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71.
72.
P. Andriani F. Conti L. Fortuna M. Frasca G. Passiante A. Rizzo 《Nonlinear dynamics》2006,44(1-4):263-268
Cellular Neural Networks (CNNs) constitute a powerful paradigm for modeling complex systems. Innovation systems are complex
systems in which small and medium enterprises play the role of simple units interacting with each other. In this paper, innovation
systems based on CNN are investigated. It is shown how a model based on CNN can reproduce the main features of innovation
systems and how this model can be generalized to include different aspects of the actors of the financial market. 相似文献
73.
Carmine Coluccini Pierangelo Metrangolo Marco Parachini Dario Pasini Giuseppe Resnati Pierpaolo Righetti 《Journal of polymer science. Part A, Polymer chemistry》2008,46(15):5202-5213
Well‐defined macromolecules have been obtained through free‐radical cyclopolymerization and cyclocopolymerization of difunctional and acrylic‐like monomers, which contained “push‐pull” supramolecular chromophores, able to form 1:1 complexes with Eu3+ ions in solution. The monomeric molecular modules are built around bismalonate crown ethers in a convergent fashion, in which one of the malonate moiety is derivatized as the ylidene malonate push‐pull fragment, and the other malonate moiety is elaborated to introduce two polymerizable and acrylic‐like substituents. The free‐radical induced cyclopolymerization of these monomers, or their cyclocopolymerization with UV/Vis “silent” but structurally related monomers, afforded macromolecular architectures characterized by GPC, NMR and DSC techniques. UV/Vis titration studies, performed with Eu(OTf)3 as the supramolecular probe, revealed how adjacent chromophores within the polymeric backbone are virtually independent from each other, and how the binding ability towards the probe of these multivalent, highly packed cyclopolymeric architectures, although reduced, is still clearly detectable. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 5202–5213, 2008 相似文献
74.
Previous research has shown a strong correlation of protein folding rates to the native state geometry, yet a complete explanation for this dependence is still lacking. Here we study the rate-geometry relationship with a simple statistical physics model, and focus on two classes of model geometries, representing ideal parallel and antiparallel structures. We find that the logarithm of the rate shows an almost perfect linear correlation with the "absolute contact order", but the slope depends on the particular class considered. We discuss these findings in the light of experimental results. 相似文献
75.
For the abelian self‐dual Chern‐Simons‐Higgs model we address existence issues of periodic vortex configurations—the so‐called condensates—of nontopological type as k → 0, where k > 0 is the Chern‐Simons parameter. We provide a positive answer to the longstanding problem on the existence of nontopological condensates with magnetic field concentrated at some of the vortex points (as a sum of Dirac measures) as k → 0, a question that is of definite physical interest. © 2015 Wiley Periodicals, Inc. 相似文献
76.
Franco Obersnel Pierpaolo Omari 《Proceedings of the American Mathematical Society》2007,135(7):2055-2058
We extend a result of J. Andres and K. Pastor concerning scalar time-periodic first order ordinary differential equations without uniqueness, by proving that the existence of just one subharmonic implies the existence of large sets of subharmonics of all given orders. Since these periodic solutions must coexist with complicated dynamics, we might paraphrase T. Y. Li and J. A. Yorke by loosely saying that in this setting even period two implies chaos. Similar results are obtained for a class of differential inclusions.
77.
In this paper we first establish an asymmetric version of the Poincaré inequality in the space of bounded variation functions, and then, basically relying on this result, we discuss the existence, the non-existence and the multiplicity of bounded variation solutions of a class of capillarity problems with asymmetric perturbations. 相似文献
78.
Pierpaolo Ceci Dr. Emilia Chiancone Prof. Oksana Kasyutich Dr. Giuliano Bellapadrona Dr. Lisa Castelli Maria Fittipaldi Dr. Dante Gatteschi Prof. Claudia Innocenti Dr. Claudio Sangregorio Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(2):709-717
A comparative analysis of the magnetic properties of iron oxide nanoparticles grown in the cavity of the DNA‐binding protein from starved cells of the bacterium Listeria innocua, LiDps, and of its triple‐mutant lacking the catalytic ferroxidase centre, LiDps‐tm, is presented. TEM images and static and dynamic magnetic and electron magnetic resonance (EMR) measurements reveal that, under the applied preparation conditions, namely alkaline pH, high temperature (65 °C), exclusion of oxygen, and the presence of hydrogen peroxide, maghemite and/or magnetite nanoparticles with an average diameter of about 3 nm are mineralised inside the cavities of both LiDps and LiDps‐tm. The magnetic nanoparticles (MNPs) thus formed show similar magnetic properties, with superparamagnetic behaviour above 4.5 K and a large magnetic anisotropy. Interestingly, in the EMR spectra an absorption at half‐field is observed, which can be considered as a manifestation of the quantum behaviour of the MNPs. These results indicate that Dps proteins can be advantageously used for the production of nanomagnets at the interface between molecular clusters and traditional MNPs and that the presence of the ferroxidase centre, though increasing the efficiency of nanoparticle formation, does not affect the nature and fine structure of the MNPs. Importantly, the self‐organisation of MNP‐containing Dps on HRTEM grids suggests that Dps‐enclosed MNPs can be deposited on surfaces in an ordered fashion. 相似文献
79.
Highly selective vapochromic fluorescence of polycarbonate films Doped with an ICT‐Based solvatochromic probe
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Muzaffer Ahmad Irina Platonova Antonella Battisti Pierpaolo Minei Giuseppe Brancato Andrea Pucci 《Journal of Polymer Science.Polymer Physics》2017,55(15):1171-1180
The vapochromic properties of a fluorescent 3‐[2‐(4‐nitrophenyl) ethenyl]‐1‐(2‐ethylhexyl)‐2‐methylindole (NPEMI‐E) characterized by intramolecular charge transfer (ICT) character, dispersed in polycarbonate (PC) films is reported. NPEMI‐E solvatochromism is investigated by means of experimental and computational methods. Fluorescent PC films containing 0.1 wt % of NPEMI‐E are prepared and exposed to saturated atmospheres of different volatile organic compounds (VOCs). NPEMI‐E/PC films show remarkable and reversible vapochromism when exposed to VOCs with high polarity index and favorable interaction with PC matrix such as CHCl3. Only minor variations in the emission wavelength are actually recorded for all other classes of VOCs investigated. The hue parameter is also used for the effective extraction of spectral information from digital color images without the need for wavelength discriminators. Overall, the present results support the use of NPEMI‐E/PC films for the cost‐effective detection of CHCl3 vapors. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55, 1171–1180 相似文献
80.
Brulatti P Gildea RJ Howard JA Fattori V Cocchi M Williams JA 《Inorganic chemistry》2012,51(6):3813-3826
A family of complexes (1a-3a and 1b-3b) was prepared, having the structure Ir(N^C^N)(N^C)Cl. Here, N^C(∧)N represents a terdentate, cyclometallating ligand derived from 1,3-di(2-pyridyl)benzene incorporating CH(3) (1a,b), F (2a,b), or CF(3) (3a,b) substituents at the 4 and 6 positions of the benzene ring, and N^C is 2-phenylpyridine (series a) or 2-(2,4-difluorophenyl)pyridine (series b). The complexes are formed using a stepwise procedure that relies on the initial introduction of the terdentate ligand to form a dichloro-bridged iridium dimer, followed by cleavage with the N^C ligand. (1)H NMR spectroscopy reveals that the isomer that is exclusively formed in each case is that in which the pyridyl ring of the N^C ligand is trans to the cyclometallating aryl ring of the N^C^N ligand. This conclusion is unequivocally confirmed by X-ray diffraction analysis for two of the complexes (1b and 3a). All of the complexes are highly luminescent in degassed solution at room temperature, emitting in the green (1a,b), blue-green (2a,b), and orange-red (3a,b) regions. The bidentate ligand offers independent fine-tuning of the emission energy: for each pair, the "b" complex is blue-shifted relative to the analogous "a" complex. These trends in the excited-state energies are rationalized in terms of the relative magnitudes of the effects of the substituents on the highest occupied and lowest unoccupied orbitals, convincingly supported by time-dependent density functional theory (TD-DFT) calculations. Luminescence quantum yields are high, up to 0.7 in solution and close to unity in a PMMA matrix for the green-emitting complexes. Organic light emitting devices (OLEDs) employing this family of complexes as phosphorescent emitters have been prepared. They display high efficiencies, at least comparable, and in some cases superior, to similar devices using the well-known tris-bidentate complexes such as fac-Ir(ppy)(3). The combination of terdentate and bidentate ligands is seen to offer a versatile approach to tuning of the photophysical properties of iridium-based emitters for such applications. 相似文献