全文获取类型
收费全文 | 200582篇 |
免费 | 3061篇 |
国内免费 | 1240篇 |
专业分类
化学 | 111620篇 |
晶体学 | 2582篇 |
力学 | 8387篇 |
综合类 | 28篇 |
数学 | 23336篇 |
物理学 | 58930篇 |
出版年
2021年 | 1353篇 |
2020年 | 1558篇 |
2019年 | 1502篇 |
2018年 | 1513篇 |
2017年 | 1541篇 |
2016年 | 3016篇 |
2015年 | 2614篇 |
2014年 | 3260篇 |
2013年 | 9216篇 |
2012年 | 7838篇 |
2011年 | 9727篇 |
2010年 | 5945篇 |
2009年 | 5967篇 |
2008年 | 8859篇 |
2007年 | 8773篇 |
2006年 | 8546篇 |
2005年 | 7932篇 |
2004年 | 7153篇 |
2003年 | 6154篇 |
2002年 | 5986篇 |
2001年 | 6530篇 |
2000年 | 5035篇 |
1999年 | 3906篇 |
1998年 | 3048篇 |
1997年 | 3062篇 |
1996年 | 3009篇 |
1995年 | 2657篇 |
1994年 | 2570篇 |
1993年 | 2399篇 |
1992年 | 2682篇 |
1991年 | 2637篇 |
1990年 | 2306篇 |
1989年 | 2298篇 |
1988年 | 2299篇 |
1987年 | 2177篇 |
1986年 | 2119篇 |
1985年 | 3121篇 |
1984年 | 3123篇 |
1983年 | 2512篇 |
1982年 | 2718篇 |
1981年 | 2576篇 |
1980年 | 2558篇 |
1979年 | 2429篇 |
1978年 | 2533篇 |
1977年 | 2464篇 |
1976年 | 2345篇 |
1975年 | 2307篇 |
1974年 | 2215篇 |
1973年 | 2268篇 |
1972年 | 1312篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
121.
Silver nitrate-acetonitrile and π iodine-benzene complexes in thermotropic liquid crystals have been studied by 1H, 2H, and 13C NMR spectroscopy and by optical microscopy. Evidence for at least two silver complexes in each liquid crystal is presented. 相似文献
122.
J.-M. Colmont B. Bakri G. Wlodarczak G. Cazzoli C. Puzzarini 《Journal of Molecular Spectroscopy》2005,231(2):171-187
For atmospheric purposes, the N2- and O2-, or Air-broadenings of selected transitions of ozone have been investigated in the 195-300 K temperature range. More precisely, the following 13 transitions in the 280-345 GHz frequency range have been studied: the 22,0 ← 21,1 (279.5 GHz), 242,22 ← 241,23 (286.2 GHz), 32,2 ← 31,3 (286.3 GHz), 52,4 ← 51,5 (293.2 GHz), 134,10 ← 143,11 (300.7 GHz), 140,14 ← 131,13 (301.8 GHz), 72,6 ← 71,7 (303.2 GHz), 262,24 ← 261,25 (315.9 GHz), 53,3 ← 62,4 (317.2 GHz), 201,19 ← 200,20 (320.0 GHz), 266,20 ← 275,23 (343.2 GHz), 262,24 ← 253,23 (343.2 GHz), and 43,1 ← 52,4 (343.5 GHz) lines. Systematic errors are known to be the principal error source and recent intercomparisons of line-broadening coefficients showed differences up to 20%, thus a large effort in minimizing systematic error sources has been taken and cross check measurements with different techniques have been carried out. The conclusion of the intercomparison performed indicates an excellent agreement of the results and that an uncertainty less than 3%, which also takes into account the systematic errors, can be claimed for the line-broadening parameters. 相似文献
123.
F. Rubio F. García H. D. Burrows A. A. C. C. Pais A. J. M. Valente M. J. Tapia J. M. García 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1788-1799
The interaction between trivalent lanthanide ions and poly(1,4,7,10,13‐pentaoxacyclopentadecan‐2‐yl‐methyl methacrylate), PCR5, in aqueous solution and in the solid state have been studied. In aqueous solution, evidence of a weak interaction between the lanthanides and PCR5 comes from the small red shift of the Ce(III) emission spectra and the slight broadening of the Gd(III) EPR spectra. From the Tb(III) lifetimes in the presence of H2O and D2O the loss of one or two water coordinated molecules is confirmed when Tb(III) is bound to PCR5. An association constant of the order of 200 M?1 was obtained for a 1:1 (lanthanide:15‐crown‐5) complex from the shift of the polymer NMR signals induced by Tb(III). A similar association constant is obtained from the differences of the molar conductivity of Ce(III) solution at various concentrations in presence and absence of PCR5. When Tb(III) is adsorbed on PCR5 membranes, lifetime experiments in H2O and D2O confirm the loss of 5 or 6 water coordinated molecules indicating that in solid state the lanthanide(III)‐PCR5 interaction is stronger than in solution. The adsorption of Ce(III) in PCR5 membranes shows a Langmuir type isotherm, from which an equilibrium constant of 39 M?1 has been calculated. SEM shows that the membrane morphology is not much affected by lanthanide adsorption. Support for lanthanide ion–crown interactions comes from ab initio calculations on 15‐crown‐5/La(III) complex. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1788–1799, 2007 相似文献
124.
C. P. Massarolo G. P. Menzala A. F. Pazoto 《Mathematical Methods in the Applied Sciences》2007,30(12):1419-1435
The aim of this work is to consider the Korteweg–de Vries equation in a finite interval with a very weak localized dissipation namely the H?1‐norm. Our main result says that the total energy decays locally uniform at an exponential rate. Our analysis improves earlier works on the subject (Q. Appl. Math. 2002; LX (1):111–129; ESAIM Control Optim. Calculus Variations 2005; 11 (3):473–486) and gives a satisfactory answer to a problem suggested in (Q. Appl. Math. 2002; LX (1):111–129). Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
125.
We introduce a random perturbed version of the classical fidelity and we show that it converges with the same rate of decay
of correlations, but not uniformly in the noise. This makes the classical fidelity unstable in the zero-noise limit. 相似文献
126.
The hyperfine constants for muonium in elemental and binary inorganic solids suggest formation of three different families
of defect centre, with distinct electronic structures. The overall range of values, spanning nearly five orders of magnitude,
and their correlation with host properties such as band gap and electron affinity, reveal a deep-to-shallow instability which
has profound implications for the electrical properties of hydrogen impurity in electronic materials, both semiconducting
and dielectric. 相似文献
127.
M. Tscherneck J. Kleinert C. Haimberger M. E. Holmes N. P. Bigelow 《Applied physics. B, Lasers and optics》2005,80(6):639-643
Ultracold molecules have been produced by photoassociation of Cs atoms trapped in a mirror magneto-optical trap. The molecules
were detected by resonantly enhanced multi-photon ionization followed by time-of-flight mass spectroscopy. The time-of-flight
ofatomic and molecular ions was investigated in the presence of a dc bias voltageapplied to the conducting mirror. This technique
provides a new tool for determining the distance between the cold molecules and the mirror surface.
This revised version was published online in August 2005 with a corrected cover date. 相似文献
128.
Kwang-Hua W. Chu 《International Journal of Theoretical Physics》2007,46(12):3230-3233
The modified Gross–Pitaevskii equation was derived and solved to obtain the 1D solution in the zero-energy limit. This stationary
solution could account for the dominated contributions due to the kinetic effect as well as the chemical potential in inhomogeneous
Bose gases. 相似文献
129.
A datalogger was developed to identify vocalizing dolphins within socially interacting captive groups. Every 50 ms the logger stores data on the level and frequency of detected sound. Dataloggers are temporarily attached to dolphins by suction cups for data collection sessions lasting up to 45 min. Later, computer analysis of data from the dataloggers reveals which dolphin produced each vocalization recorded during the session. Results from use of dataloggers with two captive bottlenose dolphins (Tursiops truncatus) at the New England Aquarium in Boston, MA are presented. The possible use of dataloggers with wild dolphins is discussed. 相似文献
130.
The classical (first integral) methods of studying restrictions on the possible motion of gravitationally interacting bodies are reviewed. The simple and flexible inequality method is extended to a similar approach to the relationship between possible forbidden motion and (asymptotic) symmetries in the relativistic few-body problem. This extended method is used to reproduce the standard results of bounded motion for a test particle in a Schwarzschild geometry. The existence of bounded motion is shown for the general relativistic few-body problem and the difficulties in determining such bounded motion is analysed. The use of this approach to obtaining a relativistic alternative to the classical Roche lobe analysis in contact binaries is discussed. 相似文献