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排序方式: 共有108条查询结果,搜索用时 281 毫秒
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The influence of temperature on crosshatching on ablating cone models made of wax and camphor is studied. Ablation experiments
are carried out in supersonic tunnels. The relation between temperature and the wavelength of crosshatching is obtained. The
effect of pressure on the wavelength of crosshatching is verified. The influence of temperature and pressure on the initial
position of the appearance of crosshatching and on the time required for both the apperance of croosshatching and the formation
of stable crosshatching are obtained and analyzed. 相似文献
65.
Bian Y Jiang J Tao Y Choi MT Li R Ng AC Zhu P Pan N Sun X Arnold DP Zhou ZY Li HW Mak TC Ng DK 《Journal of the American Chemical Society》2003,125(40):12257-12267
A series of 7 cerium double-decker complexes with various tetrapyrrole ligands including porphyrinates, phthalocyaninates, and 2,3-naphthalocyaninates have been prepared by previously described methodologies and characterized with elemental analysis and a range of spectroscopic methods. The molecular structures of two heteroleptic [(na)phthalocyaninato](porphyrinato) complexes have also been determined by X-ray diffraction analysis which exhibit a slightly distorted square antiprismatic geometry with two domed ligands. Having a range of tetrapyrrole ligands with very different electronic properties, these compounds have been systematically investigated for the effects of ligands on the valence of the cerium center. On the basis of the spectroscopic (UV-vis, near-IR, IR, and Raman), electrochemical, and structural data of these compounds and compared with those of the other rare earth(III) counterparts reported earlier, it has been found that the cerium center adopts an intermediate valence in these complexes. It assumes a virtually trivalent state in cerium bis(tetra-tert-butylnaphthalocyaninate) as a result of the two electron rich naphthalocyaninato ligands, which facilitate the delocalization of electron from the ligands to the metal center. For the rest of the cerium double-deckers, the cerium center is predominantly tetravalent. The valences (3.59-3.68) have been quantified according to their L(III)-edge X-ray absorption near-edge structure (XANES) profiles. 相似文献
66.
Qu Yang Wangyang Peihua Humayun Muhammad Sun Li Batter Buhe Li Zhijun 《Research on Chemical Intermediates》2017,43(11):6395-6406
Research on Chemical Intermediates - The coordination and reduction effects in polyol-mediated solvothermal synthesis were studied using nickel acetate as model precursor and ethylene glycol... 相似文献
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Ziye Yang Mingrui Jiang Zhuzhu Yue Peihua Wang Huinan Wang Guimei Zhang Mengyu Chen Jingqiu Zhang Zhicheng Wang Chao Zhang Yanhua Cao Yingzi Wang 《Biomedical chromatography : BMC》2022,36(3):e5279
Semen Euphorbiae (SE), the dry and mature seed of Euphorbia lathyris L., a common traditional Chinese medicine, has significant pharmacological activity. However, its toxicity limits its clinical application, and less toxic Semen Euphorbiae Pulveratum (SEP) is often used clinically. To explore the possible mechanism of SE frost-making and attenuation, this study used ultrahigh-performance liquid chromatography coupled with quadrupole time of flight mass spectrometry to perform a comprehensive metabolomics analysis of serum and urine samples from rats treated with SE and SEP, and performed histopathological evaluation of liver, kidney and colon tissues. Meanwhile, the different metabolites were visualized through multivariate statistical analysis and the HMDB and KEGG databases were used to distinguish the differential metabolites of SE and SEP to reveal related metabolic pathways and their significance. In total, 32 potential biomarkers, 14 in serum and 18 in urine, were identified. The metabolic pathway analysis revealed that arachidonic acid metabolism, sphingolipid metabolism, tyrosine and tryptophan biosynthesis, the tricarboxylic acid cycle and seven other metabolic pathways were significantly altered. Importantly, compared with SE, SEP reduced the metabolic disorder related to endogenous components. The mechanism may be related to the regulation of lipid metabolism, intestinal flora metabolites, amino acid metabolism and energy metabolism. This study provided new insights into the possible mechanism of SE freezing and attenuation. 相似文献
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Ting Yang Wenwu Xu Xiyu Wei Zhenzhen Zhang Yue Sun Houru Liu Peihua Yu Wei Li Dehong Yu 《Biomedical chromatography : BMC》2022,36(2):e5268
Ginsenoside Rh3 (GRh3) is a bacterial metabolite of ginsenoside Rg5, which is the main component of hot-processed ginseng. A simple, efficient and sensitive method was developed and validated for the determination of GRh3 in rat plasma by LC–tandem mass spectrometry. After protein precipitation with methanol/acetonitrile (1:1, vol/vol) using propranolol as the internal standard, the target analytes were separated on an XDB C18 column, with methanol containing 0.1% formic acid and water containing 0.1% formic acid used as mobile phases for gradient elution. Mass spectrometry was performed in electrospray ion source–positive ion mode and multiple reaction monitoring mode, monitoring the transitions m/z 622.5 → 425.5 and m/z 260.1 → 116.1 for GRh3 and internal standard, respectively. The concentration range of GRh3 was 20–20,000 ng/mL and the correlation coefficient (r2) was greater than 0.99. The accuracy error and relative standard deviation were below 15%. The extraction recovery and matrix effect were 74.2% to 78.7% and 96.9% to 108.4%, respectively. Under different conditions, GRh3 was stable in the range of 1.8%–8.7%. This method has been successfully applied to study the pharmacokinetics of GRh3 with an oral dose of 10.0 mg/kg and an intravenous dose of 2.0 mg/kg in rats, respectively. The absolute bioavailability of GRh3 was 37.6%. 相似文献
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Zhang H Wang R Zhu P Lai Z Han J Choi CF Ng DK Cui X Ma C Jiang J 《Inorganic chemistry》2004,43(15):4740-4742
The first slipped pseudo-quadruple-decker complex of phthalocyanines was formed unexpectedly upon treatment of the protonated double-decker SmIIIH(Pc)[Pc(alpha-OC4H9)8] with NaOH. The supramolecular structure contains two double-decker units linked by two sodium ions by an extremely rare coordination mode of phthalocyanines in which an aza nitrogen atom and two oxygen atoms from neighboring alkoxy substituents form a tridentate ligand. 相似文献