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91.
Equivalence of functional-differential equations of neutral type to well-posed abstract Cauchy problems in the state spaces n }L p ,L p resp.C is investigated. The assumptions allow non-atomic difference operators.This work was supported by the Fonds zur Förderung der wissenschaftlichen Forschung (Austria) under Grant No. P4534.Work done by this author was done during a stay at the University of Graz from October 1981 till April 1984.  相似文献   
92.
为了寻找新的有效光敏材料,设计了一系列新型氮杂2-β萘基苯并恶唑分子,用改进的PPP-SCF-CI方法,对设计分子的第一激发单线态,三线态,振子强度和跃迁矩等光物理性质进行了较为详细的研究,筛选出了一些新型的具有特殊光物理特性的分子,并预测了有可能产生新型氮杂2-β萘基苯并恶唑分子类光敏感功能材料的取代基部位。  相似文献   
93.
This Letter shows explicitly that the descent sequence of cocycles in a gauge group realizes the ech-de Rham double complex. Meanwhile the ech complex corresponds to finite gauge transformations. This Letter also shows how the indices of each order of cocycles characterizes the obstructions on overlapping spheres in different dimensions and how these indices are equal to a common one.  相似文献   
94.
An experimental investigation on shortening of travelling-wave ASE employing a transversal pumping is presented. A N2 laser with =337.1 nm, pulsewidth: 700 ps is used as a pump source. An ASE pulse with duration of 45, 55 and 45 ps from dye solution of Rh 6G, Rh B and C311, respectively, is obtained. Pulse shapes of output signals generated from these solutions in three different pumping schemes are compared.  相似文献   
95.
The streaming potential of supersaturated solution of binary carboxylic acids, which have even carbon atoms, was determined to characterize crystallization under different temperatures. The value of the streaming potential was related to the type and solubility of the acids and the starting temperature of crystallization, and was easily influenced by the pressure difference of the liquid or the rate of temperature decline. When the temperature was declined to the point where a crystal nucleus appeared, the streaming potential reached the minimum. Thereafter, as the temperature was sequentially lowered, some minicrystals grew, and the streaming potential presented an ascendant tendency. The higher the starting temperature of the acids saturated solution, the higher is the temperature corresponding to the streaming potential minimum. The less the carbon atoms in the acids and the greater the solubility of the acids are, the higher is the temperature of the streaming potential minimum. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   
96.
制备了一系列硼掺杂的还原氧化态石墨烯催化剂并应用于蒽加氢反应。结果表明,随着催化剂处理温度的升高,催化剂中有序碳结构会发生变化,硼会取代材料骨架中的碳,进而影响蒽和氢气的吸附活化。经硼改性后,催化剂对蒽加氢反应表现出了很高的加氢活性,蒽的最高转化率可达97%,深度加氢产物八氢蒽的最高选择性可达19%。  相似文献   
97.
钇对金属陶瓷力学性能和组织的影响   总被引:6,自引:0,他引:6  
研究了添加钇对Ti(C,N)基金属瓷力学性能和组织的影响。结果表明,加入适量的钇能提高Ti(C,N)基金属陶瓷的抗变强度和硬度,其原因是由于钇与杂质硫起反应在化合物,净化了陶瓷相-金属相,陶瓷相-陶瓷相界面提高子界面结合强度  相似文献   
98.
Liu J  Bi S  Yang L  Gu X  Ma P  Gan N  Wang X  Long X  Zhang F 《The Analyst》2002,127(12):1657-1665
The biological effects of aluminium have received much attention in recent years. Speciation of Al is of basic relevance as it concerns its reactivity and bioavailability. A differential pulse voltammetry (DPV) procedure is proposed for speciation analysis of Al(III) in natural waters and biological fluids using six catechols (L-dopa, dopamine, epinephrine, norepinephrine, caffeic acid and o-benzenediol) as electroactive ligands. The decrease of the DPV anodic peak current for each catechol ligand is linear with the increase of Al concentration. This speciation analysis idea is based on the measurement of the complexation capacity, namely, different affinities of Al(III) for catechols and organic ligands under two pH conditions. The labile monomeric Al fraction (mainly inorganic aluminium) is determined at pH 4.6, while the total monomeric Al fraction is determined at pH 8.5. The principle for Al(III) speciation analysis by an electrochemical method is discussed. This sensitive and simple fractionation method is successfully applied to the speciation analysis of Al in natural waters and the results agree well with those of Driscoll's method. The speciation analysis of Al in biological fluids is also explored and the results are compared with those obtained by ultrafiltration and dialysis. Compared with other speciation protocols the electrochemical method possesses some remarkable advantages: rapidity, high sensitivity, cheap instrumentation and a simple operation procedure.  相似文献   
99.
合成多肽的电喷雾质谱研究   总被引:1,自引:2,他引:1  
利用电喷雾多极串联质谱对3种合成多肽进行了系统的鉴定和分析研究。首先通过全扫描模式测定了其分子量,然后选择[M H]^ 或[M 2H]^2 离子通过串联质谱(MS/MS)得到碎片离子,采用y离子和b离子互补的方法测定了多肽序列。利用文献数据对这种方法进行了验证,实验结果表明,该方法简便、快速、实用。  相似文献   
100.
Four lanthanide coordination polymers with benzophenone‐4,4′‐dicarboxylic acid (H2bpndc) and 1,10‐phenanthroline (phen), [Ln2(bpndc)3(phen)] (Ln=La (1), Pr (2) and Tb (3)), [Yb(bpndc)15(phen)].05H2O (4) were obtained through solvothermal synthesis. The crystallographic data show that 1, 2, and 3 are isostructural, the Ln(III) ions in 1, 2 and 3 are all eight‐ and ten‐coordinated, respectively, and thus the Ln(III) ions are connected by bpndc ligands, resulting in an interpenetrating 3D structure. While in 4, the Yb(III) ions are eight‐coordinated and connected by bpndc ligands into a 3D structure with 1D rhombic channels, which result from the effect of lanthanide contraction from La(III) to Yb(III) ions, and the bpndc ligands in 1, 2, 3, and 4 display three types of coordination modes.  相似文献   
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