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Andrei B. Ouryupin Pavel V. Petrovskii Ivan A. Rakhov Tatyana A. Mastryukova 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1)
Abstract The reaction of trimethylsilylisothiocyanate with phosphorus acids chlorides was demonstrated to be reversible. 相似文献
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Leonid S. Zakharov Galina N. Molchanova Tat'yana M. Shcherbina Pavel V. Petrovskii Martin I. Kabachnik 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1)
Abstract We have studied the phosphorylation of 1-polyfluorólkyl-2-trialkylsilylethanols (I) with phosphorus acids chlorides. 相似文献
154.
Pavel Mokrejs Svatopluk Sukop Petr Svoboda 《Applied biochemistry and biotechnology》2012,168(2):434-445
The subject of our previous paper (part 1) was three-stage extraction of gelatines from short cattle tendons. In this paper, we studied influence of extraction conditions on quality of produced gelatines??protein content, ash content, rigidity of gelatine gels, viscosity, and distribution of molecular weights. Ash content of gelatines ranged in limits 3.5?C10.5?%. Rigidity of the gels was influenced by extraction conditions and by elastin content in gelatines; highest-quality gels display rigidity of 213 Bloom. Viscosity of gelatines ranged from 2.47 to 12.11?mPa?s. Molecular weights of gelatines display a proportion of fractions from 20 to 36?kDa, a quite high proportion of fractions from approximately 50 to 100?kDa, in some cases even fractions above 200?kDa appear. It was found that transition temperature and melting temperature of gelatines extracted from tendons are in accord with data on gelatines obtained by traditional extraction techniques from skins and bones. With respect to efficiency of the whole extraction process and to quality of extracted gelatine, we may recommend extraction conditions as follows: in the 1st processing stage, shaking degreased starting material with water in ratio 1:10 at 25?°C for 5?h; in the 2nd stage, treating the swelled material with 5?% (w/w) added proteolytic enzyme at 40?°C for 25?h; in 3rd stage, extracting gelatine while boiling for 16?min. 相似文献
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Milan Jakubek Zdeněk Kejík Robert Kaplánek Hana Veselá David Sýkora Pavel Martásek 《Supramolecular chemistry》2018,30(3):218-226
Perimidine-based chelators 1 and 2 were prepared, and their structures were confirmed by 1H and 13C NMR, MS spectroscopy and elemental analysis. These compounds were studied as specific synthetic receptors for the recognition of transition metal ions. They exhibited high affinity and selectivity towards Cu(II) ions. The conditional binding constants, linear dynamic range and detection limit were determined by UV–vis spectroscopy. These parameters demonstrated high potential of the prepared synthetic receptors for the recognition and determination of Cu(II) ions. The minimum detectable concentrations of Cu(II) ions for the synthetic receptors 1 and 2 were 270 and 75 nM (R 2 = 0.9915 and 0.9964) in aqueous medium (water/DMSO; 99:1 (v/v)), respectively. 相似文献
157.
Alberto S. Cattaneo Pavel Mnev Nicolai Reshetikhin 《Communications in Mathematical Physics》2014,332(2):535-603
In this paper we extend the classical BV framework to gauge theories on spacetime manifolds with boundary. In particular, we connect the BV construction in the bulk with the BFV construction on the boundary and we develop its extension to strata of higher codimension in the case of manifolds with corners. We present several examples including electrodynamics, Yang-Mills theory and topological field theories coming from the AKSZ construction, in particular, the Chern-Simons theory, the BF theory, and the Poisson sigma model. This paper is the first step towards developing the perturbative quantization of such theories on manifolds with boundary in a way consistent with gluing. 相似文献
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