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91.
Low-energy cluster beam deposition was used to deposit mass-selected Aun clusters (n = 4, 6, 13 and 20) on amorphous carbon (a-C) substrates. The resulting samples were stored at room temperature under ambient conditions for time periods up to 32 months to analyze the coarsening behaviour of the clusters. Cluster-size distributions were measured in regular time intervals by transmission electron microscopy (TEM). The TEM experiments show a significant increase of the average cluster size with time analogous to classical surface Ostwald ripening (OR). The coarsening of Au clusters can be well described by steady-state diffusion-limited kinetics. The derived surface mass-transport diffusion coefficients at room temperature range between 1.1 and 3.8·10−25 m2 s−1 for our samples. A detailed analysis of values suggests that, the rate of the surface OR for mass-selected Aun clusters increases with the cluster size in the sequence: Au4 ≈ Au6 < Au13 < Au20 for the investigated range of Au clusters. Given that the initial, on-surface cluster-size distributions are nominally monodisperse, classical OR with cluster coarsening based only on the Gibbs-Thomson effect cannot explain the observed coarsening. The activation of the coarsening process is rationalized by initial variations of the cluster sizes due to the deposition process itself and/or the interaction of the clusters with the substrate. Moreover, the presence of initial deposited Au clusters as different isomers with slightly different chemical potential on the substrate, may also initiate the coarsening by surface OR. Furthermore, we find that the coarsening is most pronounced for the paucidispersed sample with Aum (10 ? m ? 20) clusters. A possible explanation of this behaviour is the presence of an initial distribution of different cluster sizes directly after deposition. 相似文献
92.
Ionel Popescu Adriana Urda Tatiana Yuzhakova Ioan-Cezar Marcu Jozsef Kovacs Ioan Sandulescu 《Comptes Rendus Chimie》2009,12(9):1072-1078
Unsupported and γ-Al2O3-supported Ba and Pb titanate catalysts were prepared, characterized and studied in the combustion of methane, as a test reaction for VOCs’ catalytic combustion. They present good catalytic activities, and after dispersion (5%) on γ-Al2O3 the specific activity of the supported perovskite phase increased 25 and 30 times, respectively, compared with the unsupported samples. PbTiO3/γ-Al2O3 shows the best catalytic properties among the tested samples. 相似文献
93.
Gelu Popescu 《Advances in Mathematics》2009,220(3):831-3417
In this paper, we study free pluriharmonic functions on noncommutative balls γ[Bn(H)], γ>0, and their boundary behavior. These functions have the form
94.
Isabel Abnades Lzaro Neyvis Almora-Barrios Sergio Tatay Catalin Popescu Carlos Martí-Gastaldo 《Chemical science》2021,12(35):11839
Defect engineering is a valuable tool to tune the properties of metal–organic frameworks. However, defect chemistry remains still predominantly limited to UiO-type MOFs. We describe the preferential formation of missing cluster defects in heterometallic titanium–organic frameworks of the MUV-10 family when synthesised in sub-stoichiometric linker conditions. Our results show the value of integrating experimental work, computational modelling and thorough characterization in rationalizing the impact of defects over the porosity and structure of this family of materials. Correlation of experiment with computational models reveals the dominance of missing cluster vacancies in the pore size distribution of defective MUV-10. These same models were used to investigate the correlation of defects by synchrotron X-ray diffraction. The diffraction at low reflection angles is dominated by diffuse scattering that is indicative of short-range order and cannot be indexed to the defective structural models generated. In addition to the low atomic scattering factor of titanium, these results confirm the need for high-resolution electron microscopy methods for modelling nanoscale disorder in titanium MOFs.Synthesis of MUV-10 in sub-stoichiometric linker conditions favours the formation of missing cluster vacancies for direct impact in their porosity. 相似文献
95.
Irina Popescu Marcel Ionel Popa Gabrielle Charlotte Chitanu 《Macromolecular Symposia》2008,272(1):125-131
Summary: The formation of polyelectrolyte complexes by interaction between chitosan and maleic acid copolymers as strong/weak dibasic polyanions was investigated. The interaction between the sodium salt of maleic acid copolymers with styrene or vinyl acetate and the chitosan hydrochloride in aqueous solution was followed by potentiometric, conductometric and turbidimetric titration. The effect of the added low molecular salt on the complex formation was also investigated. The precipitated complexes were analyzed by FTIR spectroscopy and TG analysis. Preliminary layer-by-layer deposition experiments were performed to obtain thin films. 相似文献
96.
系统研究了霍尔赫鲁特铝电解池中SnO2基惰性阳极 (96%SnO2+2%Sb2O3+2%CuO)的电流效率,腐蚀性以及结构变化. 评价了各种操作参数(温度、电流密度、阴阳两级的距离、冰晶石量比、Al2O3 浓度和电解质组成)对电流效率和腐蚀性的影响. 相似文献
97.
Iterative methods to solve systems of linear equations Ax = b usually require preconditioners M to speed convergence. But the calculation of many preconditioners can be notoriously sequential. The sparse approximate inverse preconditioner (SPAI) has particular potential for high performance computing [1]. We have ported the SPAI algorithm to graphical processing units (GPUs) within NVIDIA's CUSP library [2] for sparse linear algebra. GPUs perform well on dense linear algebra problems where data resides for long periods on the device. Since the underlying minimization problems are independent, they are mapped to separate thread-blocks, and an optimized QR algorithm implemented using NVIDIA's CUBLAS library is employed on each. Traditionally the challenge has been to determine a sparsity pattern Sp( M ) of the preconditioner dynamically [3], which reduces the condition number of MA to a degree where a preconditioned iterative solver such as GMRES becomes computationally viable. Due to the extremely high performance of the GPU, it is possible to consider initial sparsity patterns much denser than have been previously considered. We therefore consider a fixed sparsity patterns to simplify the GPU implementation. We evaluate the performance of the resulting preconditioner on a standard set of sparse matrices, and compare SPAI to other preconditioners. (© 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
98.
A consistent quantum theory of self-action and cross-interaction of coherent light pulses in a cubically nonlinear medium is developed by using the momentum operator of the field, which takes into account the inertial nonlinearity. Specific features of generation of the quadrature-squeezed states of light pulses are considered. The spectrum of fluctuations of a quadrature below the shot-noise level is analyzed as a function of the relaxation time of nonlinearity and the magnitude of nonlinear phase additions, related to the self-action and cross-interaction. 相似文献
99.
Liviu Horia Popescu 《Journal of Differential Equations》2004,203(1):28-37
In the present work, we give necessary and sufficient conditions for linear differential non-autonomous equations on a Banach space, that satisfy exponential dichotomy, to be topologically equivalent. We shall also prove that such equations are structurally stable. 相似文献
100.
In this paper we continue to study the spectral norms and their completions ([4]) in the case of the algebraic closure $ \overline {\mathbb Q} $ of ? in ?. Let $ \widetilde{\overline{\mathbb{Q}}} $ be the completion of $ \overline {\mathbb Q} $ relative to the spectral norm. We prove that $ \widetilde{\overline{\mathbb{Q}}} $ can be identified with the R‐subalgebra of all symmetric functions of C(G), where C(G) denotes the ?‐Banach algebra of all continuous functions defined on the absolute Galois group G = Gal$ {\overline {\mathbb Q}} / {\mathbb Q} $. We prove that any compact, closed to conjugation subset of ? is the pseudo‐orbit of a suitable element of $ \widetilde{\overline{\mathbb{Q}}} $. We also prove that the topological closure of any algebraic number field in $ \widetilde{\overline{\mathbb{Q}}} $ is of the form $\widetilde{\mathbb{Q}[x]}$ with x in $ \widetilde{\overline{\mathbb{Q}}} $. 相似文献