Global analysis of the strangeness vector and axial form factors of the nucleon and their uncertainties

We have studied the strangeness contribution to the elastic vector and axial form factors of the nucleon, using all available electroweak elastic scattering data sensitive to these contributions. Specifically, we combine ??p and $\bar{\nu} p$ elastic scattering cross sections from Brookhaven E734 with parity-violating asymmetries in elastic ep scattering, and quasi-elastic ed and e ⁴He scattering, observed in the SAMPLE, HAPPEx, G0 and PVA4 experiments. We are able not only to determine these form factors at individual values of momentum-transfer (Q ²), as has been done recently, but also to fit the Q ²-dependence of these form factors using simple functional forms. We present the results of these fits using existing data.     

Probing the CH⋅⋅⋅π Weak Hydrogen Bond in Anesthetic Binding: The Sevoflurane–Benzene Cluster

Cooperativity between weak hydrogen bonds can be revealed in molecular clusters isolated in the gas phase. Here we examine the structure, internal dynamics, and origin of the weak intermolecular forces between sevoflurane and a benzene molecule, using multi‐isotopic broadband rotational spectra. This heterodimer is held together by a primary C? H???π hydrogen bond, assisted by multiple weak C? H???F interactions. The multiple nonbonding forces hinder the internal rotation of benzene around the isopropyl C? H bond in sevoflurane, producing detectable quantum tunneling effects in the rotational spectrum.     

An inequality involving permanents of certain direct products

Let A denote a decomposable symmetric complex valued n-linear function on C^m. We prove

$\text{6A·A6}{}^2\text{?2}{}^{\mathrm{n}}\text{2n}\text{n}{}^{\mathrm{?1}}\text{6A?A6}{}^2$

, where · denotes the symmetric product and ? the tensor product. As a consequence we have per

$\text{M}\text{M}\text{M}\text{M}\text{?2}{}^{\mathrm{n}}\text{[per(M)]}{}^2$

, where M is a positive semidefinite Hermitian matrix and per denotes the permanent function. A sufficient condition for equality in the matrix inequality is that M is a nonnegative diagonal matrix.     

Some improvements in Neuberger's iteration procedure for solving partial differential equations

If m and n are positive integers then let S(m, n) denote the linear space over R whose elements are the real-valued symmetric n-linear functions on E_m with operations defined in the usual way. If $\text{U}$ is a function from some sphere S in E_m to R then let $\text{U}$⁽ⁱ⁾(x) denote the ith Frechet derivative of $\text{U}$ at x. In general $\text{U}$⁽ⁱ⁾(x)∈S(m,i). In the paper “An Iterative Method for Solving Nonlinear Partial Differential Equations” [Advances in Math. 19 (1976), 245–265] Neuberger presents an iterative procedure for solving a partial differential equation of the form

$\text{AU}{}^{\mathrm{n}}\text{(x)=F(x, U(x), U′(x),…,U}{}^{\mathrm{k}}\text{(x))}$

, where k > n, $\text{U}$ is the unknown from some sphere in E_m to R, A is a linear functional on S(m, n), and F is analytic. The defect in the theory presented there was that in order to prove that the iterates converged to a solution $\text{U}$ the condition $\text{k ?}\text{n}\text{2}$ was needed. In this paper an iteration procedure that is a slight variation on Neuberger's procedure is considered. Although the condition $\text{k ?}\text{n}\text{2}$ cannot as yet be eliminated, it is shown that in a broad class of cases depending upon the nature of the functional A the restriction $\text{k ?}\text{n}\text{2}$ may be replaced by the restriction $\text{k ?}\text{3n}\text{4}$.     

Surface segregation and surface electronic interactions in PtCu

Photoemission and Auger electron spectroscopy on Pt_0.98Cu_0.02 show that the (110) face has over twice as much Cu surface segregation as the (111) face. The Cu 3d-derived surface “density of states” differ strikingly in peak shape and in width (by 0.5 eV). The centroids, compared with bulk Cu d states, are shifted by more than 0.3 eV towards the Fermi level. This is the first experimental correlation between surface segregation and surface bonding.