CSNS-II超导椭球腔形变电场平坦度仿真分析

超导椭球腔是一种通过冲压零件和电子束焊接而成型的薄壁结构,在加工过程中存在不可避免的形变,如单元倾斜、偏轴,单元长度偏差,从而影响椭球腔的轴向电场平坦度,进而降低椭球腔的运行电场梯度。因此,在椭球腔加工成型后要进行预调谐处理。椭球腔预调谐是通过对椭球腔整形,包括倾斜和偏轴矫正,单元长度矫正,以达到提高轴向电场平坦度的目的。采用COMSOL多物理场耦合软件对CSNS-II（China Spallation Neutron Source Phase II）超导椭球腔可能存在的形变进行了仿真计算,研究了各单元形变量对电场平坦度的影响,分析了腔体调谐位移量对电场平坦度的影响,为椭球腔预调谐提供数据参考,也为预调谐机的设计研制提供指导。另外,确定了椭球腔机械形变的要求,确保椭球腔机械加工质量满足CSNS-II升级的实际工程需求。     

橡胶粒子和刚性纳米粒子对注塑级硬质聚氯乙烯复合材料断裂行为的影响

采用核壳型丙烯腈-苯乙烯-丁二烯共聚物(ABS)和纳米碳酸钙(CaCO3)协同改性聚氯乙烯(PVC),制备了注塑级硬质PVC纳米复合材料.通过透射电镜(TEM)、扫描电镜(SEM)、力学性能测试研究了其结构与性能,并采用有限元模拟方法研究了ABS与纳米CaCO3粒子对复合材料断裂行为的影响.当CaCO3含量低于12 phr时,ABS和纳米CaCO3粒子在PVC基体中分散均匀,可起协同增韧作用.在外力作用下,ABS粒子形变主要以内空化方式进行.CaCO3未发生团聚时,CaCO3与PVC基体界面在外力作用下形成微孔;CaCO3发生团聚时,CaCO3与PVC基体界面处形成较大的裂纹.有限元分析结果表明,未发生团聚时,CaCO3和ABS粒子均可提高PVC基体的局部内应力,促使材料发生局部塑性屈服,导致复合材料屈服强度降低、冲击强度提高.     

Dehydrogenative Heck coupling of biologically relevant N-heteroarenes with alkenes: discovery of fluorescent core frameworks

A Pd/Cu-catalyzed dehydrogenative Heck coupling is established that allows direct alkenylation of various biologically relevant N-heteroarenes with alkenes. The resulting π-extended alkenylated N-heteroarenes exhibit interesting fluorescent properties and have proven to be potentially useful fluorescent probes for bioimaging.     

The first slipped pseudo-quadruple-decker complex of phthalocyanines

The first slipped pseudo-quadruple-decker complex of phthalocyanines was formed unexpectedly upon treatment of the protonated double-decker SmIIIH(Pc)[Pc(alpha-OC4H9)8] with NaOH. The supramolecular structure contains two double-decker units linked by two sodium ions by an extremely rare coordination mode of phthalocyanines in which an aza nitrogen atom and two oxygen atoms from neighboring alkoxy substituents form a tridentate ligand.     

透明和吸收介质非线性参数n2,X^（3）及其时间响应特性研究

对透明和吸收介质的简并四波混频理论作了处理,实验上给出了掺半导体玻璃,无机和有机材料的三阶非线性极化率x~(3)和非线性折射率n_2的值,而且确定了非线性参数x~(3)的时间响应特性,实验装置的时间分辨率为5ps.     

Indirect biamperometric determination of o-phenylenediamine in lab-on-valve format using reversible indicating redox system

The miniaturized lab-on-valve (LOV) manifold well hyphenated with indirect biamperometry is presented for automated determination of trace level concentrations of organic environmental pollutants by programmable flow. The experimental procedure was carried out by means of taking o-phenylenediamine (OPDA) as a model analyte, relying on the Fe(iii)/Fe(ii) couple that served as an indicating redox system. The miniaturized electrochemical flow cell (EFC) designed and processed was integrated into the LOV module which is assembled with two identical polarized platinum electrodes between which a small potential difference (ΔE) was applied, to implement automated on-line analysis in a closed system. Factors affecting analytical performance are discussed, including indicating redox systems, concentration of indicating system, the acidity, the potential difference, and flow variables in the LOV. The calibration curve showed an excellent linearity in the concentration range of 5.0 × 10(-7) to 1.0 × 10(-4) mol L(-1) (R(2) = 0.9993). The limits of detection (LOD) and quantitation (LOQ) for OPDA were found to be 1.1 × 10(-7) and 3.7 × 10(-7) mol L(-1), respectively. A sampling frequency of 40 h(-1) was obtained along with an R.S.D. of 2.8% at 1.0 × 10(-6) mol L(-1) OPDA (n = 11). The proposed procedure was successfully applied to the assay of OPDA in industrial waste water.     

Image Denoising by a Local Clustering Framework

Images often contain noise due to imperfections in various image acquisition techniques. Noise should be removed from images so that the details of image objects (e.g., blood vessels, inner foldings, or tumors in the human brain) can be clearly seen, and the subsequent image analyses are reliable. With broad usage of images in many disciplines—for example, medical science—image denoising has become an important research area. In the literature, there are many different types of image denoising techniques, most of which aim to preserve image features, such as edges and edge structures, by estimating them explicitly or implicitly. Techniques based on explicit edge detection usually require certain assumptions on the smoothness of the image intensity surface and the edge curves which are often invalid especially when the image resolution is low. Methods that are based on implicit edge detection often use multiresolution smoothing, weighted local smoothing, and so forth. For such methods, the task of determining the correct image resolution or choosing a reasonable weight function is challenging. If the edge structure of an image is complicated or the image has many details, then these methods would blur such details. This article presents a novel image denoising framework based on local clustering of image intensities and adaptive smoothing. The new denoising method can preserve complicated edge structures well even if the image resolution is low. Theoretical properties and numerical studies show that it works well in various applications.     

Electron-donating or -withdrawing nature of substituents revealed by the electrochemistry of metal-free phthalocyanines

The effect of substituents on the electrochemistry of metal-free phthalocyanines was examined for 17 phthalocyanine compounds. This work also provides new information about the electron-donating or -withdrawing nature of various substituents, namely, alkoxy, alkylthio, alkyl, alkynyl, phenyloxy, and phenylthio groups attached to the phthalocyanine system, from the viewpoint of electrochemistry. Most of the effects of peripheral and nonperipheral substitution and changes in the ring (pi-conjugated system) size on the electrochemistry of metal-free phthalocyanines can be reasonably explained by considering the energy levels of frontier molecular orbitals of the corresponding compounds, which were obtained by calculations using the semiempirical PM3 method.