Mechanical properties of metallic ribbons investigated by depth sensing indentation technique

The paper presents mechanical properties of two kinds of Co-based and one Fe-based metallic ribbons by the depth sensing indentation (DSI) technique. Investigations were carried out on two kinds ternary alloy Co₇₇Si_11,5B_11,5 and Fe₇₈Si₁₃B₉ and multicomponent Co₆₈Fe₄Mo₁Si_13,5B_13,5, which are so-called “zero-magnetostriction” materials. Metallic ribbons were investigated in amorphous state and partially crystallized state after annealing in 400°C in argon atmosphere. Heating of ribbons obtained by melt spinning technique was performed to check its effect on changes of mechanical properties.     

氯雷他定的结构分析

氯雷他定是一种高效抗过敏药。采用质谱、红外光谱、核磁共振氢谱、碳谱以及^1H检测的异核多量子相干相关谱等技术，对氯雷他定的分子结构进行了谱图解析。     

Solubility Study of Nimodipine Inclusion Complexation with α- and β-Cyclodextrin and some Substituted Cyclodextrins

The solubility of nimodipine was measured in aqueous solutions of the following cyclodextrins: -cyclodextrin (-CD), hydroxypropyl--CD (HP--CD), -cyclodextrin (-CD), random substituted methyl--CD (M--CD), three hydroxypropyl--CDs (HP--CD) with mutually different average degree of substitution, and hydroxypropyl--cyclodextrin (HP--CD). From the determined linear solubility diagrams the values of the binding constant K₁₁ of the inclusion complexes of nimodipine with the respective CDs were evaluated. The -CDs efficiently solubilized sparingly soluble nimodipine, the highest value of K₁₁ was found for M--CD (1680 M^-1), followed by -CD (550 M^-1) and HP--CDs, where the higher degree of substitution lowered K₁₁. Only slight solubilization of nimodipine was observed in the solutions of the -CDs and HP--CD.     

Molecular aspects of superconductivity: The role of the one-particle term at the gap formation

An exact solution for the electron-vibrational problem of the nonadiabatic molecular system has been obtained. By the quasi-particle transformation technique, the fermionic Hamiltonian has been derived and solved at the ab initio level. Results clearly and unambiguously show that the gap formation due to nonadiabatic electron–phonon coupling is mediated by the one-particle electron–phonon interaction term, whereas the two-particle one represents just a correction to the correlation energy. The temperature dependence of the gap and electronic specific heat connected with the electron–phonon coupling have also been derived.     

Duality and Polynomial Testing of Tree Homomorphisms

Let be a fixed digraph. We consider the -colouring problem, i.e., the problem of deciding which digraphs admit a homomorphism to . We are interested in a characterization in terms of the absence in of certain tree-like obstructions. Specifically, we say that has tree duality if, for all digraphs , is not homomorphic to if and only if there is an oriented tree which is homomorphic to but not to . We prove that if has tree duality then the -colouring problem is polynomial. We also generalize tree duality to bounded treewidth duality and prove a similar result. We relate these duality concepts to the notion of the -property studied by Gutjahr, Welzl, and Woeginger.

We then focus on the case when itself is an oriented tree. In fact, we are particularly interested in those trees that have exactly one vertex of degree three and all other vertices of degree one or two. Such trees are called triads. We have shown in a companion paper that there exist oriented triads for which the -colouring problem is -complete. We contrast these with several families of oriented triads which have tree duality, or bounded treewidth duality, and hence polynomial -colouring problems. If , then no oriented triad with an -complete -colouring problem can have bounded treewidth duality; however no proof of this is known, for any oriented triad . We prove that none of the oriented triads with -complete -colouring problems given in the companion paper has tree duality.

     

Homomorphisms to oriented cycles

We discuss the existence of homomorphisms to oriented cycles and give, for a special class of cyclesC, a characterization of those digraphs that admit, a homomorphism toC. Our result can be used to prove the multiplicativity of a certain class of oriented cycles, (and thus complete the characterization of multiplicative oriented cycles), as well as to prove the membership of the corresponding decision problem in the classNPcoNP. We also mention a conjecture on the existence of homomorphisms to arbitrary oriented cycles.     

Configuration and E/Z interconversion mechanism of O(S)-allyl-S(O)-methyl-N-(acridin-9-yl) iminothiocarbonate

The configuration and dynamic behavior of O-allyl-S-methyl-N-(acridin-9-yl)iminothiocarbonate (1) and its S-allyl-O-methyl regioisomer (2) were studied using quantum chemical calculations and by applying a novel graphical method to scatter maps obtained from MD simulations for evaluation of an NOE-weighted internuclear distance (r(NOE)). Energy calculations indicated that the Z configuration was predominant for each compound and, further, this was supported both by the calculated chemical shifts and the r(NOE). Both N-inversion- and rotation-type transition-state structures were also calculated for the E/Z isomerization process, the results indicating that the preferred interconversion mechanism for 1 is N-inversion, but contrastingly, interconversion via rotation is equally as probable as N-inversion for 2. This supports the notion that one or the other or both pathways can be active and each system needs to be assessed on a case-by-case basis.     

Regiospecific synthesis,structure and electron ionization mass spectra of 1,3‐thiazolidin‐4‐ones containing the acridine skeleton

The synthesis of regioisomeric 3‐alkyl(aryl)‐2‐(acridin‐9′‐yl)imino‐1,3‐thiazolidin‐4‐ones ( 8b‐i ) and 2‐alkyl(aryl)imino‐3‐(acridin‐9′‐yl)‐1,3‐thiazolidin‐4‐ones ( 11a‐i ) was performed by the reaction of 3‐(acridin‐9‐yl)‐1‐alkyl(aryl)thioureas 5a‐i with methyl bromoacetate and bromoacetyl bromide, respectively, via the corresponding isothiourea hydrobromides with excellent regioselectivity. The structure, NMR spectra and mass spectrometric behavior of the resulting compounds are discussed.     

An Easy and Fast Conversion of N2-[(tert-Butoxy)carbonyl]-L-amino Acids to Corresponding Amino-aldehydes

A new method for the preparation of N²-[(tert-butoxy)carbonyl]-L -amino-aldehydes from N²-[(tert-butoxy)carbonyl]-L -amino acids based on reduction of mixed anhydrides with LiAl(t-BuO)₃H is described.