Asymptotics of heavy atoms in high magnetic fields: II. Semiclassical regions

The ground state energy of an atom of nuclear chargeZe in a magnetic fieldB is exactly evaluated to leading order asZ in the following three regions:BZ ^4/3,BZ ^4/3 andZ ^4/3BZ³. In each case this is accomplished by a modified Thomas-Fermi (TF) type theory. We also analyze these TF theories in detail, one of their consequences being the nonintuitive fact that atoms are spherical (to leading order) despite the leading order change in energy due to theB field. This paper complements and completes our earlier analysis [1], which was primarily devoted to the regionsBZ ³ andBZ³ in which a semiclassical TF analysis is numerically and conceptually wrong. There are two main mathematical results in this paper, needed for the proof of the exactitude of the TF theories. One is a generalization of the Lieb-Thirring inequality for sums of eigenvalues to include magnetic fields. The second is a semiclassical asymptotic formula for sums of eigenvalues that isuniform in the fieldB.Work partially supported by U.S. National Science Foundation grant PHY90-19433 A02Work partially supported by U.S. National Science Foundation grant DMS 92-03829Work partially supported by the Heraeus Stiftung and the Research Fund of the University of Iceland.     

Statevector reduction in discrete time: A random walk in Hilbert space

A simple model is presented in which the statevector evolves every seconds in one of two ways, according to a particular probability rule. It is shown that this random walk in Hilbert space results in reduction of the statevector. It is also shown how the continuous spontaneous localization (CSL) theory of statevector reduction is achieved as a limiting case of this model, exactly as Brownian motion is a limiting case of ordinary random walk. Finally, a slightly different but completely equivalent form of the CSL equations suggested by the simple model given here is discussed.     

Jupiter's Great Red Spot and zonal winds as a self-consistent,one-layer,quasigeostrophic flow

We present the point of view that both the vortices and the east-west zonal winds of Jupiter are confined to the planet's shallow weather layer and that their dynamics is completely described by the weakly dissipated, weakly forced quasigeostrophic (QG) equation. The weather layer is the region just below the tropopause and contains the visible clouds. The forcing mimics the overshoot of fluid from an underlying convection zone. The late-time solutions of the weakly forced and dissipated QG equations appear to be a small subset of the unforced and undissipated equations and are robust attractors. We illustrate QG vortex dynamics and attempt to explain the important features of Jupiter's Great Red Spot and other vortices: their shapes, locations with respect to the extrema of the east-west winds, stagnation points, numbers as a function of latitude, mergers, break-ups, cloud morphologies, internal distributions of vorticity, and signs of rotation with respect to both the planet's rotation and the shear of their surrounding east-west winds. Initial-value calculations in which the weather layer starts at rest produce oscillatory east-west winds. Like the Jovian winds, the winds are east-west asymmetric and have Karman vortex streets located only at the west-going jets. From numerical calculations we present an empirically derived energy criterion that determines whether QG vortices survive in oscillatory zonal flows with nonzero potential vorticity gradients. We show that a recent proof that claims that all QG vortices decay when embedded in oscillatory zonal flows is too restrictive in its assumptions. We show that the asymmetries in the cloud morphologies and numbers of cyclones and anticyclones can be accounted for by a QG model of the Jovian atmosphere, and we compare the QG model with competing models.     

Bengazoles C-G from the Sponge Jaspis sp. Synthesis of the Side Chain and Determination of Absolute Configuration

Five new antifungal bengazoles (C-G) were isolated and fully characterized from a marine sponge of the genus Jaspis sp. Bengazoles C-G, together with the known bengazoles A and B, comprise a homologous series of n, iso, and anteiso fatty acid esters (C(13)-C(16)) of the same heterocyclic bis(oxazolyl)methanol parent. The complete relative and absolute configurations of the bengazoles were determined by application of the modified Mosher method and interpretation of exciton coupling in the CD spectra of the tetra-p-bromobenzoate derivatives of bengazole A and that of a model tetrol synthesized in seven steps from L-fucose.     

Synthesis, NMR Characterization, and a Simple Application of Lithium Borotritide

LiBH(4) is a powerful and selective reagent for regiospecific reduction reactions. A simple synthesis of LiB(3)H(4) at near theoretical specific radioactivity is reported. We have treated Li(3)H synthesized from tritium gas ((3)H(2), approximately 98%) with BBr(3) to produce LiB(3)H(4) (specific activity = 4120 GBq/mmol = 110 Ci/mmol. The maximum theoretical specific activity of LiB(3)H(4) is 4252 GBq/mmol = 115.04 Ci/mmol; 1 matom of (3)H = 1063 GBq = 28.76 Ci.) The tritium labeling performance of the reagent was tested by an exemplary reduction of 2-naphthaldehyde to 2-naphthalenemethanol. LiB(3)H(4) and the reduction products were characterized by a combination of (1)H, (3)H, and (11)B NMR techniques, as appropriate.