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181.
Let be a triangle in and let be the set of its three medians. We construct interpolants to smooth functions using transfinite (or blending) interpolation on The interpolants are of type f(1)+g(2)+h(3), where (1,2,3) are the barycentric coordinates with respect to the vertices of . Based on an error representation formula, we prove that the interpolant is the unique best L1-approximant by functions of this type subject the function to be approximated is from a certain convexity cone in C3().Received: 17 December 2003  相似文献   
182.
Motivated by perturbation theory, we prove that the nonlinear part \({H^{*}}\) of the KdV Hamiltonian \({H^{kdv}}\), when expressed in action variables \({I = (I_{n})_{n \geqslant 1}}\), extends to a real analytic function on the positive quadrant \({\ell^{2}_{+}(\mathbb{N})}\) of \({\ell^{2}(\mathbb{N})}\) and is strictly concave near \({0}\). As a consequence, the differential of \({H^{*}}\) defines a local diffeomorphism near 0 of \({\ell_{\mathbb{C}}^{2}(\mathbb{N})}\). Furthermore, we prove that the Fourier-Lebesgue spaces \({\mathcal{F}\mathcal{L}^{s,p}}\) with \({-1/2 \leqslant s \leqslant 0}\) and \({2 \leqslant p < \infty}\), admit global KdV-Birkhoff coordinates. In particular, it means that \({\ell^{2}_+(\mathbb{N})}\) is the space of action variables of the underlying phase space \({\mathcal{F}\mathcal{L}^{-1/2,4}}\) and that the KdV equation is globally in time \({C^{0}}\)-well-posed on \({\mathcal{F}\mathcal{L}^{-1/2,4}}\).  相似文献   
183.
In this paper we make comparison between a well-known theoretical model of light propagation through racetrack resonator and experimentally obtained results. Observed differences are studied and some original modifications are made in the existing model so as to achieve better alignment with experiment. The influence of several geometric parameters on racetrack’s response is used for further adjustments to be performed. This procedure opens up the possibility to estimate the free spectral range and resonant wavelength for different geometric parameters and consequently to predict resonator functionality and working conditions, as well as functionality of complex photonic devices based on resonant structures.  相似文献   
184.
Multi-walled carbon nanotubes (MWCNTs) and graphene nanoplatelets (GNPs) have been functionalized by dielectric barrier discharge (DBD) in air. The extent of functionalization of MWCNTs and GNPs reaches a maximum at the delivered discharge energy of 720 and 240 J mg−1, respectively. Further exposure to plasma leads to reduction of functional groups from the surface of the treated nanomaterials. It has also been demonstrated that DBD plasma does not produce dramatic structural changes in MWCNTs, while flakes of the treated GNPs become thinner and smaller in the lateral size. Conductive thin films, obtained by drop casting a solution of the treated nanomaterials in N-methyl-1-pyrrolidone on poly(methyl methacrylate) substrate, show significantly lower sheet resistance.  相似文献   
185.
    
The world of dendrimers presently encompasses several thousands of publications, including scientific papers and patents, several hundreds of different compositions, but only a few commercially available families of products (i.e. polyamidoamines (PAMAMs), until recently polypropyleneimines, and phosphorus‐containing dendrimers) This is the story of PAMAMOS, which recently became the first commercially available silicon‐containing dendrimers, and how we journeyed from our initial idea to the point of their commercialization. It focuses on three unique features of these new dendrimers: their ability to form precisely defined nano‐structured, honeycomb‐like, 2D or 3D networks; the amazing usefulness of these networks for the preparation of a variety of nanocomplexes and nancomposites; and some of the new vistas that these materials open up for engineering nanotechnology applications. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2755–2773, 2006  相似文献   
186.
    
The synthesis of three novel dimethyl (2‐(4,4‐dimethyl‐2,5‐dioxoimidazolidin‐1‐ylamino)‐ 2‐oxoethylamino)methylphosphonate, dimethyl (1‐ (4,4‐dimethyl‐2,5‐dioxoimidazolidin‐1‐ylamino)‐4‐ methyl‐1‐oxopentan‐2‐ylamino)methylphosphonate, and dimethyl (1‐(4,4‐dimethyl‐2,5‐dioxoimidazolidin‐ 1‐ylamino)‐1‐oxo‐3‐phenylpropan‐2‐ylamino)methylphosphonate, respectively, is reported. The newly synthesized compounds were prepared via the Kabachnik–Fields reaction. Their structures have been characterized by elemental analysis, IR, and NMR (1H, 13C, and 31P) spectra. © 2011 Wiley Periodicals, Inc. Heteroatom Chem 22:669–672, 2011; View this article online at wileyonlinelibrary.com . DOI 10.1002/hc.20731  相似文献   
187.
    
A method based on the application of ultra-performance liquid chromatography (UPLC) coupled to hybrid quadrupole-time-of-flight mass spectrometry (QqTOF-MS) with an electrospray (ESI) interface has been developed for the screening and confirmation of several anionic and non-ionic surfactants: linear alkylbenzenesulfonates (LAS), alkylsulfate (AS), alkylethersulfate (AES), dihexyl sulfosuccinate (DHSS), alcohol ethoxylates (AEOs), coconut diethanolamide (CDEA), nonylphenol ethoxylates (NPEOs), and their degradation products (nonylphenol carboxylate (NPEC), octylphenol carboxylate (OPEC), 4-nonylphenol (NP), 4-octylphenol (OP) and NPEO sulfate (NPEO-SO4). The developed methodology permits reliable quantification combined with a high accuracy confirmation based on the accurate mass of the (de)protonated molecules in the TOFMS mode. For further confirmation of the identity of the detected compounds the QqTOF mode was used. Accurate masses of product ions obtained by performing collision-induced dissociation (CID) of the (de)protonated molecules of parent compounds were matched with the ions obtained for a standard solution. The method was applied for the quantitative analysis and high accuracy confirmation of surfactants in complex mixtures in effluents from the textile industry. Positive identification of the target compounds was based on accurate mass measurement of the base peak, at least one product ion and the LC retention time of the analyte compared with that of a standard. The most frequently surfactants found in these textile effluents were NPEO and NPEO-SO4 in concentrations ranging from 0.93 to 5.68 mg/L for NPEO and 0.06 to 4.30 mg/L for NPEO-SO4. AEOs were also identified.  相似文献   
188.
    
The preparation of antimicrobial silver‐loaded cotton/polyester fabrics has been carried out by DBD surface activation followed by silver sorption from aqueous silver nitrate solution. A series of DBD fabric treatments was performed in order to determine the most suitable experimental conditions for the fabric surface activation. The capillarity, silver ion uptake, and copper number were used to assess the surface changes on the fabrics. An effective process has been developed to obtain antimicrobial silver‐loaded Co/PES fabrics. The antimicrobial activity of the silver‐loaded fabrics against different pathogens was evaluated in vitro. The quantity of bonded silver ions is enough to develop desirable antimicrobial activity in the Co/PES fabrics.

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189.
    
Here we report on the synthesis and characterization of three new N-modified analogues of hemorphin-4 with rhodamine B. Modified with chloroacetyl, chloride cotton fabric has been dyed and color coordinates of the obtained textile materials were determined. Antiviral and virucidal activities of both the peptide-rhodamine B compounds and the dyed textile material were studied. Basic physicochemical properties (acid-base behavior, solvent influence, kinetics) related to the elucidation of structural activity of the new modified peptides based on their steric open/closed ring effect were studied. The obtained results lead to the conclusion that in protic solvent with change in pH of the environment, direct control over the dyeing of textiles can be achieved. Both the new hybrid peptide compounds and the modification of functionalized textile materials with these bioactive hemorphins showed virucidal activity against the human respiratory syncytial virus (HRSV-S2) and human adenovirus serotype 5 (HAdV-5) for different time intervals (30 and 60 min) and the most active compound was Rh-3.  相似文献   
190.
Cancer is one of the leading causes of death worldwide, affecting millions of people every year. Although chemotherapy remains one of the most common cancer treatments in the world, the severe side effects of chemotherapy drugs impose serious concerns to cancer patients. In many cases, the chemotherapy can be localized to maximize the drug effects; however, the drug systemic circulation induces undesirable side effects. Here, we have developed a highly efficient cellulose-based nanoadsorbent that can capture more than 6,000 milligrams of doxorubicin (DOX), one of the most widely used chemotherapy drugs, per gram of the adsorbent at physiological conditions. Such drug capture capacity is more than 3,200% higher than other nanoadsorbents, such as DNA-based platforms. We show how anionic hairy cellulose nanocrystals, also known as electrosterically stabilized nanocrystalline cellulose (ENCC), bind to positively charged drugs in human serum and capture DOX immediately without imposing any cytotoxicity and hemolytic effects. We elucidate how ENCC provides a remarkable platform for biodetoxification at varying pH, ionic strength, ion type, and protein concentration. The outcome of this research may pave the way for developing the next-generation in vitro and in vivo drug capture additives and devices.  相似文献   
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