Effect of cerium, holmium and samarium ions on the thermal and structural properties of the HZSM-12 zeolite

The study of the incorporation of rare earth elements as additives in Y zeolites is a very interesting field of research, mainly by its potential application as additives in catalytic cracking process. In this work was studied the thermal and structural properties of cerium, holmium and samarium supported on HZSM-12 zeolite. The obtained materials were characterized by X-ray diffraction (XRD), infrared spectroscopy (FTIR), nitrogen adsorption, thermogravimetry (TG/DTG), differential scanning calorimetry (DSC) and differential thermal analysis (DTA). TG/DSC/DTA analyses showed that the dehydration temperatures of RE/HZSM-12 zeolites (RE=Ce, Ho, Sm) increase in relation to pure HZSM-12. The acid properties were investigated by pyridine thermo desorption via TG. The results showed two events of mass loss attributed to elimination of pyridine adsorbed on the weak+medium acid sites and on the strong acid sites.     

Determination of levofloxacin in pharmaceutical formulations and urine at reduced graphene oxide and carbon nanotube-modified electrodes

Journal of Solid State Electrochemistry - In this paper, we compare reduced graphene oxide (RGO) electrode with multi-walled carbon nanotubes (MWCNT) as modifiers for the sensitive detection of...     

Synthesis,crystal structure and reactivity of a new pentacoordinated chiral dioxomolybdenum(VI) complex

The novel tridentate chiral ligand 2,6-bis{[(1R,2S,4R)-2-hydroxy-1,3,3-trimethyl-bicyclo[2.2.1]hept-2-yl]}pyridine (1) was readily prepared by reaction of 2,6-dilithiopyridine with (R)-(−)-fenchone. Reaction of 1 with [MoO₂(acac)₂] resulted in the formation of the new metal-oxo five-coordinated complex [MoO₂(ONO)] (2) [ONO = (1 – 2H)]. The reactivity of 2 has been studied and the derivatives [MoS₂(ONO)] (3) and [MoO(O₂)(ONO)] (4) were prepared. The compounds 1–4 have been characterised by ¹H and ¹³C{¹H} NMR, microanalysis and IR spectroscopy. Furthermore, the molecular structures of 1 and 2 have been determined by single-crystal X-ray diffraction. The behaviour of 2 as catalyst in oxotransfer and in nucleophilic substitution of propargylic alcohols reactions has been tested.     

Gaussian wave packet states of relic gravitons

In this contribution, we investigate quantum effects of relic gravitons in a Friedmann–Robertson–Walker (FRW) cosmological background. We reduce the problem to that of a generalized time-dependent harmonic oscillator and find the corresponding exact Schrödinger states with the help of linear invariants and of the dynamical invariant method. Afterwards, we construct Gaussian wave packet states and calculate the quantum dispersions as well as the quantum correlations for each mode of the quantized field.     

Study of the plasma potential evolution during ECRH in the T-10 tokamak and TJ-II stellarator

Comparison of the plasma electric potential evolution in the T-10 tokamak and TJ-II stellarator was performed. The core potential was measured by the heavy-ion beam probing and the edge potential was measured by Langmuir probe. The intrinsic potentials in both devices are different in sign, positive in TJ-II low-density discharge and negative in T-10 higher-density discharges, but during ECRH they evolve similarly: the potential becomes more positive, and increase of ECRH power leads to stronger rise of core potential. Presented at the Workshop “Electric Fields, Structures and Relaxation in Edge Plasmas”, Tarragona, Spain, July 3–4, 2005.     

Regio- and stereoselective methoxyselenenylation of chiral 2-vinyl perhydro-1,3-benzoxazines promoted by selenium-heteroatom nonbonded interactions

Regio- and diastereoselective methoxyselenenylations of double bonds attached to the N,O-ketalic carbon of chiral perhydrobenzoxazines occur in high yields by reaction with benzeneselenenyl chloride in dichloromethane-methanol. The diastereoselection is dependent on the reaction conditions and the structure of the starting compounds and can be rationalized by accepting the coordination of the selenium to the oxygen atom of the heterocycle.     

Detection of hydrogen peroxide releasing from prostate cancer cell using a biosensor

In this work, highly sensitive and selective hydrogel microstructures to detect hydrogen peroxide releasing from cancer cell based on electrochemical biosensors are proposed. Gold nanoparticles (AuNPs) were conjugated with horseradish peroxidase and were dispersed in the prepolymer solution of poly(ethylene glycol) diacrylate. The prepolymer solution was photolithographically patterned in alignment with an array of Au microelectrodes fabricated on glass. Performance of this biosensor was characterized by transmission electron microscopy, electrochemical impedance spectroscopy, and cyclic voltammetry. Under the optimal condition, the proposed biosensor can detect hydrogen peroxide (H₂O₂) in a wide linear range from 2 to 100 μM with a low detection limit of 0.01 μM. It can be also directly used to mark out extracellular H₂O₂ released from prostate cells. Furthermore, the reproducibility, stability, and selectivity of the biosensor are analogous with the previous report, so this methodology can be used in physiological and pathological detection of H₂O₂ in the future.     

Regiospecific synthesis of 1-arylpyrazoles

A new regiospecific synthesis of 1-aryl-substituted pyrazoles by reaction of aryl-hydrazines with β-aminoenones is reported.