Modulational instability in a passive fiber cavity, revisited

Modulation instability in a passive fiber cavity is revisited. We address the problem in the statement with a continuous-time Ikeda map, rather than in the mean-field limit. It is found that plane wave solutions are unstable for both normal and anomalous dispersion regimes of an optical fiber. The origin of the instability in the continuous-time Ikeda map is in the mode mixing introduced by the beam splitter. The obtained conditions for the instability were compared with ones known for the discrete-time Ikeda map, showing appreciable difference, which, however reduces in the mean-field limit.     

FIXED POINT RESULTS ON METRIC-TYPE SPACES

In this paper we obtain fixed point and common fixed point theorems for self- mappings defined on a metric-type space, an ordered metric-type space or a normal cone metric space. Moreover, some examples and an application to integral equations are given to illustrate the usability of the obtained results.     

N-D-labeled ionic probes for mass spectrometry

An effective ¹⁵N- and deuterium (D)-labeled 2,6-bis(oxazolin-2-yl)pyridine (pybox)-La complex based probe ionization method that produces a distinct isotopic shift was developed. The distinct isotopic shift was detected by using the newly synthesized ¹⁵N-D-labeled pybox complexes. Moreover, O-[3-(tetramethylpybox)-propyl]-hydroxylamine (oxime-TMpybox) was prepared for attachment to the carbonyl group of the target molecule. Distinct isotopic shifts and multiple charged ions were detected for various compounds having amino, thiol, carboxyl, and carbonyl groups and fullerenes, using the TMpybox ionic probe series in cold-spray ionization mass spectrometry.     

Calix[4]arene-based crab-like molecular sensors for highly selective detection of mercury and copper ions

In this work, two novel chemosensors based on calix[4]arene bearing (thio)barbituric acid groups (BC1 and BC2) were synthesised, and their structures were characterised by HRMS, NMR and FTIR. Furthermore, their binding properties towards various biologically relevant metal ions were studied by fluorescence titrations, ¹H NMR spectroscopies and Job’s plot evaluations. The chemosensor BC1 displayed excellent binding affinity and selectivity towards Cu²⁺, which was characterised using fluorescence spectroscopy. On the other hand, BC2 exhibited a very remarkable fluorescence enhancement as well as visible colour change from pale green to sunset yellow, in presence of Hg²⁺ ions. Finally, Job’s plot method revealed 1:1 binding stoichiometry for both BC1:Cu²⁺ complex and BC2:Hg²⁺ complex.     

An efficient one-pot method for the synthesis of novel ferrocene-triamide conjugates via pseudo five-component reaction

A simple and efficient one-pot synthesis of novel ferrocene-triamide conjugates from the reaction of ferrocenecarboxaldehyde with Meldrum’s acid and isocyanides in the presence of NH-containing compounds is described. This transformation proceeds through the creation of two CC bonds, two CN bonds, and one CO bond, leading to three peptide bonds, and presumably occurs via a domino sequence involving Knoevenagel condensation, [1+4] cycloaddition, deacetonation, and aminolysis reactions.     

A Hexagonally Ordered Nanoporous Silica-Based Fiber Coating for SPME of Polycyclic Aromatic Hydrocarbons from Water Followed by GC–MS

A highly porous fiber coating material was prepared and functionalized with 3-amino propyl triethoxysilane (APTES) on hexagonally ordered nanoporous silica (SBA-15). Applicability of this coating was assessed employing a laboratory made solid-phase microextraction (SPME) device and gas chromatography–mass spectrometry for the simultaneous sampling and determination of trace polycyclic aromatic hydrocarbons (PAHs) from aqueous sample solutions. A one at the time optimization strategy was applied to investigate and optimize important extraction parameters such as extraction temperature, extraction time, ionic strength and sonication time. In the optimum conditions, the relative standard deviations for deionized water, spiked with selected PAHs were between 3.3 and 7.7% (n = 3), and detection limits for the studied compounds were 4.2 and 26.1 pg mL⁻¹. No significant change was observed in the extraction efficiency of the new SPME fiber, over 50 extractions. The proposed method was successfully applied to the extraction and determination of PAHs in the waste water samples.

     

An Efficient One‐Pot,Four‐Component Synthesis of {[(1H‐1,2,3‐Triazol‐4‐yl)methoxy]phenyl}‐1H‐pyrazolo[1,2‐b]phthalazine‐5,10‐dione Derivatives

The 1‐{[(1H‐1,2,3‐Triazol‐4‐yl)methoxy]phenyl}‐1H‐pyrazolo[1,2‐b]phthalazine‐5,10‐dione derivatives 5 were synthesized by a simple and efficient method, i.e., by the four‐component, one‐pot condensation reaction of phthalohydrazide 4 , a (propargyloxy)benzaldehyde 1 , an active methylene compound 3 (malononitrile or ethyl cyanoacetate), and an azide 2 in the presence of Cu(OAc)₂/sodium L ‐ascorbate as catalyst and 1‐methyl‐1H‐imidazolium trifluoroacetate ([Hmim](CF₃COO)) as an ionic‐liquid medium in good to excellent yields (Scheme 1).     

6.4 GHz ECR ion source at VECC

The 6.4 GHz ECR ion source that was indigenously developed a few years ago has been operating continuously for injecting oxygen and neon beams to the cyclotron since 1997. VEC-ECR is a single stage high magnetic field ion source provided with a negatively biased electron repeller placed on the axis, near the injection mirror point. The supply of cold electrons and use of low mass mixing gas improve the stability of ECR plasma. Very recently, the effect of aluminum oxide coating on the copper plasma chamber wall has been studied. The plasma chamber wall was coated with aluminum by vacuum evaporation method and then exposed to oxygen gas to form aluminum oxide. It was noticed that the process substantially shifts the charge state distribution to the higher charge state with an enhancement of ion current by an order of magnitude. With the aluminized plasma chamber, the VEC-ECR can now produce 12 μA of O⁷⁺, 6.5 μA of Ar¹²⁺, 1.5 μA of Kr²⁰⁺ and 1.0 μA of Xe³¹⁺.