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61.
Ponnusamy Shanmugam Vadivel Vaithiyanathan Kodirajan Selvakumar 《Tetrahedron letters》2008,49(13):2119-2123
A simple, mild and efficient CAN mediated oxidation of Morita-Baylis-Hillman adducts of 5-methyl-N-alkylisatins 1a-13a to 5-formyl-N-alkylisatins 1b-13b under ambient reaction conditions is reported. Simple and isomerized 5-methyl-N-alkylisatin derivatives 1-4 have also been tested and failed to provide the corresponding formylated products. A plausible reaction mechanism has been proposed. 相似文献
62.
M. Okada S. Ponnusamy A. Vasudevarao H. Yanagihara 《Mathematische Nachrichten》2016,289(8-9):1044-1051
We study the class of univalent analytic functions f in the unit disk of the form satisfying where Ω will be a proper subdomain of which is starlike with respect to . Let be the unique conformal mapping of onto Ω with and and . Let denote the arclength of the image of the circle , . The first result in this paper is an inequality for , which solves the general extremal problem , and contains many other well‐known results of the previous authors as special cases. Other results of this article cover another set of related problems about integral means in the general setting of the class . 相似文献
63.
Murugavel Saminathan Mohan Raj Jayakumar Ravikumar Chandrasekaran Ranganathan Raja Jaabil George Ponnuswamy Alagusundaram 《Journal of heterocyclic chemistry》2021,58(3):841-863
The N-phenylbenzo[g]indazole derivatives, 3-(4-chlorophenyl)-3,3a,4,5-tetrahydro-N-phenylbenzo[g]indazole-2-carbothioamide (4CLPBIC), 3-(4-bromophenyl)-3,3a,4,5-tetrahydro-N-phenylbenzo[g]indazole-2-carbothioamide (4BRPBIC), and 3-(3-bromophenyl)-3,3a,4,5-tetrahydro-N-phenylbenzo[g]indazole-2-carbothioamide (3BRPBIC), were synthesized by the one-pot green amalgamation of solvent-free granulating methodology procedure at room temperature. The synthesized crystals were characterized by single-crystal X-ray diffraction (SC-XRD), FT-IR, FT-Raman, NMR, and UV–Vis techniques. The molecular geometries from XRD experimental values of synthesized compounds 4CLPBIC, 4BRPBIC, and 3BRPBIC in the ground state are compared theoretically by applying the density functional theory (DFT), a method with the B3LYP/6-311G(d,p) basis set using Gaussian 09 software. The vibrational assignments of the synthesized compounds were studied based on potential energy distribution (PED) by the VEDA4 program. The scaled DFT/B3LYP/6-311G(d,p) results show the best agreement with the experimental values. Computational 1H and 13C NMR were acquired by utilizing gauge-independent atomic orbital (GIAO) procedure, and chemical shift results are in good agreement with the experimental values. A web-based theoretical investigation was performed to understand the drug-likeness and ADMET properties of the compounds. Molecular docking studies were carried out against bacterial cholesterol inhibitor block and inhibitor of lanosterol-14α-demethylase CYP51 used in the treatment of topical and systemic mycoses in fungal to understand the inhibitory activity of synthesized compounds. The synthesized molecules were also tested for antibacterial and antifungal activities. 相似文献
64.
A novel regioselective synthesis of a number of functionalized 3-spiropyrrolizidine and 3-spiropyrrolidine oxindoles from Baylis-Hillman adducts of isatin and heteroaldehydes via [3+2] cycloaddition of azomethine ylides in excellent yields has been reported. 相似文献
65.
Murugavel Saminathan Saranya Kanagarajan Ravikumar Chandrasekaran Archana Sivasubramaniyan Ranganathan Raja Ponnusamy Alagusundaram 《中国化学会会志》2020,67(6):1100-1112
Two novel compounds 1-(5-[4-fluorophenyl]-3-phenyl-4,5-dihydro-1H-pyrazol-1-yl)-2-thiocyanatoethanone (FSCN) and 1-(5-[4-chlorophenyl]-3-phenyl-4,5-dihydro-1H-pyrazol-1-yl)-2-thiocyanatoethanone (ClSCN) were synthesized and characterized by SC-XRD, 1H NMR, 13C NMR, FTIR, and UV methods. The X-ray diffraction studies were utilized to prove the 3D crystal structures of FSCN and ClSCN. In both the compounds, the packing is mostly driven by C H⋯N, C H⋯O, and C H⋯π (benzene ring as an acceptor) interactions. In ClSCN, additionally, the π⋯π interaction is observed between the pyrazole ring of one molecule and the benzene ring of the other molecule. The experimental values were compared with the results of DFT/B3LYP/6-311G++(d,p) theoretical computations. The pharmacological screening for FSCN and ClSCN was performed using molinspiration and PreADMET web server. To analyze antibacterial inhibition of the synthesized ligands and Ciprofloxacin (control drug) were interacted with antibacterial protein Thymidylate Kinase (TMK) (PDB ID: 4QGG) with the help of AutoDock Vina tool. The ADMET and docking results of FSCN and ClSCN pointed out the better drug likeness nature and good inhibition behavior with TMK protein. The antibacterial in vitro studies suggested that FSCN compound inhibited well with antibacterial strains than that of ClSCN. The current investigation suggests that with further improvements, our compounds could be preferred as substitute medicine for bacterial diseases. 相似文献
66.
We have fabricated electroactive multilayer thin films containing ferritin protein cages. The multilayer thin films were prepared on a solid substrate by the alternate electrostatic adsorption of (apo)ferritin and poly(N-isopropylacrylamide-co-2-carboxyisopropylacrylamide) (NIPAAm-co-CIPAAm) in pH 3.5 acetate buffer solution. The assembly process was monitored using a quartz crystal microbalance. The (apo)ferritin/poly(NIPAAm-co-CIPAAm) multilayer thin films were then cross-linked using a water-soluble carbodiimide, 1-[3-(dimethylamino)propyl]-3-ethylcarbodiimide. The cross-linked films were stable under a variety of conditions. The surface morphology and thickness of the multilayer thin films were characterized by atomic force microscopy, and the ferritin iron cores were observed by scanning electron microscopy to confirm the assembly mechanism. Cyclic voltammetry measurements showed different electrochemical properties for the cross-linked ferritin and apoferritin multilayer thin films, and the effect of stability of the multilayer film on its electrochemical properties was also examined. Our method for constructing multilayer films containing protein cages is expected to be useful in building more complex functional inorganic nanostructures. 相似文献
67.
WAVE PROPAGATION IN A TRANSVERSELY ISOTROPIC THERMOELASTIC SOLID CYLINDER OF ARBITRARY CROSS-SECTION
The wave propagation in an infinite, homogeneous, transversely isotropic solid cylinder of arbitrary cross-section is studied using Fourier expansion collocation method, within the frame work of linearized, three-dimensional theory of thermoelasticity. Three displacement potential functions are introduced, to uncouple the equations of motion and the heat conduction. The frequency equations are obtained for longitudinal and flexural (symmetric and antisymmetric) modes of vibration and are studied numerically for elliptic and parabolic cross-sectional zinc cylinders. The computed non-dimensional wave numbers are presented in the form of dispersion curves. 相似文献
68.
In this paper, our aim is to show some mean value inequalities for the modified Bessel functions of the first and second kind. Our proofs are based on some bounds for the logarithmic derivatives of these functions, which are in fact equivalent to the corresponding Turán-type inequalities for these functions. As an application of the results concerning the modified Bessel function of the second kind, we prove that the cumulative distribution function of the gamma–gamma distribution is log-concave. At the end of this paper, several open problems are posed, which may be of interest for further research. 相似文献
69.
Murugesan Vairalakshmi Veerian Raj Ponnusamy Sami Kasi Rajasekaran 《Transition Metal Chemistry》2011,36(8):875-882
The kinetics of oxidation of phenol and a few ring-substituted phenols by heteropoly 11-tungstophosphovanadate(V), [PVVW11O40]4− (HPA) have been studied spectrophotometrically in aqueous acidic medium containing perchloric acid and also in acetate buffers
of several pH values at 25 °C. EPR and optical studies show that HPA is reduced to the one-electron reduced heteropoly blue
(HPB) [PVIVW11O40]5−. In acetate buffers, the build up and decay of the intermediate biphenoquinone show the generation of phenoxyl radical (ArO·) in the rate-determining step. At constant pH, the reaction shows simple second-order kinetics with first-order dependence
of rate on both [ArOH] and [HPA]. At constant [ArOH], the rate of the reaction increases with increase in pH. The plot of
apparent second-order rate constant, k
2, versus 1/[H+] is linear with finite intercept. This shows that both the undissociated phenol (ArOH) and the phenoxide ion (ArO−) are the reactive species. The ArO−–HPA reaction is the dominant pathway in acetate buffer and it proceeds through the OH− ion triggered sequential proton transfer followed by electron transfer (PT-ET) mechanism. The rate constant for ArO−–HPA reaction, calculated using Marcus theory, agrees fairly well with the experimental value. The reactivity of substituted
phenoxide ions correlates with the Hammett σ+ constants, and ρ value was found to be −4.8. In acidic medium, ArOH is the reactive species. Retardation of rate for the
oxidation of C6H5OD in D2O indicates breaking of the O–H bond in the rate-limiting step. The results of kinetic studies show that the HPA-ArOH reaction
proceeds through a concerted proton-coupled electron transfer mechanism in which water acts as proton acceptor (separated-CPET). 相似文献
70.
Sarangapani Muniraj Cheing-Tong Yan Hou-Kung Shih Vinoth Kumar Ponnusamy Jen-Fon Jen 《Analytica chimica acta》2012
A new simultaneous derivatization and extraction method for the preconcentration of ammonia using new one-step headspace dynamic in-syringe liquid-phase microextraction with in situ derivatization was developed for the trace determination of ammonium in aqueous samples by liquid chromatography with fluorescence detection (LC–FLD). The acceptor phase (as derivatization reagent) containing o-phthaldehyde and sodium sulfite was held within a syringe barrel and immersed in the headspace of sample container. The gaseous ammonia from the alkalized aqueous sample formed a stable isoindole derivative with the acceptor phase inside the syringe barrel through the reciprocated movements of plunger. After derivatization-cum-extraction, the acceptor phase was directly injected into LC–FLD for analysis. Parameters affecting the ammonia evolution and the extraction/derivatization efficiency such as sample matrix, pH, temperature, sampling time, and the composition of derivatization reagent, reaction temperature, and frequency of reciprocated plunger, were studied thoroughly. Results indicated that the maximum extraction efficiency was obtained by using 100 μL derivatization reagent in a 1-mL gastight syringe under 8 reciprocated movements of plunger per min to extract ammonia evolved from a 20 mL alkalized aqueous solution at 70 °C (preheated 4 min) with 380 rpm stirring for 8 min. The detection was linear in the concentration range of 0.625–10 μM with the correlation coefficient of 0.9967 and detection limit of 0.33 μM (5.6 ng mL−1) based on S N−1 = 3. The method was applied successfully to determine ammonium in real water samples without any prior cleanup of the samples, and has been proved to be a simple, sensitive, efficient and cost-effective procedure for trace ammonium determination in aqueous samples. 相似文献