Untersuchungen an oxidischen Katalysatoren. XXIV [1]. Adsorptions- und katalytische Eigenschaften von CeNaY- und CrNaY-Zeolithen

Studies on Oxide Catalysts. XXIV. Adsorption and Catalytic Properties of CeNaY and CrNaY Zeolites The adsorption of benzene, n-butylamine and ammonia(isotherms and heats of adsorption) on CeNaY and CrNaY zeolites of different exchange degrees has been measured. The acidic properties were characterized by titration with n-butylamine. As function of exchange degree the adsorption and catalytic properties (cracking of cumene) both change in the same manner. Whereas the reaction rate constants up to exchange degrees of 40–50% change only insignificantly, they are exponentially increasing at higher exchange degrees. The energies of activation are nearly independent of the degree and run to 23–25 kcal mol^?1.     

Untersuchungen an oxidischen Katalysatoren. XXVIII. Einfluß der Vorbehandlungsbedingungen auf Die katalytischen Eigenschaften von NiNaY- und NiCoNaY-Zeolithen

Studies on Oxide Catalysts. XXVIII. Influence of Pretreatment on Catalytic Properties of Zeolites NiNaY and NiCoNaY The influence of the pretreatment conditions on the acidic properties, the reduction degree of nickel, and the catalytic activity and selectivity of zeolites NiNaY and NiCoNaY in the alkylation of benzene with ethylene has been investigated. From the experimental results can be concluded that sec. buthylbenzene from benzene and ethylene is only formed on zeolite samples which contain both together BRÖNSTED acidic centres and Ni²⁺ cations or NiO. Catalysts which contain only metallic nickel are inactive for this reaction. Catalysts with nickel in different forms are active in the formation of ethylbenzene, diethylbenzene, butane and sec. buthylbenzene, the yields depending on the relation of Ni°, Ni²⁺, and NiO. Changing this relation makes possible to regulate the selectivity in the alkylation of benzene with ethylene.     

Evaluation of carborane-containing nematic liquid crystals for electro-optical applications

Three new structurally similar compounds in series 1[2] and 2 containing 12- and 10-vertex p-carborane units (A and B) were prepared. Their thermal properties were investigated in the pure state and compared to those of their carbocyclic analogues. Using several higher homologues in the series 1[n], clearing temperatures for the unknown 1[4] and 1[10] were predicted. Optical, dielectric and rotational viscosity parameters for carborane derivatives 1[2] and 2 and their cyclohexane analogies were obtained by extrapolation of values measured for 10% solutions in a standard nematic host. The observed trends were rationalised using computed molecular parameters.     

Pathplanning and control of an autonomous robot vehicle with a manipulator

An autonomous mobile robot is presented. It consists of two parts: a mobile vehicle underneath a robotarm with DOF 5. These two are a nonholomic (the mobile vehicle) and a holonomic subsystem (the robotarm). To give the robot orders or tasks to accomplish this can be done from an external controlsoftware via TCP–IP to the controlsoftware of the robot. An embedded system involves chart creation, pathplanning (global, local), evaluation of sensorsignals, object– and/or marker–detection and a controlled movement. Futhermore it communicates over FIFOs with an nonrealtime–task which allows a communication via TCP–IP. Several sensors are implemented, e.g. infrared–/ ultrasonic–range sensors connected via CAN to the embedded board, as well as the control boards for each engine. A Laserscanner is installed in front of the robot to detect edges and obstacles. For marker–tracking and object recognition an USB–Webcam is added on the robotarm. For avoidance of collisions between the robotarm and the mobile robot a repeller is introduced. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

An Experimental Method for the Phase Controlled Frequency Response Measurement of Nonlinear Vibration Systems

Experimental determination of frequency response function of nonlinear systems is difficult when there exists more than one solution branch. Depending on the system at hand, various types of jump phenomena can be observed and in the example of the well-known Duffing-oscillator, it is not possible to experimentally determine the unstable solution branch if the system is excited by a harmonic force. In the present paper we investigate the Duffing-oscillator and present a method, which allows to reformulate the equation of motion of the system with force-excitation in the form of an equivalent self-excited system. Considering the phase between force and response as the input variable, it is possible to evaluate the frequency of the systems vibration for any given phase shift. In the same way the corresponding response amplitude is determined. An experimental set-up is presented, which is used to validate the performance of the method. Measurements of the backbone curve are performed and discussed on the background of theoretical predictions. (© 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)