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141.
The stationary workload W A+B φ of a queue with capacity φ loaded by two independent processes A and B is investigated. When the probability of load deviation in process A decays slower than both in B and $e^{ - \sqrt x } $ , we show that W A+B φ is asymptotically equal to the reduced load queue W A φ?b , where b is the mean rate of B. Given that this property does not hold when both processes have lighter than $e^{ - \sqrt x } $ deviation decay rates, our result establishes the criticality of $e^{ - \sqrt x } $ in the functional behavior of the workload distribution. Furthermore, using the same methodology, we show that under an equivalent set of conditions the results on sampling at subexponential times hold.  相似文献   
142.
The thermal stability and degradation behavior of a series of nine different exactly alternating silphenylene-siloxane polymers which contained methyl, vinyl, hydrido, 3,3,3-trifluoropropyl, and tridecafluoro-1,1,2,2-tetrahydrooctyl side groups, or their combinations, were investigated by dynamic and isothermal gravimetric analyses in air and in nitrogen. Two distinctly different mechanisms were observed in these atmospheres: a complex multi-step weight loss process in air and a single-step process in nitrogen. In nitrogen all polymers produced black, insoluble, highly stable degradation residues which were characterized by high carbon content. In contrast, in air the nonfluorine containing polymers degraded to pure silica, while the fluoroalkyl substituted polymers may have formed fluorosilicates of unspecified structures. There appears to be no significant molecular weight effect on the thermal stability of these polymers, at least not above an M w value of about 35,000. Isothermal investigations indicate that 300°C in air and 350°C in nitrogen may be possible upper use temperatures for the methylvinyl substituted, exactly alternating silphenylene–siloxane polymers for extended periods of time. A strong thermostabilizing effect by vinyl side groups on the degradation behavior of these polymers was established. The extent of stabilization depends on the content of vinyl units, but it can already be clearly seen at the 5 mol % vinyl level, and it increases exponentially with increasing vinyl concentration. In contrast to this behavior, by comparison with the parent all-methyl substituted, exactly alternating silphenylene–siloxane polymers, the hydrido and fluroalkyl side groups reduce overall polymer thermal stability in terms of the degradation onset temperature, the temperature for 50% weight loss, and the amount of degradation residue. The presence of these groups also extends the later stages of the degradation processes to higher temperatures. Based on these and previous results, an order of stability is proposed as a function of the type of the substituent side groups for the thermal degradation of these polymers.  相似文献   
143.
144.
Summary Some sharp inequalities involving n-monotone functions and their derivatives are obtained. In particular, the following generalization of the Favard-Berwald inequality is established here: \emph{If\/ is non-negative and -f is -monotone, then   相似文献   
145.
    
Recently, we reported that dimethylsilanolate‐initiated anionic ring opening polymerization of dimethylsiloxy‐ and diphenylsiloxy‐cyclic siloxanes results in polymer chain branching by dimethylsilanolate‐induced cleavage of only one Si‐CAr side bond in diphenylsiloxy repeat units, leading to formation of “Ph‐T‐branches”, and not extending to the cleavage of the second phenyl group. We attributed this behavior to electronic structures of the participating dimethylsiloxy‐, diphenylsiloxy and Ph‐T‐branch silicons and predicted that copolymers prepared by this synthetic route from dimethylsiloxy‐ and methylphenylsiloxy‐cyclics should not undergo branching at all but should have perfect linear chain configuration. Here, we describe results of a study of two such dimethylsilanolate‐initiated ring opening polymerizations of dimethylsiloxy‐ and methyphenylsiloxy‐cyclic tetramers and characterization of the resulting polymers by SEC‐MALS‐VIS, Mark‐Houwink‐Sakurada relationship and 29Si NMR. The results obtained clearly confirmed our prediction of expected linearity of these polymer chains and also indicated that the resulting polymers were completely amorphous even at as low methylphenylsiloxy‐content as 3.9 mol %. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 1122–1129  相似文献   
146.
    
For studying spectral properties of a nonnormal matrix A C n × n , information about its spectrum σ(A) alone is usually not enough. Effects of perturbations on σ(A) can be studied by computing ε‐pseudospectra, i.e. the level sets of the resolvent norm function g ( z ) = ( z I ? A ) ? 1 2 . The computation of ε‐pseudospectra requires determining the smallest singular values σ min ( z I ? A ) for all z on a portion of the complex plane. In this work, we propose a reduced basis approach to pseudospectra computation, which provides highly accurate estimates of pseudospectra in the region of interest, in particular, for pseudospectra estimates in isolated parts of the spectrum containing few eigenvalues of A. It incorporates the sampled singular vectors of zI ? A for different values of z, and implicitly exploits their smoothness properties. It provides rigorous upper and lower bounds for the pseudospectra in the region of interest. In addition, we propose a domain splitting technique for tackling numerically more challenging examples. We present a comparison of our algorithms to several existing approaches on a number of numerical examples, showing that our approach provides significant improvement in terms of computational time.  相似文献   
147.
    
Constructing plasmonic hotspots in metal nanostructures is essential for plasmon‐enhanced spectroscopies (PESs), but their application in quantitative analysis is a long‐standing challenge. Herein, highly uniform, reproducible, stable, and sensitive 3D hotspots platform substrates are assembled on hydrophobic silicon wafers using a drop of solution containing silica coated surface plasmon resonance (SPR) active nanoparticles (NPs). Plasmon‐enhanced second harmonic generation (PESHG) and surface‐enhanced Raman scattering (SERS) experimental signals increase sharply with the increase of droplet evaporation time, which is attributed to the rapid increase of 3D hotspots generated by gradual decrease of distance between adjacent NPs. Compared with 3D bare metal NP substrate, 3D metal shell‐isolated nanoparticles (SHINs) substrate demonstrates much more stable PESHG and SERS signals attributing to the protecting SiO2 shells. Besides that, uniform distribution of 3D “hotspots” on the hydrophobic substrate can facilitate the quantitative analysis of an analyte using SERS. Experimental and theoretical results demonstrate that the 3D hotspots platform has the potential to be developed as a plasmon‐enhanced substrate for linear and nonlinear spectroscopies with practical sensing applications.  相似文献   
148.
    
Some new N- and C-modified biomolecular peptide analogues of both VV-hemorphin-5 and VV-hemorphin-7 with varied amino acids (Cys, Glu, His), 1-adamantanecarboxylic acid, and niacin (nicotinic acid) were synthesized by solid-phase peptide synthesis—Fmoc (9-fluorenylmethoxy-carbonyl) chemistry and were characterized in water solutions with different pH using spectroscopic and electrochemical techniques. Basic physicochemical properties related to the elucidation of the peptide structure at physiological pH have been also studied. The results showed that the interaction of peptide compounds with light and electricity preserves the structural and conformational integrity of the compounds in the solutions. Moreover, textile cotton fibers were modified with the new compounds and the binding of the peptides to the surface of the material was proved by FTIR and SEM analysis. Washing the material with an alkaline soap solution did not show a violation of the modified structure of the cotton. Antiviral activity against the human respiratory syncytial virus (HRSV-S2) and human adenovirus serotype 5 (HAdV-5), the antimicrobial activity against B. cereus and P. aeruginosa used as model bacterial strains and cytotoxic effect of the peptide derivatives and modified cotton textile material has been evaluated. Antimicrobial tests showed promising activity of the newly synthesized compounds against the used Gram-positive and Gram-negative bacteria. The compounds C-V, H-V, AC-V, and AH-V were found slightly more active than NH7C and NCH7. The activity has been retained after the deposition of the compounds on cotton fibers.  相似文献   
149.
Two physiological tests for screening drought tolerance of barley (Hordeum vulgare, L.) plants are compared in this work. Water deficit is induced by treating the plants' roots with polyethylene glycol (PEG 8000). The relative water content (RWC) of the plants is used as a measure of the water status. Conductometrically determined electrolyte leakage from the leaf tissue demonstrates the membrane injury caused by dehydration. It is shown that the injury index increases with the decrease of the RWC of the leaves. The F(v)/F(m) ratio is employed to assess changes in the primary photochemical reactions of the photosynthetic apparatus after dehydration. The results suggest that PSII is weakly affected by the imposed osmotic stress. The fluorescence behaviour of the examined cultivars is related to their RWC.  相似文献   
150.
We report on the electrochemical preparation of porous GaAs substrates in fluoride-iodide aqueous electrolytes for the lattice mismatched epitaxial growth from the vapor phase. The aim is to gain control over the uniformity of the pore nucleation layer and pore branching below this layer to achieve structures with a high degree of porosity and periodicity while leaving minimum damage on the substrate surface. Layers of InxGa1-xAs with varying In content are grown on GaAs substrates with different pore geometries and depths. Substantial differences in the surface morphology and photoluminescence efficiency of the layers grown on porous and conventional substrates are observed.  相似文献   
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