtained from the Clausius-Mossottirelation. The Varshni formula has been shown to explain fairly well the temperature dependence of energy gap and the constants involved have been derived. The calculated isobaric temperature gradient of Eg[(] has been found to be in accordance with the reported values, and the electron lattice interaction has been evaluated. 相似文献
142.
J. K. Srivastava G. Jéhanno K. Muraleedharan J. A. Kulkarni V. R. Marathe V. S. Darshane R. Vijayaraghavan 《Hyperfine Interactions》1986,28(1-4):519-523
Mössbauer measurements in mixed spinel ferrite Gax Fe1–x Ni Cr O4 (0x0.8), carried out between 4.2 and 298°K, show the presence of entropic spins in this system. Recent Monte Carlo calculations /4/ have predicted the presence of such spins in a frustrated spin glass lattice. 相似文献
143.
R. K. Nigam B. P. Hajela S. Sengupta B. C. Srivastava K. M. Gupta 《Hyperfine Interactions》1986,28(1-4):935-939
The effect of pigments on the development of corrosion products between the painting system and metal surface when exposed to marine environments has been discussed. The pigments studied were; Red Mud Zinc chromate, Zinc chromate, Red oxide Zinc Phosphate, Manganese Phosphate Barium chromate and Basic Lead Silico Chromate. Mossbauer Spectroscopy revealed that the upper rust layer in all the cases consisted of-Fe203,-FeOOH and-FeOOH. The lower rust layer immediately in contact with the metal surface consisted of an asymmetrical doublet due to -FeOOH. 相似文献
144.
Abramowicz H Belusevic R Blondel A Blümer H Böckmann P Brummel HD Buchholz P Burkhardt H Debu P Duda J Dydak F Falkenburg B Fiedler M Geiges R Geweniger C Grant AL Guyot C Hagelberg R Hepp V Hughes EW Kampschulte B Keilwerth H Kleinknecht K Knobloch J Krasny M Królikowski J Kurz N Lipniacka A Merlo J Müller E Para A Perez P Perrier F Pollman D Ranjard F Renk B Schuller J Taureg H Tittel K Turlay R Vallage B Wachsmuth H Wotschack J 《Physical review letters》1986,57(3):298-301
145.
Snow is a sound absorbing porous sintered material composed of solid matrix of ice skeleton with air (+water vapour) saturated pores. Investigation of snow acoustic properties is useful to understand the interaction between snow structure and sound waves, which can be further used to devise non-destructive way for exploring physical (non-acoustic) properties of snow. The present paper discusses the experimental measurements of various acoustical properties of snow such as acoustic absorption coefficient, surface impedance and transmission losses across different snow samples, followed by inverse characterization of different geometrical parameters of snow. The snow samples were extracted from a natural snowpack and transported to a nearby controlled environmental facility at Patsio, located in the Great Himalayan range of India. An impedance tube system (ITS), working in the frequency range 63–6300 Hz, was used for acoustic measurements of these snow samples. The acoustic behaviour of snow was observed strongly dependent upon the incident acoustic frequency; for frequencies smaller than 1 kHz, the average acoustic absorption coefficient was found below than 0.4, however, for the frequencies more than 1 kHz it was found to be 0.85. The average acoustic transmission loss was observed from 1.45 dB cm−1 to 3.77 dB cm−1 for the entire frequency range. The real and imaginary components of normalized surface impedance of snow samples varied from 0.02 to 7.77 and −6.05 to 5.69, respectively. Further, the measured acoustic properties of snow were used for inverse characterization of non-acoustic geometrical parameters such as porosity, flow resistivity, tortuosity, viscous and thermal characteristic lengths using the equivalent fluid model proposed by Johnson, Champoux and Allard (JCA). Acoustically derived porosity and flow resistivity were also compared with experimentally measured values and good agreement was observed between them. 相似文献
146.
147.
A. H.M. Zaheri S. Srivastava K. Tankeshwar 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,61(4):465-473
Expressions for zeroth, second and fourth sum rules of longitudinal and bulk
stress auto correlation functions have been derived for binary fluid mixtures.
Longitudinal and bulk viscosities of an Ar–Kr mixture have been calculated using
Mori's memory function formalism coupled with the sum rules of longitudinal and
bulk stress auto correlation functions.
The results obtained are compared with the molecular dynamics
simulation. Mass dependence of the longitudinal and bulk viscosities has
been studied for different compositions
of an isotopic mixture at different densities and temperatures. For very large mass ratio, the
longitudinal and bulk viscosities of the isotopic mixture are more dependent on mole fraction than on mass. 相似文献
148.
Animesh K. Ojha Sunil K. Srivastava B. P. Asthana Ranjan K. Singh 《Journal of Raman spectroscopy : JRS》2007,38(2):159-165
The isotropic and anisotropic parts of the Raman spectra of NH2 bending and ν(CO) stretching modes of HCONH2 in a hydrogen‐bonding solvent, methanol, at different concentrations have been analyzed carefully in order to study the noncoincidence effect (NCE). In neat HCONH2, the experimentally measured values of noncoincidence Δνnc are ∼11 and ∼18 cm−1 for the NH2 bending and ν(CO) stretching modes, which reduce to 0.45 and 1.14 cm−1, respectively at the concentration of HCONH2 in mole fraction, χm = 0.1. The experimental results have been explained on the basis of two models, namely, the microscopic prediction of Logan and the macroscopic model of Mirone and Fini. The relative success of the two models in explaining the experimental data for both the modes have been discussed. It has been observed that in case of the ν(CO) stretching vibrational mode the Logan model can reproduce the experimental data rather precisely, whereas in the case of the NH2 bending mode, Mirone and Fini model yields more accurate results. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
149.
The method of separation of variables is applied in order to investigate the analytical solutions of a certain two-dimensional
rectangular heat equation. In the analysis presented here, the partial differential equation is directly transformed into
ordinary differential equations. The closed-form transient temperature distributions and heat transfer rates are generalized
for a linear combination of the products of Fourier-Bessel series of the exponential type. Relevant connections with some
other closely-related recent works are also indicated. 相似文献
150.
Mukesh Kumar Alaria A. K. Sinha A. Bera V. Srivastava 《International Journal of Infrared and Millimeter Waves》2008,29(12):1083-1090
The main objective of the paper is to make an efficient design of the input and output coaxial coupler for a helix TWTs. An
approach has been developed for the efficient design and analysis of the coaxial couplers in the practical situation. Normally
multi-section impedance transformer approach is used for any wide band coupler. For a space helix TWT, coupler should be wide
bandwidth and small size. In this case coupler is matched with helix slow wave structure and the standard 50-ohm connectors.
The simulated return loss (dB) profile for different type of couplers is obtained by using Ansoft HFSS, CST microwave studio
and compares those with experimental results. The tip loss design at sever ends for the input and the output section has been
also optimized. 相似文献