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21.
22.
High resolution conventional AFP NMR/ON studies provide evidence for very small efg's of predominantly negative sign at the nucleus of the nominal S-state ion54Mn in single crystal nickel when the applied field is paralled to the 111 direction. The form of the mid passage signals for opposing sweep directions indicates a unique efg super-imposed upon a random component of comparable magnitude. The advantages of a second analyzing sweep performed during spin lattice relaxation of a conventional post-passage AFP NMR/ON sweep are demonstrated. 相似文献
23.
Edie M. Rasmussen Peter Willett Terence Wilson Gordon A. Manson George A. Wilson 《Analytica chimica acta》1990
The use of two types of parallel computer hardware for increasing the efficiency of processing in chemical structure data bases is discussed. The distributed array processor can be used for the clustering of 2-D chemical structure data bases by using the Jarvis—Patrick clustering method and for the ranking of output in an experimental system for substructure searching in the 3-D macromolecules in the Protein Data Bank. The Inmos transputer can be used in the construction of PC-based systems for 2-D substructure searching and in the identification of the maximal substructures common to pairs of 3-D molecules. 相似文献
24.
A perturbative approach is employed to solve the Bloch-Torrey equations in the presence of distant-dipole fields in nuclear magnetic resonance. The procedure, although only carried out to first order in the perturbation parameter a=1/k2Dtaud, could, in principle, be generalized to higher orders. Here D is the diffusivity, taud the dipolar demagnetization time, and k is the wave vector of the spatial modulation of magnetization produced by the magnetic field gradient. The results are especially interesting for dilute binary mixtures consisting of molecular species with different diffusivities. In this case the calculated two-dimensional correlation spectroscopy revamped by asymmetric Z-gradient echo detection spectra are shown to be free from some inadequacies resulting from a simplistic application of standard approximations. 相似文献
25.
Three theories which have been proposed to explain the observed shortening of a single bond when it is adjacent to a double bond are discussed. Possible predictions from these theories are examined, especially for comparison with various quantities measurable by microwave spectroscopy. It is concluded that the steric theory is probably untenable, that some conjugation appears necessary to explain observed barries to internal rotation, and that it is difficult to find testable predictions from the hybridization theory. 相似文献
26.
27.
Ernst Berger David W. T. Griffith Gerhard Schuster Stephen R. Wilson 《Mikrochimica acta》1988,95(1-6):239-241
The use of an integrating sphere for the measurement of absorption spectra of thin films is described. The thin film (for example a rare gas matrix) is grown directly on the inside surface of the sphere. Multiple reflections inside the integrating sphere lead to significant enhancement of weak absorptions of the film, increasing the sensitivity of such measurements. 相似文献
28.
Determination of aflatoxins in food products by chromatography. 总被引:1,自引:0,他引:1
Several chromatographic methods for the determination of aflatoxins in agricultural and food products are reviewed. During the past two decades, identification and determination of aflatoxins were done by thin-layer chromatography (TLC) because it was easy, fast and inexpensive. However, high-performance liquid chromatography (HPLC) using fluorescence detection is now the method of choice for determining aflatoxins and is also growing in popularity for their identification. The reasons for selecting HPLC over TLC can be summarized as the ability to analyze for a wide variety of compounds, including compounds that are easily degraded by heat, light or air, the ease of adaptation to confirmatory procedures, the potential for automation and the dramatic improvement in instrumentation, including the development of increasingly sensitive fluorescence and electrochemical detectors and short, high-resolution, reversed-phase columns. 相似文献
29.
Leon P. Jenner Mickael V. Cherrier Patricia Amara Luis M. Rubio Yvain Nicolet 《Chemical science》2021,12(14):5269
The nitrogenase MoFe protein contains two different FeS centers, the P-cluster and the iron–molybdenum cofactor (FeMo-co). The former is a [Fe8S7] center responsible for conveying electrons to the latter, a [MoFe7S9C-(R)-homocitrate] species, where N2 reduction takes place. NifB is arguably the key enzyme in FeMo-co assembly as it catalyzes the fusion of two [Fe4S4] clusters and the insertion of carbide and sulfide ions to build NifB-co, a [Fe8S9C] precursor to FeMo-co. Recently, two crystal structures of NifB proteins were reported, one containing two out of three [Fe4S4] clusters coordinated by the protein which is likely to correspond to an early stage of the reaction mechanism. The other one was fully complemented with the three [Fe4S4] clusters (RS, K1 and K2), but was obtained at lower resolution and a satisfactory model was not obtained. Here we report improved processing of this crystallographic data. At odds with what was previously reported, this structure contains a unique [Fe8S8] cluster, likely to be a NifB-co precursor resulting from the fusion of K1- and K2-clusters. Strikingly, this new [Fe8S8] cluster has both a structure and coordination sphere geometry reminiscent of the fully reduced P-cluster (PN-state) with an additional μ2-bridging sulfide ion pointing toward the RS cluster. Comparison of available NifB structures further unveils the plasticity of this protein and suggests how ligand reorganization would accommodate cluster loading and fusion in the time-course of NifB-co synthesis.The K-cluster of NifB as a key intermediate in the synthesis of the nitrogenase active site supports [Fe4S4] cluster fusion occurs before carbide and sulfide insertion and displays ligand spatial arrangement reminiscent to that of the P-cluster. 相似文献
30.
The wavefunctions and various partitions of the energy are examined for a variety of small molecules (H2, H3, H4, HeH, HeH2, He2, LiH, and BH) in order to isolate the factors crucial for bond formation. We find that a natural partition of the energy leads to the conclusion that the crucial factor is the exchange, or nonclassical, part of the kinetic energy, T
x. The change in T
xupon pushing the atoms towards one another is the dominant term in the binding energy; it is negative when the resulting molecule is stable and positive when it is unstable. We show that T
x is related to the interference kinetic energy considered by Ruedenberg.
Partially supported by a grant (GP-15423) from the National Science Foundation. This paper is based on a portion of the PhD thesis (California Institute of Technology, 1970) by CWW.
National Science Foundation Predoctoral Trainee.
Alfred P. Sloan Foundation Research Fellow.
Contribution No. 3917. 相似文献
Zusammenfassung Die Wellenfunktionen und verschiedene Zerlegungen der Energie werden für eine Reihe kleiner Moleküle untersucht (H2, H3, H4, HeH, HeH2, He2, LiH und BH), um die Faktoren zu finden, die für die Bindungsbildung ausschlaggebend sind. Die natürliche Zerlegung der Energie läßt die Folgerung zu, daß der bestimmende Faktor der Austauschanteil T x(oder nichtklassische Anteil) der kinetischen Energie ist. Die Änderung von T xbeim Zusammenführen der Atome ist der dominierende Term für die Bindungsenergie; er ist negativ, wenn das resultierende Molekül stabil ist, und positiv, falls es instabil ist. Es wird gezeigt, daß T x im Zusammenhang zum Wechselwirkungsanteil der kinetischen Energie nach Ruedenberg steht.
Partially supported by a grant (GP-15423) from the National Science Foundation. This paper is based on a portion of the PhD thesis (California Institute of Technology, 1970) by CWW.
National Science Foundation Predoctoral Trainee.
Alfred P. Sloan Foundation Research Fellow.
Contribution No. 3917. 相似文献