Proximity effect in superconductor/ferromagnet layered system: Influence of superconductivity on magnetic properties of Nb/Fe epitaxial bilayers

Magnetic and superconducting properties of Fe/Nb epitaxial bilayers have been studied. Single crystal Fe/Nb (110) bilayers with a Nb thicknessd _Nb in the range from 250 to 650 Å and with a Fe thicknessd _Fe in the range from 7 to 27 Å were prepared using molecular beam epitaxy techniques. Magnetization measurements showed the existence of a magnetically “dead” Fe-interface layer with a thicknessd _NM varying strongly with minor modifications of the growth conditions. For bilayers with a small magnetic layer thicknessd _M and a smalld _NM the FMR measurements revealed an anomalous decrease of the effective magnetization 4πM _eff of the ferromagnetic Fe layer below the superconducting transition temperatureT _c. The absolute change of 4πM _eff belowT _c depends strongly on the actual values ofd _M andd _NM: upon decreasing bothd _M andd _NM the effect increases considerably. As a possible mechanism for the anomalous temperature dependence of 4πM _eff belowT _c we discuss a spatial modulation of ferromagnetic order due to a modification of the RKKY inter-action in the superconducting state.     

Spin wave spectrum and exchange interactions in the antiferromagnetic garnet Ca3Cr2Ge3O12 by inelastic neutron scattering

We have measured the spin wave spectrum for the garnet Ca₃Cr₂Ge₃O₁₂ by means of inelastic neutron scattering. The data can be well described in the framework of linear spin wave theory if we assume a Heisenberg model with two exchange parameters up to the next nearest neighbours (J ₁ andJ ₂) and a staggered anisotropy field (A). A least squares fit to the observed dispersion relations yield the following values for these parameters: J ₁=–0.582(8)K,J ₂=0.416(4)K,A=0.25(8)K. Although symmetry requires that two nearest neighbour exchange constantsJ ₁ andJ ₁ ^' must be distinguished, only the average J ₁=(J ₁+3J ₁ ^' )/4 and the condition –0.35 K <J ₁=J ₁-J ₁ ^' <0.50 K could be deduced from the experiment. The most striking result is the positive value ofJ ₂. We discuss the implications for an understanding of superexchange mediated by more than one oxygen atom. In an extension of the conventional analysis we have calculated the integrated intensities in order to check the eigenvectors directly. Good agreement between observed and calculated intensities was obtained.     

Forward-backward multiplicity correlations in σ+ p,K + p andpp collisions at 250 GeV/c

Forward-backward multiplicity correlations in σ⁺,K ⁺ p andpp collisions at 250 GeV/c ( \(\sqrt s \) =22 GeV) are given for all charges and for the different charge combinations. The correlations are found to be caused predominantly by centrally produced particles. It is demonstrated that this result is an agreement with observations at the ISR and the CERNp \(\bar p\) -Collider. The results are compared to expectations from LUND, DPM and FRITIOF Monte Carlo models and a geometrical picture relating correlations in hadron-hadron collisions toe ⁺ e ^? data in terms of impact parameters is tested.     

Spectroscopic investigation of the ionization kinetics in XeCl laser discharges by Xe* density measurements

Time and spatially resolved absorption measurements of Xe^* particle number densities performed at an X-ray preionized self-sustained XeCl^*-laser discharge were used to investigate the reaction kinetics of such discharges and to test the validity of the commonly-made assumption that they are fit well by spatially homogeneous numerical models. It turned out that the Xe^* density distribution over the discharge cross section remains homogeneous for less than 100 ns only. Comparing the experimental results of the homogeneous discharge phase with zero-dimensional model calculations, we conclude that induced emission modeled using two excited xenon levels must be taken into account for the quantitative interpretation of the absorption measurements. For the interpretation of the Xe 6s-6p absorption measurements even a multilevel model will be necessary. Further we conclude from the relative courses and the absolute values of the Xe^* particle number densities that realistic HCl kinetics should contain three vibrationally excited levels and stepwise excitation processes as proposed by Dem'yanov et al. [8].     

Tunable UV laser photolysis of organometallics with product detection by laser mass spectroscopy: Trimethylaluminum

We use tunable UV laser light in the region 200–320 nm, produced by frequency doubling the output of a dye laser, for the decomposition of organometallic compounds. This method has been applied to TMA, trimethylaluminum Al(CH₃)₃. Only the TMA monomer absorbs UV light for >220 nm. TMA decomposes by one-photon absorption mainly into two channels: aluminum atoms Al plus organic fragments, and aluminummonomethyl AlCH₃ molecules plus organic fragments. The ratio [Al]/[AlCH₃] is wavelength dependent. We present a mechanism to explain the photolysis of trimethyl compounds of group III elements (Al, Ga, In).     

Synthesen von Heterocyclen, 122. Mitt.: Über die Reaktion des Perimidons mit aktiven Malonestern

Zusammenfassung Perimidon (1) reagiert mit monosubstit. Malonsäure-trichlorphenylestern (2) bei 250° zu 9-Hydroxy-5,7-dioxo-4,5-dihydro-7H-pyrido[1,2,3-cd]perimidinen (3), die durch saure Hydrolyse zu 10-Amino-4-hydroxy-benzo[h]carbostyrilen (4) gespalten werden.

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Syntheses of heterocycles, CXXII: Reaction of perimidone with reactive malonates

Perimidone (1) reacts with monosubstituted 2.4.6-trichlorophenyl malonates at 250° to 9-hydroxy-5.7-dioxo-4.5-dihydro-7H-pyrido[1.2.3-cd]perimidines (3), which are cleaved by acid yielding 10-amino-4-hydroxy-benzo[h]quinolin-2-ones (4).

     

Positron annihilation studies in highT c superconductor YBa2Cu3Cd x O y (x=0, 0.05)

Positron lifetime and Doppler broadening of the annihilation line measurements were performed in highT _c superconducting samples YBa₂Cu₃Cd _x O _y ,x=0, 0.05 and 6.9<y<7, as a function of temperature in the region of 14–300 K. It was found that the positron lifetime and theS parameter values are lower in the Cd doped sample than those in the undoped one. It was also observed that the positron annihilation parameters show similar temperature dependence for the undoped and Cd doped samples. We conclude that the Cd doping in highT _c superconductor YBa₂Cu₃Cd _x O _y , 6.9<y<7 fills defects associated with oxygen vacancies probably in oxygen deficient regions which can trap positrons.     

A highly specific polyclonal antiserum to the environmental contaminant 1,1,1-trichloro-2,2-bis-(4-chlorophenyl)-ethane (p,p′-DDT)

A very selective polyclonal antiserum against 1,1,1-trichloro-2,2-bis-(4-chlorophenyl)-ethane (p,p′-DDT) was obtained by a careful choice of the haptenic structure (2,2-bis(4-chlorophenyl)-ethanol hemisuccinate). This hapten was conjugated to BSA to prepare the immunogen. The effects of different types of solid phases on the equilibrium reaction between the hapten on solid phase and the polyclonal antiserum were evaluated to obtain a fine tuning of the antiserum performances in terms of specificity for p,p′-DDT and sensitivity to low levels of this pesticide. The calibration curves obtained show that it is possible to set up a sensitive assay for p,p′-DDT, employing a p,p′-dichlorodiphenylacetic acid-based solid phase, with a detection limit of 0.12 ng/mL and a working range of about 0.21–40 ng/mL. Selectivity towards several p,p′-DDT-related substances was good (o,p-DDT 17%, p,p′-DDD 1.2% o,p-DDD 6.3%, p,p′-DDE 6.7%).